Trichlorido{2-dimethoxymethyl-4-methyl-6-[(quinolin-8-yl)iminomethyl]phenolato-κ3N,N′,O1}tin(IV)

Trichlorido{2-dimethoxymethyl-4-methyl-6-[(quinolin-8-yl)iminomethyl]phenolato-κ3N,N′,O1}tin(IV)

In the title compound, [Sn(C20H19N2O3)Cl3], the SnIV ion is surrounded by a tridentate monoanionic Schiff base and by three meridional chloride ions in a six-coordinated distorted octahedral geometry. The Sn—Cl bond [2.366 (2) Å] trans to nitrog...

Full description

Bibliographic Details
Main Authors: Keisuke Kawamoto, Takashi Shibahara
Format: Article
Language:English
Published: International Union of Crystallography 2012-02-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812002528
id doaj-0c0e7c95e79c4112aa5e77fd1dc2ed91
record_format Article
spelling doaj-0c0e7c95e79c4112aa5e77fd1dc2ed912020-11-25T01:35:43ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-02-01682m208m20810.1107/S1600536812002528Trichlorido{2-dimethoxymethyl-4-methyl-6-[(quinolin-8-yl)iminomethyl]phenolato-κ3N,N′,O1}tin(IV)Keisuke KawamotoTakashi ShibaharaIn the title compound, [Sn(C20H19N2O3)Cl3], the SnIV ion is surrounded by a tridentate monoanionic Schiff base and by three meridional chloride ions in a six-coordinated distorted octahedral geometry. The Sn—Cl bond [2.366 (2) Å] trans to nitrogen is shorter than the others [2.438 (2) and 2.414 (2) Å]. The N—Sn—N angle [76.19 (11)°] is smaller than the O—Sn—N angle [87.89 (10)°] in the Schiff base ligand. No classical intermolecular hydrogen-bonding interactions are observed. The crystal packing exhibits π–π stacking interactions, with a distance of 3.595 (2) Å between the centroids of the phenolate ring and the benzene ring of the quinoline group of inversion-related molecules.http://scripts.iucr.org/cgi-bin/paper?S1600536812002528
collection DOAJ
language English
format Article
sources DOAJ
author Keisuke Kawamoto
Takashi Shibahara
spellingShingle Keisuke Kawamoto
Takashi Shibahara
Trichlorido{2-dimethoxymethyl-4-methyl-6-[(quinolin-8-yl)iminomethyl]phenolato-κ3N,N′,O1}tin(IV)
Acta Crystallographica Section E
author_facet Keisuke Kawamoto
Takashi Shibahara
author_sort Keisuke Kawamoto
title Trichlorido{2-dimethoxymethyl-4-methyl-6-[(quinolin-8-yl)iminomethyl]phenolato-κ3N,N′,O1}tin(IV)
title_short Trichlorido{2-dimethoxymethyl-4-methyl-6-[(quinolin-8-yl)iminomethyl]phenolato-κ3N,N′,O1}tin(IV)
title_full Trichlorido{2-dimethoxymethyl-4-methyl-6-[(quinolin-8-yl)iminomethyl]phenolato-κ3N,N′,O1}tin(IV)
title_fullStr Trichlorido{2-dimethoxymethyl-4-methyl-6-[(quinolin-8-yl)iminomethyl]phenolato-κ3N,N′,O1}tin(IV)
title_full_unstemmed Trichlorido{2-dimethoxymethyl-4-methyl-6-[(quinolin-8-yl)iminomethyl]phenolato-κ3N,N′,O1}tin(IV)
title_sort trichlorido{2-dimethoxymethyl-4-methyl-6-[(quinolin-8-yl)iminomethyl]phenolato-κ3n,n′,o1}tin(iv)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-02-01
description In the title compound, [Sn(C20H19N2O3)Cl3], the SnIV ion is surrounded by a tridentate monoanionic Schiff base and by three meridional chloride ions in a six-coordinated distorted octahedral geometry. The Sn—Cl bond [2.366 (2) Å] trans to nitrogen is shorter than the others [2.438 (2) and 2.414 (2) Å]. The N—Sn—N angle [76.19 (11)°] is smaller than the O—Sn—N angle [87.89 (10)°] in the Schiff base ligand. No classical intermolecular hydrogen-bonding interactions are observed. The crystal packing exhibits π–π stacking interactions, with a distance of 3.595 (2) Å between the centroids of the phenolate ring and the benzene ring of the quinoline group of inversion-related molecules.
url http://scripts.iucr.org/cgi-bin/paper?S1600536812002528
work_keys_str_mv AT keisukekawamoto trichlorido2dimethoxymethyl4methyl6quinolin8yliminomethylphenolatoamp9543nnamp8242o1tiniv
AT takashishibahara trichlorido2dimethoxymethyl4methyl6quinolin8yliminomethylphenolatoamp9543nnamp8242o1tiniv
_version_ 1725066780338028544

Similar Items