Bis(acetato-κO)bis(2-pyridinealdoxime-κ2N,N′)cadmium

Bis(acetato-κO)bis(2-pyridinealdoxime-κ2N,N′)cadmium

In the title molecule, [Cd(CH3COO)2(C6H6N2O)2], the CdII cation is N,N′-chelated by two 2-pyridinealdoxime ligands and coordinated by two acetate anions in a distorted octahedral geometry. The hydroxy groups of the 2-pyridinealdoxime ligands link to the acetate anions via intramolecula...

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Bibliographic Details
Main Authors: Sadif A. Shirvan, Sara Haydari Dezfuli
Format: Article
Language:English
Published: International Union of Crystallography 2012-08-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812031819
Description
Summary:In the title molecule, [Cd(CH3COO)2(C6H6N2O)2], the CdII cation is N,N′-chelated by two 2-pyridinealdoxime ligands and coordinated by two acetate anions in a distorted octahedral geometry. The hydroxy groups of the 2-pyridinealdoxime ligands link to the acetate anions via intramolecular O—H...O hydrogen bonds. Weak intermolecular C—H...O hydrogen bonds occur in the crystal.
ISSN:1600-5368

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