Pentapotassium μ-arsenato-bis(hydroxytetramolybdate) dihydrate

Pentapotassium μ-arsenato-bis(hydroxytetramolybdate) dihydrate

The title arsenatomolybdate, K5[Mo8O24(OH)2(AsO4)]·2H2O, which was obtained hydrothermally, features an [AsMo8O28(OH)2]5− anion, which is formed by two Mo4O14(OH) units that are linked by As in a sandwich-like fashion. The overall symmetry of the anion is m2m. The {Mo4O14(...

Full description

Bibliographic Details
Main Authors: Hai-Hui Yu, Li Kong, Ji-Wen Cui, Hai-Tao Wang
Format: Article
Language:English
Published: International Union of Crystallography 2011-02-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810054176
id doaj-0c893f0c44cf4eed971646774372985a
record_format Article
spelling doaj-0c893f0c44cf4eed971646774372985a2020-11-25T01:35:43ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-02-01672i15i1510.1107/S1600536810054176Pentapotassium μ-arsenato-bis(hydroxytetramolybdate) dihydrateHai-Hui YuLi KongJi-Wen CuiHai-Tao WangThe title arsenatomolybdate, K5[Mo8O24(OH)2(AsO4)]·2H2O, which was obtained hydrothermally, features an [AsMo8O28(OH)2]5− anion, which is formed by two Mo4O14(OH) units that are linked by As in a sandwich-like fashion. The overall symmetry of the anion is m2m. The {Mo4O14(OH)} core is composed of two pairs of confacial bioctahedral {Mo2O9} units with two μ4-O atoms which have been characterized as hydroxyl groups. The anions are further interconnected by potassium cations, forming a three-dimensional network structure with the uncoordinated water molecules occupying the channels. The structure is further stabilized by O—H...O hydrogen bonding. http://scripts.iucr.org/cgi-bin/paper?S1600536810054176
collection DOAJ
language English
format Article
sources DOAJ
author Hai-Hui Yu
Li Kong
Ji-Wen Cui
Hai-Tao Wang
spellingShingle Hai-Hui Yu
Li Kong
Ji-Wen Cui
Hai-Tao Wang
Pentapotassium μ-arsenato-bis(hydroxytetramolybdate) dihydrate
Acta Crystallographica Section E
author_facet Hai-Hui Yu
Li Kong
Ji-Wen Cui
Hai-Tao Wang
author_sort Hai-Hui Yu
title Pentapotassium μ-arsenato-bis(hydroxytetramolybdate) dihydrate
title_short Pentapotassium μ-arsenato-bis(hydroxytetramolybdate) dihydrate
title_full Pentapotassium μ-arsenato-bis(hydroxytetramolybdate) dihydrate
title_fullStr Pentapotassium μ-arsenato-bis(hydroxytetramolybdate) dihydrate
title_full_unstemmed Pentapotassium μ-arsenato-bis(hydroxytetramolybdate) dihydrate
title_sort pentapotassium μ-arsenato-bis(hydroxytetramolybdate) dihydrate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2011-02-01
description The title arsenatomolybdate, K5[Mo8O24(OH)2(AsO4)]·2H2O, which was obtained hydrothermally, features an [AsMo8O28(OH)2]5− anion, which is formed by two Mo4O14(OH) units that are linked by As in a sandwich-like fashion. The overall symmetry of the anion is m2m. The {Mo4O14(OH)} core is composed of two pairs of confacial bioctahedral {Mo2O9} units with two μ4-O atoms which have been characterized as hydroxyl groups. The anions are further interconnected by potassium cations, forming a three-dimensional network structure with the uncoordinated water molecules occupying the channels. The structure is further stabilized by O—H...O hydrogen bonding.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810054176
work_keys_str_mv AT haihuiyu pentapotassiumamp956arsenatobishydroxytetramolybdatedihydrate
AT likong pentapotassiumamp956arsenatobishydroxytetramolybdatedihydrate
AT jiwencui pentapotassiumamp956arsenatobishydroxytetramolybdatedihydrate
AT haitaowang pentapotassiumamp956arsenatobishydroxytetramolybdatedihydrate
_version_ 1725066782206590976

Similar Items