Ambiphilic boron in 1,4,2,5-diazadiborinine
Boranes are archetypal Lewis acids owing to an empty p-orbital on the boron, although Lewis basic tricoordinate boranes have been developed too. Here, the authors report an annulated 1,4,2,5-diazadiborinine derivative with boron atoms that exhibit both Lewis acidic and basic properties.
Main Authors: | Baolin Wang, Yongxin Li, Rakesh Ganguly, Hajime Hirao, Rei Kinjo |
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Format: | Article |
Language: | English |
Published: |
Nature Publishing Group
2016-06-01
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Series: | Nature Communications |
Online Access: | https://doi.org/10.1038/ncomms11871 |
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