Propane-1,3-diaminium bis(perchlorate)–18-crown-6 (1/2)

In the title compound, C3H12N22+·2ClO4−·2C12H24O6, the central C atom of the propane-1,3-diammonium cation is located on a twofold rotation axis and the two terminal –NH3 groups insert into the crown rings through N—H...O hydrogen b...

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Bibliographic Details
Main Author: Min-Min Zhao
Format: Article
Language:English
Published: International Union of Crystallography 2012-02-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811056248
Description
Summary:In the title compound, C3H12N22+·2ClO4−·2C12H24O6, the central C atom of the propane-1,3-diammonium cation is located on a twofold rotation axis and the two terminal –NH3 groups insert into the crown rings through N—H...O hydrogen bonding, resulting in the formation of a 1:2 supramolecular [(C3H12N2)·(C12H24O6)2]+ complex. The perchlorate anion links with the supramolecular complex via weak C—H...O hydrogen bonding.
ISSN:1600-5368