Dibromido(2,9-dimethyl-1,10-phenanthroline-κ2N,N′)(dimethyl sulfoxide-κO)cadmium

Dibromido(2,9-dimethyl-1,10-phenanthroline-κ2N,N′)(dimethyl sulfoxide-κO)cadmium

In the molecule of the title compound, [CdBr2(C14H12N2)(C2H6OS)], the CdII atom is five-coordinated in a distorted trigonal–bipyramidal configuration by two N atoms from a 2,9-dimethyl-1,10-phenanthroline ligand, one O atom from a dimethyl sulfoxide ligand and two Br atoms. In the crys...

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Main Author: Khadijeh Moghanlou
Format: Article
Language:English
Published: International Union of Crystallography 2013-01-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812050106
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spelling doaj-0dcbe7a7bcef4ff5aaa022e17b6cef112020-11-25T01:56:47ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682013-01-01691m49m4910.1107/S1600536812050106Dibromido(2,9-dimethyl-1,10-phenanthroline-κ2N,N′)(dimethyl sulfoxide-κO)cadmiumKhadijeh MoghanlouIn the molecule of the title compound, [CdBr2(C14H12N2)(C2H6OS)], the CdII atom is five-coordinated in a distorted trigonal–bipyramidal configuration by two N atoms from a 2,9-dimethyl-1,10-phenanthroline ligand, one O atom from a dimethyl sulfoxide ligand and two Br atoms. In the crystal, π–π contacts between the pyridine and benzene rings [centroid–centroid distances = 3.710 (5), 3.711 (6) and 3.627 (5) Å] stabilize the structure.http://scripts.iucr.org/cgi-bin/paper?S1600536812050106
collection DOAJ
language English
format Article
sources DOAJ
author Khadijeh Moghanlou
spellingShingle Khadijeh Moghanlou
Dibromido(2,9-dimethyl-1,10-phenanthroline-κ2N,N′)(dimethyl sulfoxide-κO)cadmium
Acta Crystallographica Section E
author_facet Khadijeh Moghanlou
author_sort Khadijeh Moghanlou
title Dibromido(2,9-dimethyl-1,10-phenanthroline-κ2N,N′)(dimethyl sulfoxide-κO)cadmium
title_short Dibromido(2,9-dimethyl-1,10-phenanthroline-κ2N,N′)(dimethyl sulfoxide-κO)cadmium
title_full Dibromido(2,9-dimethyl-1,10-phenanthroline-κ2N,N′)(dimethyl sulfoxide-κO)cadmium
title_fullStr Dibromido(2,9-dimethyl-1,10-phenanthroline-κ2N,N′)(dimethyl sulfoxide-κO)cadmium
title_full_unstemmed Dibromido(2,9-dimethyl-1,10-phenanthroline-κ2N,N′)(dimethyl sulfoxide-κO)cadmium
title_sort dibromido(2,9-dimethyl-1,10-phenanthroline-κ2n,n′)(dimethyl sulfoxide-κo)cadmium
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2013-01-01
description In the molecule of the title compound, [CdBr2(C14H12N2)(C2H6OS)], the CdII atom is five-coordinated in a distorted trigonal–bipyramidal configuration by two N atoms from a 2,9-dimethyl-1,10-phenanthroline ligand, one O atom from a dimethyl sulfoxide ligand and two Br atoms. In the crystal, π–π contacts between the pyridine and benzene rings [centroid–centroid distances = 3.710 (5), 3.711 (6) and 3.627 (5) Å] stabilize the structure.
url http://scripts.iucr.org/cgi-bin/paper?S1600536812050106
work_keys_str_mv AT khadijehmoghanlou dibromido29dimethyl110phenanthrolineamp9542nnamp8242dimethylsulfoxideamp954ocadmium
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