Di-μ-chromato-κ4O:O′-bis[bis(phenanthroline-κ2N,N′)cadmium(II)] dihydrate

Di-μ-chromato-κ4O:O′-bis[bis(phenanthroline-κ2N,N′)cadmium(II)] dihydrate

In the title compound, [Cd2Cr2O8(C12H8N2)4]·2H2O, which was obtained by hydrothermal reaction of CdCO3 and phenanthroline with K2CrO4 at 393 K, two distorted Cd(N4O2) octahedra are linked through μ2-bridging chromate anions, forming a centrosymmetric tetranucl...

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Main Authors: Hai-Xing Liu, Fang-Fang Jian, Jing Wang
Format: Article
Language:English
Published: International Union of Crystallography 2009-04-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S160053680900823X
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spelling doaj-0dcfe21b4e65448380c2f095f9fed3cc2020-11-25T00:22:23ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-04-01654m392m39310.1107/S160053680900823XDi-μ-chromato-κ4O:O′-bis[bis(phenanthroline-κ2N,N′)cadmium(II)] dihydrateHai-Xing LiuFang-Fang JianJing WangIn the title compound, [Cd2Cr2O8(C12H8N2)4]·2H2O, which was obtained by hydrothermal reaction of CdCO3 and phenanthroline with K2CrO4 at 393 K, two distorted Cd(N4O2) octahedra are linked through μ2-bridging chromate anions, forming a centrosymmetric tetranuclear eight-membered ring complex. The water molecules link the chromate O atoms via intermolecular O—H...O hydrogen bonds. These aggregates pack to a three-dimensional network through weak intermolecular C—H...O and C—H...π hydrogen-bonding contacts. http://scripts.iucr.org/cgi-bin/paper?S160053680900823X
collection DOAJ
language English
format Article
sources DOAJ
author Hai-Xing Liu
Fang-Fang Jian
Jing Wang
spellingShingle Hai-Xing Liu
Fang-Fang Jian
Jing Wang
Di-μ-chromato-κ4O:O′-bis[bis(phenanthroline-κ2N,N′)cadmium(II)] dihydrate
Acta Crystallographica Section E
author_facet Hai-Xing Liu
Fang-Fang Jian
Jing Wang
author_sort Hai-Xing Liu
title Di-μ-chromato-κ4O:O′-bis[bis(phenanthroline-κ2N,N′)cadmium(II)] dihydrate
title_short Di-μ-chromato-κ4O:O′-bis[bis(phenanthroline-κ2N,N′)cadmium(II)] dihydrate
title_full Di-μ-chromato-κ4O:O′-bis[bis(phenanthroline-κ2N,N′)cadmium(II)] dihydrate
title_fullStr Di-μ-chromato-κ4O:O′-bis[bis(phenanthroline-κ2N,N′)cadmium(II)] dihydrate
title_full_unstemmed Di-μ-chromato-κ4O:O′-bis[bis(phenanthroline-κ2N,N′)cadmium(II)] dihydrate
title_sort di-μ-chromato-κ4o:o′-bis[bis(phenanthroline-κ2n,n′)cadmium(ii)] dihydrate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-04-01
description In the title compound, [Cd2Cr2O8(C12H8N2)4]·2H2O, which was obtained by hydrothermal reaction of CdCO3 and phenanthroline with K2CrO4 at 393 K, two distorted Cd(N4O2) octahedra are linked through μ2-bridging chromate anions, forming a centrosymmetric tetranuclear eight-membered ring complex. The water molecules link the chromate O atoms via intermolecular O—H...O hydrogen bonds. These aggregates pack to a three-dimensional network through weak intermolecular C—H...O and C—H...π hydrogen-bonding contacts.
url http://scripts.iucr.org/cgi-bin/paper?S160053680900823X
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AT fangfangjian diamp956chromatoamp9544ooamp8242bisbisphenanthrolineamp9542nnamp8242cadmiumiidihydrate
AT jingwang diamp956chromatoamp9544ooamp8242bisbisphenanthrolineamp9542nnamp8242cadmiumiidihydrate
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