Hierarchy of bond stiffnesses within icosahedral-based gold clusters protected by thiolates

The hierarchy of bond stiffness may contribute to the thermal properties of metal clusters. Here, the authors use X-ray absorption spectroscopy to study the stiffness of the gold–gold and gold–sulfur bonds in a series of thiolate-protected, icosahedral-based gold clusters.

Bibliographic Details
Main Authors:	Seiji Yamazoe, Shinjiro Takano, Wataru Kurashige, Toshihiko Yokoyama, Kiyofumi Nitta, Yuichi Negishi, Tatsuya Tsukuda
Format:	Article
Language:	English
Published:	Nature Publishing Group 2016-01-01
Series:	Nature Communications
Online Access:	https://doi.org/10.1038/ncomms10414

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spelling	doaj-0df2f791d40547c4b19af8ed619534262021-05-11T10:36:01ZengNature Publishing GroupNature Communications2041-17232016-01-01711710.1038/ncomms10414Hierarchy of bond stiffnesses within icosahedral-based gold clusters protected by thiolatesSeiji Yamazoe0Shinjiro Takano1Wataru Kurashige2Toshihiko Yokoyama3Kiyofumi Nitta4Yuichi Negishi5Tatsuya Tsukuda6Department of Chemistry, School of Science, The University of TokyoDepartment of Chemistry, School of Science, The University of TokyoDepartment of Applied Chemistry, Faculty of Science, Tokyo University of ScienceDepartment of Materials Molecular Science, Institute for Molecular Science, MyodaijiJapan Synchrotron Radiation Research InstituteDepartment of Applied Chemistry, Faculty of Science, Tokyo University of ScienceDepartment of Chemistry, School of Science, The University of TokyoThe hierarchy of bond stiffness may contribute to the thermal properties of metal clusters. Here, the authors use X-ray absorption spectroscopy to study the stiffness of the gold–gold and gold–sulfur bonds in a series of thiolate-protected, icosahedral-based gold clusters.https://doi.org/10.1038/ncomms10414
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Seiji Yamazoe Shinjiro Takano Wataru Kurashige Toshihiko Yokoyama Kiyofumi Nitta Yuichi Negishi Tatsuya Tsukuda
spellingShingle	Seiji Yamazoe Shinjiro Takano Wataru Kurashige Toshihiko Yokoyama Kiyofumi Nitta Yuichi Negishi Tatsuya Tsukuda Hierarchy of bond stiffnesses within icosahedral-based gold clusters protected by thiolates Nature Communications
author_facet	Seiji Yamazoe Shinjiro Takano Wataru Kurashige Toshihiko Yokoyama Kiyofumi Nitta Yuichi Negishi Tatsuya Tsukuda
author_sort	Seiji Yamazoe
title	Hierarchy of bond stiffnesses within icosahedral-based gold clusters protected by thiolates
title_short	Hierarchy of bond stiffnesses within icosahedral-based gold clusters protected by thiolates
title_full	Hierarchy of bond stiffnesses within icosahedral-based gold clusters protected by thiolates
title_fullStr	Hierarchy of bond stiffnesses within icosahedral-based gold clusters protected by thiolates
title_full_unstemmed	Hierarchy of bond stiffnesses within icosahedral-based gold clusters protected by thiolates
title_sort	hierarchy of bond stiffnesses within icosahedral-based gold clusters protected by thiolates
publisher	Nature Publishing Group
series	Nature Communications
issn	2041-1723
publishDate	2016-01-01
description	The hierarchy of bond stiffness may contribute to the thermal properties of metal clusters. Here, the authors use X-ray absorption spectroscopy to study the stiffness of the gold–gold and gold–sulfur bonds in a series of thiolate-protected, icosahedral-based gold clusters.
url	https://doi.org/10.1038/ncomms10414
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Hierarchy of bond stiffnesses within icosahedral-based gold clusters protected by thiolates

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