{6-[(2-Anilinoethyl)iminomethyl]-2-ethoxyphenolato}(thiocyanato-κN)copper(II)
In the title complex, [Cu(C17H19N2O2)(NCS)], the CuII atom is chelated by the phenolate O atom, the imine N atom and the amine N atom of the N,N′,O-tridentate 2-ethoxy-6-[(2-anilinoethyl)iminomethyl]phenolate ligand, and by the N atom of a thiocyanate anion, forming a distorted CuON3 s...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2010-04-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810010305 |
| Summary: | In the title complex, [Cu(C17H19N2O2)(NCS)], the CuII atom is chelated by the phenolate O atom, the imine N atom and the amine N atom of the N,N′,O-tridentate 2-ethoxy-6-[(2-anilinoethyl)iminomethyl]phenolate ligand, and by the N atom of a thiocyanate anion, forming a distorted CuON3 square-planar geometry. The dihedral angle between the aromatic rings of the ligand is 67.9 (4)°. In the crystal, inversion dimers linked by pairs of N—H...O hydrogen bonds occur, generating R22(8) loops. |
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| ISSN: | 1600-5368 |