{6-[(2-Anilinoethyl)iminomethyl]-2-ethoxyphenolato}(thiocyanato-κN)copper(II)
In the title complex, [Cu(C17H19N2O2)(NCS)], the CuII atom is chelated by the phenolate O atom, the imine N atom and the amine N atom of the N,N′,O-tridentate 2-ethoxy-6-[(2-anilinoethyl)iminomethyl]phenolate ligand, and by the N atom of a thiocyanate anion, forming a distorted CuON3 s...
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| Language: | English |
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International Union of Crystallography
2010-04-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810010305 |
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doaj-0e5f73e90eb1418fa8ccc3ac046306cf2020-11-25T02:24:30ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-04-01664m445m44610.1107/S1600536810010305{6-[(2-Anilinoethyl)iminomethyl]-2-ethoxyphenolato}(thiocyanato-κN)copper(II)Chen-Yi WangJing-Fen LiFeng CaoIn the title complex, [Cu(C17H19N2O2)(NCS)], the CuII atom is chelated by the phenolate O atom, the imine N atom and the amine N atom of the N,N′,O-tridentate 2-ethoxy-6-[(2-anilinoethyl)iminomethyl]phenolate ligand, and by the N atom of a thiocyanate anion, forming a distorted CuON3 square-planar geometry. The dihedral angle between the aromatic rings of the ligand is 67.9 (4)°. In the crystal, inversion dimers linked by pairs of N—H...O hydrogen bonds occur, generating R22(8) loops. http://scripts.iucr.org/cgi-bin/paper?S1600536810010305 |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Chen-Yi Wang Jing-Fen Li Feng Cao |
| spellingShingle |
Chen-Yi Wang Jing-Fen Li Feng Cao {6-[(2-Anilinoethyl)iminomethyl]-2-ethoxyphenolato}(thiocyanato-κN)copper(II) Acta Crystallographica Section E |
| author_facet |
Chen-Yi Wang Jing-Fen Li Feng Cao |
| author_sort |
Chen-Yi Wang |
| title |
{6-[(2-Anilinoethyl)iminomethyl]-2-ethoxyphenolato}(thiocyanato-κN)copper(II) |
| title_short |
{6-[(2-Anilinoethyl)iminomethyl]-2-ethoxyphenolato}(thiocyanato-κN)copper(II) |
| title_full |
{6-[(2-Anilinoethyl)iminomethyl]-2-ethoxyphenolato}(thiocyanato-κN)copper(II) |
| title_fullStr |
{6-[(2-Anilinoethyl)iminomethyl]-2-ethoxyphenolato}(thiocyanato-κN)copper(II) |
| title_full_unstemmed |
{6-[(2-Anilinoethyl)iminomethyl]-2-ethoxyphenolato}(thiocyanato-κN)copper(II) |
| title_sort |
{6-[(2-anilinoethyl)iminomethyl]-2-ethoxyphenolato}(thiocyanato-κn)copper(ii) |
| publisher |
International Union of Crystallography |
| series |
Acta Crystallographica Section E |
| issn |
1600-5368 |
| publishDate |
2010-04-01 |
| description |
In the title complex, [Cu(C17H19N2O2)(NCS)], the CuII atom is chelated by the phenolate O atom, the imine N atom and the amine N atom of the N,N′,O-tridentate 2-ethoxy-6-[(2-anilinoethyl)iminomethyl]phenolate ligand, and by the N atom of a thiocyanate anion, forming a distorted CuON3 square-planar geometry. The dihedral angle between the aromatic rings of the ligand is 67.9 (4)°. In the crystal, inversion dimers linked by pairs of N—H...O hydrogen bonds occur, generating R22(8) loops. |
| url |
http://scripts.iucr.org/cgi-bin/paper?S1600536810010305 |
| work_keys_str_mv |
AT chenyiwang 62anilinoethyliminomethyl2ethoxyphenolatothiocyanatoamp954ncopperii AT jingfenli 62anilinoethyliminomethyl2ethoxyphenolatothiocyanatoamp954ncopperii AT fengcao 62anilinoethyliminomethyl2ethoxyphenolatothiocyanatoamp954ncopperii |
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