catena-Poly[[chloridocopper(II)]bis(μ-3,3′,5,5′-tetramethyl-4,4′-methylenedipyrazole)[chloridocopper(II)]-di-μ-chlorido]
In the title compound, [Cu2Cl4(C11H16N4)]n, the Cu atom is coordinated by two N atoms of two 3,3′,5,5′-tetramethyl-4,4′-methylenedipyrazole (H2mbdpz) ligands, two bridging Cl atoms and one terminal Cl atom, forming a square-pyramidal geometry. The bridging Cl atoms and...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2008-04-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808006909 |
| Summary: | In the title compound, [Cu2Cl4(C11H16N4)]n, the Cu atom is coordinated by two N atoms of two 3,3′,5,5′-tetramethyl-4,4′-methylenedipyrazole (H2mbdpz) ligands, two bridging Cl atoms and one terminal Cl atom, forming a square-pyramidal geometry. The bridging Cl atoms and the bridging H2mbdpz ligands connect the Cu atoms to build up an extended one-dimensional chain. The chains are further connected through N—H...Cl hydrogen bonds to build up a two-dimensional layer in the (011) plane. An inversion centre lies between every pair of adjacent Cu atoms. |
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| ISSN: | 1600-5368 |