Reaction of 1, 1′, 2, 2′-Tetrakis (phenylamino) Ethane with Glyoxal; Synthesis of N2, N3, N7, N8, 1, 4, 5, 6, 9, 10 -Decaphenyltetradecahydro - dipyrazino [2, 3-b: 2, 3-e] Pyrazine-2, 3, 7, 8 -Tetraamine and 5, 6 -bis (ethoxy) -N2, N3, 1, 4 -Tetraphenylhexahydro -2, 3- Pyrazinediamine

Compound N2, N3, N7, N8, 1, 4, 5, 6, 9, 10-decaphenyltetradecahydrodipyrazino [2, 3-b: 2, 3-e] pyrazine-2, 3, 7, 8-tetraamine (4) was prepared by condensation of 1, 1′, 2, 2′-tetrakis (phenylamino) ethane (1d) and glyoxal in EtOH or i-PrOH. Also, reaction of 1d with glyoxal in equimolare in EtOH res...

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Main Authors:	Ali Kakanejadifard, Sayed Morteza Farnia, Issa Kakoiedinaki
Format:	Article
Language:	English
Published:	Iranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECR 2005-06-01
Series:	Iranian Journal of Chemistry & Chemical Engineering
Subjects:	polyazapolycyclic hexabenzyl-hexaaza-isowortzitane tetraazabicyclo [3, 3, 0] octane 1,1′, 2, 2′-tetrakis (phenylamino) ethane n2, n3, n7, n8, 1, 4, 5, 6, 9, 10-decaphenyltetradecahydrod- pyrazino [2, 3-b: 2, 3-e] pyrazine-2, 3, 7, 8-tetraamine 5, 6-bis (ethoxy)-n2, n3, 1, 4-tetraphenylhexa- hydro -2, 3-pyrazinediamine
Online Access:	http://www.ijcce.ac.ir/article_8123_126cf4002691b6b2a4bcd6dd1bded6fe.pdf

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spelling	doaj-0f24426c2dd5461f9342caa109ceefd92020-11-25T02:02:17ZengIranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECRIranian Journal of Chemistry & Chemical Engineering 1021-99861021-99862005-06-0124239428123Reaction of 1, 1′, 2, 2′-Tetrakis (phenylamino) Ethane with Glyoxal; Synthesis of N2, N3, N7, N8, 1, 4, 5, 6, 9, 10 -Decaphenyltetradecahydro - dipyrazino [2, 3-b: 2, 3-e] Pyrazine-2, 3, 7, 8 -Tetraamine and 5, 6 -bis (ethoxy) -N2, N3, 1, 4 -Tetraphenylhexahydro -2, 3- PyrazinediamineAli Kakanejadifard0Sayed Morteza Farnia1Issa Kakoiedinaki2Department of Chemistry, Faculty of Science, University of Lorestan, Khoramabad, I. R. IRANDepartment of Chemistry, Faculty of Science, University of Tehran, I. R. IRANDepartment of Chemistry, Faculty of Science, University of Tehran, I. R. IRANCompound N2, N3, N7, N8, 1, 4, 5, 6, 9, 10-decaphenyltetradecahydrodipyrazino [2, 3-b: 2, 3-e] pyrazine-2, 3, 7, 8-tetraamine (4) was prepared by condensation of 1, 1′, 2, 2′-tetrakis (phenylamino) ethane (1d) and glyoxal in EtOH or i-PrOH. Also, reaction of 1d with glyoxal in equimolare in EtOH resulted 5,6-bis (ethoxy)-N2, N3, 1, 4-tetraphenylhexahydro-2, 3-pyrazinediamine (5). The natures of products are sensitive to acidity, temperature and solvent. In acidic media, 4 and 5 are unstable and degraded to diimine 6.http://www.ijcce.ac.ir/article_8123_126cf4002691b6b2a4bcd6dd1bded6fe.pdfpolyazapolycyclichexabenzyl-hexaaza-isowortzitanetetraazabicyclo [3, 3, 0] octane1,1′, 2, 2′-tetrakis (phenylamino) ethanen2, n3, n7, n8, 1, 4, 5, 6, 9, 10-decaphenyltetradecahydrod- pyrazino [2, 3-b: 2, 3-e] pyrazine-2, 3, 7, 8-tetraamine5, 6-bis (ethoxy)-n2, n3, 1, 4-tetraphenylhexa- hydro -2, 3-pyrazinediamine
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Ali Kakanejadifard Sayed Morteza Farnia Issa Kakoiedinaki
spellingShingle	Ali Kakanejadifard Sayed Morteza Farnia Issa Kakoiedinaki Reaction of 1, 1′, 2, 2′-Tetrakis (phenylamino) Ethane with Glyoxal; Synthesis of N2, N3, N7, N8, 1, 4, 5, 6, 9, 10 -Decaphenyltetradecahydro - dipyrazino [2, 3-b: 2, 3-e] Pyrazine-2, 3, 7, 8 -Tetraamine and 5, 6 -bis (ethoxy) -N2, N3, 1, 4 -Tetraphenylhexahydro -2, 3- Pyrazinediamine Iranian Journal of Chemistry & Chemical Engineering polyazapolycyclic hexabenzyl-hexaaza-isowortzitane tetraazabicyclo [3, 3, 0] octane 1,1′, 2, 2′-tetrakis (phenylamino) ethane n2, n3, n7, n8, 1, 4, 5, 6, 9, 10-decaphenyltetradecahydrod- pyrazino [2, 3-b: 2, 3-e] pyrazine-2, 3, 7, 8-tetraamine 5, 6-bis (ethoxy)-n2, n3, 1, 4-tetraphenylhexa- hydro -2, 3-pyrazinediamine
author_facet	Ali Kakanejadifard Sayed Morteza Farnia Issa Kakoiedinaki
author_sort	Ali Kakanejadifard
title	Reaction of 1, 1′, 2, 2′-Tetrakis (phenylamino) Ethane with Glyoxal; Synthesis of N2, N3, N7, N8, 1, 4, 5, 6, 9, 10 -Decaphenyltetradecahydro - dipyrazino [2, 3-b: 2, 3-e] Pyrazine-2, 3, 7, 8 -Tetraamine and 5, 6 -bis (ethoxy) -N2, N3, 1, 4 -Tetraphenylhexahydro -2, 3- Pyrazinediamine
title_short	Reaction of 1, 1′, 2, 2′-Tetrakis (phenylamino) Ethane with Glyoxal; Synthesis of N2, N3, N7, N8, 1, 4, 5, 6, 9, 10 -Decaphenyltetradecahydro - dipyrazino [2, 3-b: 2, 3-e] Pyrazine-2, 3, 7, 8 -Tetraamine and 5, 6 -bis (ethoxy) -N2, N3, 1, 4 -Tetraphenylhexahydro -2, 3- Pyrazinediamine
title_full	Reaction of 1, 1′, 2, 2′-Tetrakis (phenylamino) Ethane with Glyoxal; Synthesis of N2, N3, N7, N8, 1, 4, 5, 6, 9, 10 -Decaphenyltetradecahydro - dipyrazino [2, 3-b: 2, 3-e] Pyrazine-2, 3, 7, 8 -Tetraamine and 5, 6 -bis (ethoxy) -N2, N3, 1, 4 -Tetraphenylhexahydro -2, 3- Pyrazinediamine
title_fullStr	Reaction of 1, 1′, 2, 2′-Tetrakis (phenylamino) Ethane with Glyoxal; Synthesis of N2, N3, N7, N8, 1, 4, 5, 6, 9, 10 -Decaphenyltetradecahydro - dipyrazino [2, 3-b: 2, 3-e] Pyrazine-2, 3, 7, 8 -Tetraamine and 5, 6 -bis (ethoxy) -N2, N3, 1, 4 -Tetraphenylhexahydro -2, 3- Pyrazinediamine
title_full_unstemmed	Reaction of 1, 1′, 2, 2′-Tetrakis (phenylamino) Ethane with Glyoxal; Synthesis of N2, N3, N7, N8, 1, 4, 5, 6, 9, 10 -Decaphenyltetradecahydro - dipyrazino [2, 3-b: 2, 3-e] Pyrazine-2, 3, 7, 8 -Tetraamine and 5, 6 -bis (ethoxy) -N2, N3, 1, 4 -Tetraphenylhexahydro -2, 3- Pyrazinediamine
title_sort	reaction of 1, 1′, 2, 2′-tetrakis (phenylamino) ethane with glyoxal; synthesis of n2, n3, n7, n8, 1, 4, 5, 6, 9, 10 -decaphenyltetradecahydro - dipyrazino [2, 3-b: 2, 3-e] pyrazine-2, 3, 7, 8 -tetraamine and 5, 6 -bis (ethoxy) -n2, n3, 1, 4 -tetraphenylhexahydro -2, 3- pyrazinediamine
publisher	Iranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECR
series	Iranian Journal of Chemistry & Chemical Engineering
issn	1021-9986 1021-9986
publishDate	2005-06-01
description	Compound N2, N3, N7, N8, 1, 4, 5, 6, 9, 10-decaphenyltetradecahydrodipyrazino [2, 3-b: 2, 3-e] pyrazine-2, 3, 7, 8-tetraamine (4) was prepared by condensation of 1, 1′, 2, 2′-tetrakis (phenylamino) ethane (1d) and glyoxal in EtOH or i-PrOH. Also, reaction of 1d with glyoxal in equimolare in EtOH resulted 5,6-bis (ethoxy)-N2, N3, 1, 4-tetraphenylhexahydro-2, 3-pyrazinediamine (5). The natures of products are sensitive to acidity, temperature and solvent. In acidic media, 4 and 5 are unstable and degraded to diimine 6.
topic	polyazapolycyclic hexabenzyl-hexaaza-isowortzitane tetraazabicyclo [3, 3, 0] octane 1,1′, 2, 2′-tetrakis (phenylamino) ethane n2, n3, n7, n8, 1, 4, 5, 6, 9, 10-decaphenyltetradecahydrod- pyrazino [2, 3-b: 2, 3-e] pyrazine-2, 3, 7, 8-tetraamine 5, 6-bis (ethoxy)-n2, n3, 1, 4-tetraphenylhexa- hydro -2, 3-pyrazinediamine
url	http://www.ijcce.ac.ir/article_8123_126cf4002691b6b2a4bcd6dd1bded6fe.pdf
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Reaction of 1, 1′, 2, 2′-Tetrakis (phenylamino) Ethane with Glyoxal; Synthesis of N2, N3, N7, N8, 1, 4, 5, 6, 9, 10 -Decaphenyltetradecahydro - dipyrazino [2, 3-b: 2, 3-e] Pyrazine-2, 3, 7, 8 -Tetraamine and 5, 6 -bis (ethoxy) -N2, N3, 1, 4 -Tetraphenylhexahydro -2, 3- Pyrazinediamine

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