NEW MX2 AND M’Cl3 (M = Cu, Zn; M’= Y, Dy, Pr; X = Cl, Br) MALEATO COMPLEXES AND TETRAPHENYLANTIMONY FORMIATE ADDUCT: SYNTHESIS AND INFRARED STUDY

NEW MX2 AND M’Cl3 (M = Cu, Zn; M’= Y, Dy, Pr; X = Cl, Br) MALEATO COMPLEXES AND TETRAPHENYLANTIMONY FORMIATE ADDUCT: SYNTHESIS AND INFRARED STUDY

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Eleven complexes and adduct have been synthesized and studied by infrared. The suggested structures are discrete with tetrahedral, trigonal bipyramidal, square planar or octahedral environments around Zn, Ni, Hg and Cu centres – the coordination number is eight in the yttrium compound and ten in th...

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Main Authors: DAME SEYE, CHEIKH ABDOUL KHADIR DIOP, ASSANE TOURE, LIBASSE DIOP
Format: Article
Language:English
Published: Alma Mater Publishing House "Vasile Alecsandri" University of Bacau 2018-03-01
Series:Journal of Engineering Studies and Research
Subjects:
bidentate
bichelating
discrete structure
supramolecular architecture
Online Access:http://www.jesr.ub.ro/1/article/view/66
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spelling doaj-0f747663504d4465814d2813890bf3912021-10-02T19:18:43ZengAlma Mater Publishing House "Vasile Alecsandri" University of BacauJournal of Engineering Studies and Research2068-75592344-49322018-03-0124110.29081/jesr.v24i1.66NEW MX2 AND M’Cl3 (M = Cu, Zn; M’= Y, Dy, Pr; X = Cl, Br) MALEATO COMPLEXES AND TETRAPHENYLANTIMONY FORMIATE ADDUCT: SYNTHESIS AND INFRARED STUDYDAME SEYE0 CHEIKH ABDOUL KHADIR DIOP1ASSANE TOURE 2LIBASSE DIOP3Universite Cheikh Anta Diop, Faculte des Sciences et Techniques, Departement de Chimie, Laboratoire de Chimie Minerale et Analytique, Dakar, Senegal Universite Cheikh Anta Diop, Faculte des Sciences et Techniques, Departement de Chimie, Laboratoire de Chimie Minerale et Analytique, Dakar, Senegal Universite Cheikh Anta Diop, Faculte des Sciences et Techniques, Departement de Chimie, Laboratoire de Chimie Minerale et Analytique, Dakar, Senegal Universite Cheikh Anta Diop, Faculte des Sciences et Techniques, Departement de Chimie, Laboratoire de Chimie Minerale et Analytique, Dakar, Senegal Eleven complexes and adduct have been synthesized and studied by infrared. The suggested structures are discrete with tetrahedral, trigonal bipyramidal, square planar or octahedral environments around Zn, Ni, Hg and Cu centres – the coordination number is eight in the yttrium compound and ten in the dysprosium one-. The maleate anion behaves as a bidentate, a monochelating, a bichelating or a tetradentate ligand while the formiate anion behaves as a monodentate ligand. For compounds containing a protonated amine or a methanol molecule, when hydrogen bonds are considered a supramolecular architecture may be obtained. http://www.jesr.ub.ro/1/article/view/66bidentatebichelatingdiscrete structuresupramolecular architecture
collection DOAJ
language English
format Article
sources DOAJ
author DAME SEYE
CHEIKH ABDOUL KHADIR DIOP
ASSANE TOURE
LIBASSE DIOP
spellingShingle DAME SEYE
CHEIKH ABDOUL KHADIR DIOP
ASSANE TOURE
LIBASSE DIOP
NEW MX2 AND M’Cl3 (M = Cu, Zn; M’= Y, Dy, Pr; X = Cl, Br) MALEATO COMPLEXES AND TETRAPHENYLANTIMONY FORMIATE ADDUCT: SYNTHESIS AND INFRARED STUDY
Journal of Engineering Studies and Research
bidentate
bichelating
discrete structure
supramolecular architecture
author_facet DAME SEYE
CHEIKH ABDOUL KHADIR DIOP
ASSANE TOURE
LIBASSE DIOP
author_sort DAME SEYE
title NEW MX2 AND M’Cl3 (M = Cu, Zn; M’= Y, Dy, Pr; X = Cl, Br) MALEATO COMPLEXES AND TETRAPHENYLANTIMONY FORMIATE ADDUCT: SYNTHESIS AND INFRARED STUDY
title_short NEW MX2 AND M’Cl3 (M = Cu, Zn; M’= Y, Dy, Pr; X = Cl, Br) MALEATO COMPLEXES AND TETRAPHENYLANTIMONY FORMIATE ADDUCT: SYNTHESIS AND INFRARED STUDY
title_full NEW MX2 AND M’Cl3 (M = Cu, Zn; M’= Y, Dy, Pr; X = Cl, Br) MALEATO COMPLEXES AND TETRAPHENYLANTIMONY FORMIATE ADDUCT: SYNTHESIS AND INFRARED STUDY
title_fullStr NEW MX2 AND M’Cl3 (M = Cu, Zn; M’= Y, Dy, Pr; X = Cl, Br) MALEATO COMPLEXES AND TETRAPHENYLANTIMONY FORMIATE ADDUCT: SYNTHESIS AND INFRARED STUDY
title_full_unstemmed NEW MX2 AND M’Cl3 (M = Cu, Zn; M’= Y, Dy, Pr; X = Cl, Br) MALEATO COMPLEXES AND TETRAPHENYLANTIMONY FORMIATE ADDUCT: SYNTHESIS AND INFRARED STUDY
title_sort new mx2 and m’cl3 (m = cu, zn; m’= y, dy, pr; x = cl, br) maleato complexes and tetraphenylantimony formiate adduct: synthesis and infrared study
publisher Alma Mater Publishing House "Vasile Alecsandri" University of Bacau
series Journal of Engineering Studies and Research
issn 2068-7559
2344-4932
publishDate 2018-03-01
description Eleven complexes and adduct have been synthesized and studied by infrared. The suggested structures are discrete with tetrahedral, trigonal bipyramidal, square planar or octahedral environments around Zn, Ni, Hg and Cu centres – the coordination number is eight in the yttrium compound and ten in the dysprosium one-. The maleate anion behaves as a bidentate, a monochelating, a bichelating or a tetradentate ligand while the formiate anion behaves as a monodentate ligand. For compounds containing a protonated amine or a methanol molecule, when hydrogen bonds are considered a supramolecular architecture may be obtained.
topic bidentate
bichelating
discrete structure
supramolecular architecture
url http://www.jesr.ub.ro/1/article/view/66
work_keys_str_mv AT dameseye newmx2andmcl3mcuznmydyprxclbrmaleatocomplexesandtetraphenylantimonyformiateadductsynthesisandinfraredstudy
AT cheikhabdoulkhadirdiop newmx2andmcl3mcuznmydyprxclbrmaleatocomplexesandtetraphenylantimonyformiateadductsynthesisandinfraredstudy
AT assanetoure newmx2andmcl3mcuznmydyprxclbrmaleatocomplexesandtetraphenylantimonyformiateadductsynthesisandinfraredstudy
AT libassediop newmx2andmcl3mcuznmydyprxclbrmaleatocomplexesandtetraphenylantimonyformiateadductsynthesisandinfraredstudy
_version_ 1716847256465833984

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