Novel Organophosphorus Cage Compound Produced by an Unexpected Oxidative Coupling of 1,2,4-Triphosphole: Crystal and Molecular Structures of Two Isomers of Formula P6C4But4 CHSiMe3

Novel Organophosphorus Cage Compound Produced by an Unexpected Oxidative Coupling of 1,2,4-Triphosphole: Crystal and Molecular Structures of Two Isomers of Formula P6C4But4 CHSiMe3

Reaction of Li(P3C2Bu t2 ) with BrCH(SiMe3)2 results in a novel organophosphorus compound with the formula, P6C4Bu t4 CHSiMe3 (1). Compound 1 was fully characterised spectroscopically and its unique molecular structure determined by single crystal X-ray diffraction. Another isomer (2) with a saturat...

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Bibliographic Details
Main Authors: Araujo Maria Helena, Rajão Daniel A., Doriguetto Antonio C., Ellena Javier, Castellano Eduardo E., Hitchcock Peter B., Caliman Vinicius
Format: Article
Language:English
Published: Sociedade Brasileira de Química 2002-01-01
Series:Journal of the Brazilian Chemical Society
Subjects:
organophosphorus compounds
multinuclear NMR
X-ray molecular structure
Online Access:http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532002000500002

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