Effect of Anionic Surfactant on the Thermo Acoustical Properties of Sodium Dodecyl Sulphate in Polyvinyl Alcohol Solution by Ultrasonic Method

The interaction of sodium dodecyl sulphate (SDS) / poly(vinyl alcohol) (PVA) solution was studied by ultrasonic velocity measurements. Ultrasonic velocity, density, viscosity in mixtures of sodium dodecyl sulphate in polyvinyl alcohol was measured over the entire range of composition. From the exper...

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Bibliographic Details
Main Authors: S. Ravichandran, C. Rathika Thaya Kumari
Format: Article
Language:English
Published: Hindawi Limited 2011-01-01
Series:E-Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2011/741971
Description
Summary:The interaction of sodium dodecyl sulphate (SDS) / poly(vinyl alcohol) (PVA) solution was studied by ultrasonic velocity measurements. Ultrasonic velocity, density, viscosity in mixtures of sodium dodecyl sulphate in polyvinyl alcohol was measured over the entire range of composition. From the experimental data, other related thermodynamic parameters, viz., adiabatic compressibility, intermolecular free length, surface tension, relative association, relaxation time, absorption coefficient and internal pressure were calculated. Formations of rods interfere with velocity of ultrasonic waves. Hence the ultrasonic velocity decreases with concentration. These results were interpreted in terms of polymer-surfactant complex reactions.
ISSN:0973-4945
2090-9810