Platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane Complex as a Pt Source for Pt/SnO2 Catalyst
This paper presents new preparation method of Pt/SnO2, an important catalytic system. Besides of its application as a heterogenic industrial catalyst, it is also used as a catalyst in electrochemical processes, especially in fuel cells. Platinum is commonly used as an anode catalyst in low temperatu...
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doaj-124c5001ff5044d691aaf00a6396a4b82020-11-24T22:08:43ZengHindawi LimitedJournal of Nanomaterials1687-41101687-41292014-01-01201410.1155/2014/275197275197Platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane Complex as a Pt Source for Pt/SnO2 CatalystAgnieszka Martyla0Maciej Kopczyk1Piotr Marciniak2Robert Przekop3Institute of Non-Ferrous Metals Division in Poznan, Central Laboratory of Batteries and Cells, 12 Forteczna Street, 61-362 Poznan, PolandInstitute of Non-Ferrous Metals Division in Poznan, Central Laboratory of Batteries and Cells, 12 Forteczna Street, 61-362 Poznan, PolandPoznan Science and Technology Park of Adam Mickiewicz University Foundation, 46 Rubiez Street, 61-612 Poznan, PolandCentre of Advanced Technologies Adam Mickiewicz University, 6 Grunwaldzka Street, 60-780 Poznan, PolandThis paper presents new preparation method of Pt/SnO2, an important catalytic system. Besides of its application as a heterogenic industrial catalyst, it is also used as a catalyst in electrochemical processes, especially in fuel cells. Platinum is commonly used as an anode catalyst in low temperature fuel cells, fuelled with alcohols of low molecular weight such as methanol. Platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex was used as a precursor of metallic phase. The aim of the research was to obtain a highly active in electrochemical system Pt/SnO2 catalyst with low metal load. Considering small size of Pt crystallites, it should result in high activity of Pt/SnO2 system. The presented method of SnO2 synthesis allows for obtaining support consisting of nanoparticles. The effect of the thermal treatment on activity of Pt/SnO2 gel was demonstrated. The system properties were investigated using TEM, FTIR (ATR), and XRD techniques to describe its thermal structural evolution. The results showed two electrocatalytical activity peaks for drying at a temperature of 430 K and above 650 K.http://dx.doi.org/10.1155/2014/275197 |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Agnieszka Martyla Maciej Kopczyk Piotr Marciniak Robert Przekop |
spellingShingle |
Agnieszka Martyla Maciej Kopczyk Piotr Marciniak Robert Przekop Platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane Complex as a Pt Source for Pt/SnO2 Catalyst Journal of Nanomaterials |
author_facet |
Agnieszka Martyla Maciej Kopczyk Piotr Marciniak Robert Przekop |
author_sort |
Agnieszka Martyla |
title |
Platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane Complex as a Pt Source for Pt/SnO2 Catalyst |
title_short |
Platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane Complex as a Pt Source for Pt/SnO2 Catalyst |
title_full |
Platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane Complex as a Pt Source for Pt/SnO2 Catalyst |
title_fullStr |
Platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane Complex as a Pt Source for Pt/SnO2 Catalyst |
title_full_unstemmed |
Platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane Complex as a Pt Source for Pt/SnO2 Catalyst |
title_sort |
platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex as a pt source for pt/sno2 catalyst |
publisher |
Hindawi Limited |
series |
Journal of Nanomaterials |
issn |
1687-4110 1687-4129 |
publishDate |
2014-01-01 |
description |
This paper presents new preparation method of Pt/SnO2, an important catalytic system. Besides of its application as a heterogenic industrial catalyst, it is also used as a catalyst in electrochemical processes, especially in fuel cells. Platinum is commonly used as an anode catalyst in low temperature fuel cells, fuelled with alcohols of low molecular weight such as methanol. Platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex was used as a precursor of metallic phase. The aim of the research was to obtain a highly active in electrochemical system Pt/SnO2 catalyst with low metal load. Considering small size of Pt crystallites, it should result in high activity of Pt/SnO2 system. The presented method of SnO2 synthesis allows for obtaining support consisting of nanoparticles. The effect of the thermal treatment on activity of Pt/SnO2 gel was demonstrated. The system properties were investigated using TEM, FTIR (ATR), and XRD techniques to describe its thermal structural evolution. The results showed two electrocatalytical activity peaks for drying at a temperature of 430 K and above 650 K. |
url |
http://dx.doi.org/10.1155/2014/275197 |
work_keys_str_mv |
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