cis-Dichlorido[2-methyl-8-(pyridin-2-ylmethoxy)quinoline-κ3N,O,N′](triphenylphosphane-κP)ruthenium(II) methanol monosolvate

cis-Dichlorido[2-methyl-8-(pyridin-2-ylmethoxy)quinoline-κ3N,O,N′](triphenylphosphane-κP)ruthenium(II) methanol monosolvate

In the structure of the title compound, [RuCl2(C16H14N2O)(C18H15P)]·CH3OH, he RuII ion shows a slightly distorted octahedral coordination by two N atoms and one O atom from the 2-methyl-8-(pyridin-2-ylmethoxy)quinoline acting as an N,O,N′-tridentate ligand, two Cl atoms, a...

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Main Authors: Qing-Yang Du, Yu Li, Hui-Jun Xu
Format: Article
Language:English
Published: International Union of Crystallography 2010-12-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810047033
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spelling doaj-12692c542eee4ce9ac3bfc3103462ab72020-11-25T00:53:40ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-12-016612m1679m167910.1107/S1600536810047033cis-Dichlorido[2-methyl-8-(pyridin-2-ylmethoxy)quinoline-κ3N,O,N′](triphenylphosphane-κP)ruthenium(II) methanol monosolvateQing-Yang DuYu LiHui-Jun XuIn the structure of the title compound, [RuCl2(C16H14N2O)(C18H15P)]·CH3OH, he RuII ion shows a slightly distorted octahedral coordination by two N atoms and one O atom from the 2-methyl-8-(pyridin-2-ylmethoxy)quinoline acting as an N,O,N′-tridentate ligand, two Cl atoms, and one P atom from a PPh3 ligand. The two Cl atoms adopt a cis arrangement with the PPh3 ligand trans to one Cl atom. The N,O,N′-tridentate ligand occupies a mer position in the coordination sphere. http://scripts.iucr.org/cgi-bin/paper?S1600536810047033
collection DOAJ
language English
format Article
sources DOAJ
author Qing-Yang Du
Yu Li
Hui-Jun Xu
spellingShingle Qing-Yang Du
Yu Li
Hui-Jun Xu
cis-Dichlorido[2-methyl-8-(pyridin-2-ylmethoxy)quinoline-κ3N,O,N′](triphenylphosphane-κP)ruthenium(II) methanol monosolvate
Acta Crystallographica Section E
author_facet Qing-Yang Du
Yu Li
Hui-Jun Xu
author_sort Qing-Yang Du
title cis-Dichlorido[2-methyl-8-(pyridin-2-ylmethoxy)quinoline-κ3N,O,N′](triphenylphosphane-κP)ruthenium(II) methanol monosolvate
title_short cis-Dichlorido[2-methyl-8-(pyridin-2-ylmethoxy)quinoline-κ3N,O,N′](triphenylphosphane-κP)ruthenium(II) methanol monosolvate
title_full cis-Dichlorido[2-methyl-8-(pyridin-2-ylmethoxy)quinoline-κ3N,O,N′](triphenylphosphane-κP)ruthenium(II) methanol monosolvate
title_fullStr cis-Dichlorido[2-methyl-8-(pyridin-2-ylmethoxy)quinoline-κ3N,O,N′](triphenylphosphane-κP)ruthenium(II) methanol monosolvate
title_full_unstemmed cis-Dichlorido[2-methyl-8-(pyridin-2-ylmethoxy)quinoline-κ3N,O,N′](triphenylphosphane-κP)ruthenium(II) methanol monosolvate
title_sort cis-dichlorido[2-methyl-8-(pyridin-2-ylmethoxy)quinoline-κ3n,o,n′](triphenylphosphane-κp)ruthenium(ii) methanol monosolvate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-12-01
description In the structure of the title compound, [RuCl2(C16H14N2O)(C18H15P)]·CH3OH, he RuII ion shows a slightly distorted octahedral coordination by two N atoms and one O atom from the 2-methyl-8-(pyridin-2-ylmethoxy)quinoline acting as an N,O,N′-tridentate ligand, two Cl atoms, and one P atom from a PPh3 ligand. The two Cl atoms adopt a cis arrangement with the PPh3 ligand trans to one Cl atom. The N,O,N′-tridentate ligand occupies a mer position in the coordination sphere.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810047033
work_keys_str_mv AT qingyangdu cisdichlorido2methyl8pyridin2ylmethoxyquinolineamp9543nonamp8242triphenylphosphaneamp954prutheniumiimethanolmonosolvate
AT yuli cisdichlorido2methyl8pyridin2ylmethoxyquinolineamp9543nonamp8242triphenylphosphaneamp954prutheniumiimethanolmonosolvate
AT huijunxu cisdichlorido2methyl8pyridin2ylmethoxyquinolineamp9543nonamp8242triphenylphosphaneamp954prutheniumiimethanolmonosolvate
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