Effect of Electric Current Pulse on Microstructure and Corrosion Resistance of Hypereutectic High Chromium Cast Iron

The effect of electric current pulse on the microstructure and corrosion resistance of hypereutectic high chromium cast iron was explored. The morphology of carbides in solidification microstructure was observed by an optical microscope and a scanning electron microscope and the composition was dete...

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Main Authors: Haiyang Lv, Rongfeng Zhou, Lu Li, Haitao Ni, Jiang Zhu, Tong Feng
Format: Article
Language:English
Published: MDPI AG 2018-11-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/11/11/2220
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spelling doaj-1335d6155a5b4af396fa414de1b4cd762020-11-24T20:49:10ZengMDPI AGMaterials1996-19442018-11-011111222010.3390/ma11112220ma11112220Effect of Electric Current Pulse on Microstructure and Corrosion Resistance of Hypereutectic High Chromium Cast IronHaiyang Lv0Rongfeng Zhou1Lu Li2Haitao Ni3Jiang Zhu4Tong Feng5College of Materials and Chemical Engineering, Chongqing University of Arts and Sciences, Chongqing 402160, ChinaCollege of Materials Science and Engineering, Kunming University of Science and Technology, Kunming 650093, ChinaCollege of Materials Science and Engineering, Kunming University of Science and Technology, Kunming 650093, ChinaCollege of Materials and Chemical Engineering, Chongqing University of Arts and Sciences, Chongqing 402160, ChinaCollege of Materials and Chemical Engineering, Chongqing University of Arts and Sciences, Chongqing 402160, ChinaResearch Institute for New Materials Technology, Chongqing University of Arts and Sciences, Chongqing 402160, ChinaThe effect of electric current pulse on the microstructure and corrosion resistance of hypereutectic high chromium cast iron was explored. The morphology of carbides in solidification microstructure was observed by an optical microscope and a scanning electron microscope and the composition was determined by an electron probe micro-analyzer. The microhardness of primary carbides and corrosion resistance of samples were also compared. Under the active of electric current pulse, the microstructure of hypereutectic high chromium cast iron was homogenized and its performance improved accordingly. On treatment by electric current, the morphology of primary carbides changed from thick long rods to hexagonal blocks or granular structures. The interlayer spacing of eutectic carbide decreased from ~26.3 &#956;m to ~17.8 &#956;m. Size statistics showed that the average diameter of primary carbide decreased from ~220 &#956;m to ~60 &#956;m. As a result, microhardness increased from 1412 HV to 1511 HV. No obvious microcrack propagation was found at the microindentation sites. The average length of microcracks decreased from ~20.7 &#956;m to ~5.7 &#956;m. Furthermore, corrosion resistance was remarkably enhanced. The average corrosion rate decreased from 2.65 mg/cm<sup>2</sup>&#183;h to 1.74 mg/cm<sup>2</sup>&#183;h after pulse current treatment.https://www.mdpi.com/1996-1944/11/11/2220electric current pulsehigh chromium cast ironprimary carbidemorphologycorrosion resistance
collection DOAJ
language English
format Article
sources DOAJ
author Haiyang Lv
Rongfeng Zhou
Lu Li
Haitao Ni
Jiang Zhu
Tong Feng
spellingShingle Haiyang Lv
Rongfeng Zhou
Lu Li
Haitao Ni
Jiang Zhu
Tong Feng
Effect of Electric Current Pulse on Microstructure and Corrosion Resistance of Hypereutectic High Chromium Cast Iron
Materials
electric current pulse
high chromium cast iron
primary carbide
morphology
corrosion resistance
author_facet Haiyang Lv
Rongfeng Zhou
Lu Li
Haitao Ni
Jiang Zhu
Tong Feng
author_sort Haiyang Lv
title Effect of Electric Current Pulse on Microstructure and Corrosion Resistance of Hypereutectic High Chromium Cast Iron
title_short Effect of Electric Current Pulse on Microstructure and Corrosion Resistance of Hypereutectic High Chromium Cast Iron
title_full Effect of Electric Current Pulse on Microstructure and Corrosion Resistance of Hypereutectic High Chromium Cast Iron
title_fullStr Effect of Electric Current Pulse on Microstructure and Corrosion Resistance of Hypereutectic High Chromium Cast Iron
title_full_unstemmed Effect of Electric Current Pulse on Microstructure and Corrosion Resistance of Hypereutectic High Chromium Cast Iron
title_sort effect of electric current pulse on microstructure and corrosion resistance of hypereutectic high chromium cast iron
publisher MDPI AG
series Materials
issn 1996-1944
publishDate 2018-11-01
description The effect of electric current pulse on the microstructure and corrosion resistance of hypereutectic high chromium cast iron was explored. The morphology of carbides in solidification microstructure was observed by an optical microscope and a scanning electron microscope and the composition was determined by an electron probe micro-analyzer. The microhardness of primary carbides and corrosion resistance of samples were also compared. Under the active of electric current pulse, the microstructure of hypereutectic high chromium cast iron was homogenized and its performance improved accordingly. On treatment by electric current, the morphology of primary carbides changed from thick long rods to hexagonal blocks or granular structures. The interlayer spacing of eutectic carbide decreased from ~26.3 &#956;m to ~17.8 &#956;m. Size statistics showed that the average diameter of primary carbide decreased from ~220 &#956;m to ~60 &#956;m. As a result, microhardness increased from 1412 HV to 1511 HV. No obvious microcrack propagation was found at the microindentation sites. The average length of microcracks decreased from ~20.7 &#956;m to ~5.7 &#956;m. Furthermore, corrosion resistance was remarkably enhanced. The average corrosion rate decreased from 2.65 mg/cm<sup>2</sup>&#183;h to 1.74 mg/cm<sup>2</sup>&#183;h after pulse current treatment.
topic electric current pulse
high chromium cast iron
primary carbide
morphology
corrosion resistance
url https://www.mdpi.com/1996-1944/11/11/2220
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