Evolution of the electrochemical interface in sodium ion batteries with ether electrolytes

Sodium ion batteries are known to benefit from the use of ether electrolytes. Here the authors reveal the origin showing that the energy barrier of charge transfer at the electrolyte/electrode interface dominates the interfacial electrochemical characteristics and is favorably small.

Bibliographic Details
Main Authors:	Kaikai Li, Jun Zhang, Dongmei Lin, Da-Wei Wang, Baohua Li, Wei Lv, Sheng Sun, Yan-Bing He, Feiyu Kang, Quan-Hong Yang, Limin Zhou, Tong-Yi Zhang
Format:	Article
Language:	English
Published:	Nature Publishing Group 2019-02-01
Series:	Nature Communications
Online Access:	https://doi.org/10.1038/s41467-019-08506-5

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spelling	doaj-136ae9dd74d8473b87c4b3c344279d7c2021-05-11T11:51:06ZengNature Publishing GroupNature Communications2041-17232019-02-0110111010.1038/s41467-019-08506-5Evolution of the electrochemical interface in sodium ion batteries with ether electrolytesKaikai Li0Jun Zhang1Dongmei Lin2Da-Wei Wang3Baohua Li4Wei Lv5Sheng Sun6Yan-Bing He7Feiyu Kang8Quan-Hong Yang9Limin Zhou10Tong-Yi Zhang11Shenzhen Environmental Science and New Energy Technology Engineering Laboratory, Tsinghua-Berkeley Shenzhen Institute (TBSI), Tsinghua UniversityShenzhen Environmental Science and New Energy Technology Engineering Laboratory, Tsinghua-Berkeley Shenzhen Institute (TBSI), Tsinghua UniversityDepartment of Mechanical Engineering, The Hong Kong Polytechnic UniversitySchool of Chemical Engineering, The University of New South WalesShenzhen Key Laboratory for Graphene-based materials and Engineering Laboratory for Functionalized Carbon Materials, Graduate School at Shenzhen, Tsinghua UniversityShenzhen Key Laboratory for Graphene-based materials and Engineering Laboratory for Functionalized Carbon Materials, Graduate School at Shenzhen, Tsinghua UniversityMaterials Genome Institute, Shanghai UniversityShenzhen Key Laboratory for Graphene-based materials and Engineering Laboratory for Functionalized Carbon Materials, Graduate School at Shenzhen, Tsinghua UniversityShenzhen Environmental Science and New Energy Technology Engineering Laboratory, Tsinghua-Berkeley Shenzhen Institute (TBSI), Tsinghua UniversityShenzhen Environmental Science and New Energy Technology Engineering Laboratory, Tsinghua-Berkeley Shenzhen Institute (TBSI), Tsinghua UniversityInterdisciplinary Division of Aeronautical and Aviation Engineering, The Hong Kong Polytechnic UniversityMaterials Genome Institute, Shanghai UniversitySodium ion batteries are known to benefit from the use of ether electrolytes. Here the authors reveal the origin showing that the energy barrier of charge transfer at the electrolyte/electrode interface dominates the interfacial electrochemical characteristics and is favorably small.https://doi.org/10.1038/s41467-019-08506-5
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Kaikai Li Jun Zhang Dongmei Lin Da-Wei Wang Baohua Li Wei Lv Sheng Sun Yan-Bing He Feiyu Kang Quan-Hong Yang Limin Zhou Tong-Yi Zhang
spellingShingle	Kaikai Li Jun Zhang Dongmei Lin Da-Wei Wang Baohua Li Wei Lv Sheng Sun Yan-Bing He Feiyu Kang Quan-Hong Yang Limin Zhou Tong-Yi Zhang Evolution of the electrochemical interface in sodium ion batteries with ether electrolytes Nature Communications
author_facet	Kaikai Li Jun Zhang Dongmei Lin Da-Wei Wang Baohua Li Wei Lv Sheng Sun Yan-Bing He Feiyu Kang Quan-Hong Yang Limin Zhou Tong-Yi Zhang
author_sort	Kaikai Li
title	Evolution of the electrochemical interface in sodium ion batteries with ether electrolytes
title_short	Evolution of the electrochemical interface in sodium ion batteries with ether electrolytes
title_full	Evolution of the electrochemical interface in sodium ion batteries with ether electrolytes
title_fullStr	Evolution of the electrochemical interface in sodium ion batteries with ether electrolytes
title_full_unstemmed	Evolution of the electrochemical interface in sodium ion batteries with ether electrolytes
title_sort	evolution of the electrochemical interface in sodium ion batteries with ether electrolytes
publisher	Nature Publishing Group
series	Nature Communications
issn	2041-1723
publishDate	2019-02-01
description	Sodium ion batteries are known to benefit from the use of ether electrolytes. Here the authors reveal the origin showing that the energy barrier of charge transfer at the electrolyte/electrode interface dominates the interfacial electrochemical characteristics and is favorably small.
url	https://doi.org/10.1038/s41467-019-08506-5
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Evolution of the electrochemical interface in sodium ion batteries with ether electrolytes

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