Tris[2-(2H-indazol-2-yl)ethyl]amine

Tris[2-(2H-indazol-2-yl)ethyl]amine

The title tertiary amine, C27H27N7, a potential tripodal ligand for coordination chemistry, crystallizes with the central N atom located on a threefold axis of a trigonal cell. The gauche conformation of the N(amime)—CH2—CH2—N(indazole) chain [torsion angle...

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Main Authors: Saúl Ovalle, Perla Elizondo Martínez, Nancy Pérez Rodríguez, Sylvain Bernès, Marcos Flores-Alamo
Format: Article
Language:English
Published: International Union of Crystallography 2012-06-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812022027
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spelling doaj-13a471057cf54029a0a0cc59099162252020-11-25T00:12:43ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-06-01686o1879o188010.1107/S1600536812022027Tris[2-(2H-indazol-2-yl)ethyl]amineSaúl OvallePerla Elizondo MartínezNancy Pérez RodríguezSylvain BernèsMarcos Flores-AlamoThe title tertiary amine, C27H27N7, a potential tripodal ligand for coordination chemistry, crystallizes with the central N atom located on a threefold axis of a trigonal cell. The gauche conformation of the N(amime)—CH2—CH2—N(indazole) chain [torsion angle = −64.2 (2)°] places the pendant 2H-indazole heterocycles surrounding the symmetry axis, affording a claw-like shaped molecule. Two symmetry-related indazole planes in the molecule make an acute angle of 60.39 (4)°. The lone pair of the tertiary N atom is located inside the cavity, and should thus be inactive (as a ligand). In the crystal, neither significant π–π nor C—H...π interactions between molecules are found.http://scripts.iucr.org/cgi-bin/paper?S1600536812022027
collection DOAJ
language English
format Article
sources DOAJ
author Saúl Ovalle
Perla Elizondo Martínez
Nancy Pérez Rodríguez
Sylvain Bernès
Marcos Flores-Alamo
spellingShingle Saúl Ovalle
Perla Elizondo Martínez
Nancy Pérez Rodríguez
Sylvain Bernès
Marcos Flores-Alamo
Tris[2-(2H-indazol-2-yl)ethyl]amine
Acta Crystallographica Section E
author_facet Saúl Ovalle
Perla Elizondo Martínez
Nancy Pérez Rodríguez
Sylvain Bernès
Marcos Flores-Alamo
author_sort Saúl Ovalle
title Tris[2-(2H-indazol-2-yl)ethyl]amine
title_short Tris[2-(2H-indazol-2-yl)ethyl]amine
title_full Tris[2-(2H-indazol-2-yl)ethyl]amine
title_fullStr Tris[2-(2H-indazol-2-yl)ethyl]amine
title_full_unstemmed Tris[2-(2H-indazol-2-yl)ethyl]amine
title_sort tris[2-(2h-indazol-2-yl)ethyl]amine
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-06-01
description The title tertiary amine, C27H27N7, a potential tripodal ligand for coordination chemistry, crystallizes with the central N atom located on a threefold axis of a trigonal cell. The gauche conformation of the N(amime)—CH2—CH2—N(indazole) chain [torsion angle = −64.2 (2)°] places the pendant 2H-indazole heterocycles surrounding the symmetry axis, affording a claw-like shaped molecule. Two symmetry-related indazole planes in the molecule make an acute angle of 60.39 (4)°. The lone pair of the tertiary N atom is located inside the cavity, and should thus be inactive (as a ligand). In the crystal, neither significant π–π nor C—H...π interactions between molecules are found.
url http://scripts.iucr.org/cgi-bin/paper?S1600536812022027
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AT nancypamp233rezrodramp237guez tris22hindazol2ylethylamine
AT sylvainbernamp232s tris22hindazol2ylethylamine
AT marcosfloresalamo tris22hindazol2ylethylamine
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