Tetrakis(2-amino-6-methylpyridinium) hexachloridobismuthate(III) chloride monohydrate
The asymmetric unit of the title compound, (C6H9N2)4[BiCl6]Cl·H2O, contains four protonated 2-amino-6-methylpyridine (HAMP) cations and two-halves of two [BiCl6]3− anions, together with one water molecule and one chloride anion. The BiIII atoms are hexacoordinated by Cl at...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2009-08-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809025446 |
| Summary: | The asymmetric unit of the title compound, (C6H9N2)4[BiCl6]Cl·H2O, contains four protonated 2-amino-6-methylpyridine (HAMP) cations and two-halves of two [BiCl6]3− anions, together with one water molecule and one chloride anion. The BiIII atoms are hexacoordinated by Cl atoms, forming distorted octahedral geometries. In the crystal structure, intramolecular O—H...Cl and N—H...Cl, and intermolecular O—H...Cl and N—H...O interactions link the molecules into a three-dimensional network. |
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| ISSN: | 1600-5368 |