Polyimide/Ionic Liquid Composite Membranes for Middle and High Temperature Fuel Cell Application: Water Sorption Behavior and Proton Conductivity
Four water insoluble room-temperature protic ionic liquids (PILs) based on the <i>N</i>-alkylimidazolium cation with the alkyl chain length from 1 to 4 and bis(trifluoromethylsulfonyl)imide anion were synthesized and their chemical structure was confirmed by the <sup>1</sup>H...
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doaj-140ee9019b7c47beb842bd149ea5cbac2020-11-25T03:05:54ZengMDPI AGMembranes2077-03752020-04-0110828210.3390/membranes10050082Polyimide/Ionic Liquid Composite Membranes for Middle and High Temperature Fuel Cell Application: Water Sorption Behavior and Proton ConductivityKateryna Fatyeyeva0Sergiy Rogalsky1Stanislav Makhno2Oksana Tarasyuk3Jorge Arturo Soto Puente4Stéphane Marais5Polymères Biopolymères Surfaces (PBS), Normandie University, UNIROUEN, INSA ROUEN, CNRS, 76000 Rouen, FranceInstitute of Bioorganic Chemistry and Petrochemistry, National Academy of Science of Ukraine, 50, Kharkivske Schose, 02160 Kyiv, UkraineChuiko Institute of Surface Chemistry, National Academy of Sciences of Ukraine, 17, General Naumov St., 03164 Kyiv, UkraineInstitute of Bioorganic Chemistry and Petrochemistry, National Academy of Science of Ukraine, 50, Kharkivske Schose, 02160 Kyiv, UkrainePolymères Biopolymères Surfaces (PBS), Normandie University, UNIROUEN, INSA ROUEN, CNRS, 76000 Rouen, FrancePolymères Biopolymères Surfaces (PBS), Normandie University, UNIROUEN, INSA ROUEN, CNRS, 76000 Rouen, FranceFour water insoluble room-temperature protic ionic liquids (PILs) based on the <i>N</i>-alkylimidazolium cation with the alkyl chain length from 1 to 4 and bis(trifluoromethylsulfonyl)imide anion were synthesized and their chemical structure was confirmed by the <sup>1</sup>H NMR and <sup>19</sup>F NMR analysis. PILs were revealed to be thermally stable up to 360 and 400 °C. At the same time, the proton conductivity of PILs was found to be dependent mostly on the temperature and, to a less extent, on the type of the cation, i.e., the increase of the conductivity from ~3 × 10<sup>−4</sup> S/cm at 25 °C to 2 × 10<sup>−2</sup> S/cm at 150 °C was observed. The water vapour sorption capacity of PILs was evaluated as a function of relative humidity and the influence of the alkyl chain length on the phase behaviour in the PIL-water system was discussed. The composite polyimide/PILs membranes were prepared by the PIL immobilization in the porous polymer (Matrimid<sup>®</sup> 5218) film. The composite membranes showed a high level of proton conductivity (~10<sup>−3</sup> S/cm) at elevated temperatures (up to 160 °C). The obtained results reveal that the elaborated composite polyimide/PIL membranes are promising candidates for the application as proton exchange membrane at middle and high temperatures.https://www.mdpi.com/2077-0375/10/5/82porous polyimide membraneionic liquidconductivityvapour sorptionthermal stability |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Kateryna Fatyeyeva Sergiy Rogalsky Stanislav Makhno Oksana Tarasyuk Jorge Arturo Soto Puente Stéphane Marais |
spellingShingle |
Kateryna Fatyeyeva Sergiy Rogalsky Stanislav Makhno Oksana Tarasyuk Jorge Arturo Soto Puente Stéphane Marais Polyimide/Ionic Liquid Composite Membranes for Middle and High Temperature Fuel Cell Application: Water Sorption Behavior and Proton Conductivity Membranes porous polyimide membrane ionic liquid conductivity vapour sorption thermal stability |
author_facet |
Kateryna Fatyeyeva Sergiy Rogalsky Stanislav Makhno Oksana Tarasyuk Jorge Arturo Soto Puente Stéphane Marais |
author_sort |
Kateryna Fatyeyeva |
title |
Polyimide/Ionic Liquid Composite Membranes for Middle and High Temperature Fuel Cell Application: Water Sorption Behavior and Proton Conductivity |
title_short |
Polyimide/Ionic Liquid Composite Membranes for Middle and High Temperature Fuel Cell Application: Water Sorption Behavior and Proton Conductivity |
title_full |
Polyimide/Ionic Liquid Composite Membranes for Middle and High Temperature Fuel Cell Application: Water Sorption Behavior and Proton Conductivity |
title_fullStr |
Polyimide/Ionic Liquid Composite Membranes for Middle and High Temperature Fuel Cell Application: Water Sorption Behavior and Proton Conductivity |
title_full_unstemmed |
Polyimide/Ionic Liquid Composite Membranes for Middle and High Temperature Fuel Cell Application: Water Sorption Behavior and Proton Conductivity |
title_sort |
polyimide/ionic liquid composite membranes for middle and high temperature fuel cell application: water sorption behavior and proton conductivity |
publisher |
MDPI AG |
series |
Membranes |
issn |
2077-0375 |
publishDate |
2020-04-01 |
description |
Four water insoluble room-temperature protic ionic liquids (PILs) based on the <i>N</i>-alkylimidazolium cation with the alkyl chain length from 1 to 4 and bis(trifluoromethylsulfonyl)imide anion were synthesized and their chemical structure was confirmed by the <sup>1</sup>H NMR and <sup>19</sup>F NMR analysis. PILs were revealed to be thermally stable up to 360 and 400 °C. At the same time, the proton conductivity of PILs was found to be dependent mostly on the temperature and, to a less extent, on the type of the cation, i.e., the increase of the conductivity from ~3 × 10<sup>−4</sup> S/cm at 25 °C to 2 × 10<sup>−2</sup> S/cm at 150 °C was observed. The water vapour sorption capacity of PILs was evaluated as a function of relative humidity and the influence of the alkyl chain length on the phase behaviour in the PIL-water system was discussed. The composite polyimide/PILs membranes were prepared by the PIL immobilization in the porous polymer (Matrimid<sup>®</sup> 5218) film. The composite membranes showed a high level of proton conductivity (~10<sup>−3</sup> S/cm) at elevated temperatures (up to 160 °C). The obtained results reveal that the elaborated composite polyimide/PIL membranes are promising candidates for the application as proton exchange membrane at middle and high temperatures. |
topic |
porous polyimide membrane ionic liquid conductivity vapour sorption thermal stability |
url |
https://www.mdpi.com/2077-0375/10/5/82 |
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