Influence of enhanced Asian NO_<i>x</i> emissions on ozone in the upper troposphere and lower stratosphere in chemistry&ndash;climate model simulations

• Main Authors: C. Roy, S. Fadnavis, R. Müller, D. C. Ayantika, F. Ploeger, A. Rap
• Format: Article
• Language: English
• Published: Copernicus Publications 2017-01-01
• Series: Atmospheric Chemistry and Physics
• Online Access: http://www.atmos-chem-phys.net/17/1297/2017/acp-17-1297-2017.pdf

The Asian summer monsoon (ASM) anticyclone is the most pronounced circulation pattern in the upper troposphere and lower stratosphere (UTLS) during northern hemispheric summer. ASM convection plays an important role in efficient vertical transport from the surface to the upper-level anticyclone. In this paper we investigate the potential impact of enhanced anthropogenic nitrogen oxide (NO_<i>x</i>) emissions on the distribution of ozone in the UTLS using the fully coupled aerosol&ndash;chemistry&ndash;climate model, ECHAM5-HAMMOZ. Ozone in the UTLS is influenced both by the convective uplift of ozone precursors and by the uplift of enhanced-NO_<i>x</i>-induced tropospheric ozone anomalies. We performed anthropogenic NO_<i>x</i> emission sensitivity experiments over India and China. In these simulations, covering the years 2000&ndash;2010, anthropogenic NO_<i>x</i> emissions have been increased by 38 % over India and by 73 % over China with respect to the emission base year 2000. These emission increases are comparable to the observed linear trends of 3.8 % per year over India and 7.3 % per year over China during the period 2000 to 2010. Enhanced NO_<i>x</i> emissions over India by 38 % and China by 73 % increase the ozone radiative forcing in the ASM anticyclone (15&ndash;40° N, 60&ndash;120° E) by 16.3 and 78.5 mW m⁻² respectively. These elevated NO_<i>x</i> emissions produce significant warming over the Tibetan Plateau and increase precipitation over India due to a strengthening of the monsoon Hadley circulation. However, increase in NO_<i>x</i> emissions over India by 73 % (similar to the observed increase over China) results in large ozone production over the Indo-Gangetic Plain and Tibetan Plateau. The higher ozone concentrations, in turn, induce a reversed monsoon Hadley circulation and negative precipitation anomalies over India. The associated subsidence suppresses vertical transport of NO_<i>x</i> and ozone into the ASM anticyclone.