A Highly Selective Sensor for Cyanide in Organic Media and on Solid Surfaces
The application of IR 786 perchlorate (IR-786) as a selective optical sensor for cyanide anion in both organic solution (acetonitrile (MeCN), 100%) and solvent-free solid surfaces was demonstrated. In MeCN, IR-786 was selective to two anions in the following order: CN− > OH−. A significant ch...
Main Authors: | , , , , , |
---|---|
Format: | Article |
Language: | English |
Published: |
MDPI AG
2016-02-01
|
Series: | Sensors |
Subjects: | |
Online Access: | http://www.mdpi.com/1424-8220/16/3/271 |
id |
doaj-15474b4868944043b1866acbe2fefe63 |
---|---|
record_format |
Article |
spelling |
doaj-15474b4868944043b1866acbe2fefe632020-11-24T23:55:16ZengMDPI AGSensors1424-82202016-02-0116327110.3390/s16030271s16030271A Highly Selective Sensor for Cyanide in Organic Media and on Solid SurfacesBelygona Barare0Ilknur Babahan1Yousef M. Hijji2Enock Bonyi3Solomon Tadesse4Kadir Aslan5Department of Chemistry, Morgan State University, Baltimore, MD 21251, USADepartment of Chemistry, Morgan State University, Baltimore, MD 21251, USADepartment of Chemistry and Earth Sciences, Qatar University, P.O. Box 2713, Doha, QatarDepartment of Chemistry, Morgan State University, Baltimore, MD 21251, USADepartment of Chemistry, Morgan State University, Baltimore, MD 21251, USADepartment of Chemistry, Morgan State University, Baltimore, MD 21251, USAThe application of IR 786 perchlorate (IR-786) as a selective optical sensor for cyanide anion in both organic solution (acetonitrile (MeCN), 100%) and solvent-free solid surfaces was demonstrated. In MeCN, IR-786 was selective to two anions in the following order: CN− > OH−. A significant change in the characteristic dark green color of IR-786 in MeCN to yellow was observed as a result of nucleophilic addition of CN− to the fluorophore, i.e., formation of IR 786-(CN), which was also verified by a blue shift in the 775 nm absorbance peak to 430 nm. A distinct green fluorescence emission from the IR-786-(CN) in MeCN was also observed, which demonstrated the selectivity of IR-786 towards CN− in MeCN. Fluorescence emission studies of IR-786 showed that the lower detection limit and the sensitivity of IR-786 for CN− in MeCN was 0.5 μM and 0.5 to 8 μM, respectively. The potential use of IR-786 as a solvent-free solid state sensor for the selective sensing and monitoring of CN− in the environment was also demonstrated. On solvent-free solid state surfaces, the sensitivity of the IR-786 to CN− in water samples was in the range of 50–300 μM with minimal interference by OH−.http://www.mdpi.com/1424-8220/16/3/271IR-786anion sensingcyanide sensingcyanine dyesnear-infrared fluorophoresoptical sensorschemical sensors |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Belygona Barare Ilknur Babahan Yousef M. Hijji Enock Bonyi Solomon Tadesse Kadir Aslan |
spellingShingle |
Belygona Barare Ilknur Babahan Yousef M. Hijji Enock Bonyi Solomon Tadesse Kadir Aslan A Highly Selective Sensor for Cyanide in Organic Media and on Solid Surfaces Sensors IR-786 anion sensing cyanide sensing cyanine dyes near-infrared fluorophores optical sensors chemical sensors |
author_facet |
Belygona Barare Ilknur Babahan Yousef M. Hijji Enock Bonyi Solomon Tadesse Kadir Aslan |
author_sort |
Belygona Barare |
title |
A Highly Selective Sensor for Cyanide in Organic Media and on Solid Surfaces |
title_short |
A Highly Selective Sensor for Cyanide in Organic Media and on Solid Surfaces |
title_full |
A Highly Selective Sensor for Cyanide in Organic Media and on Solid Surfaces |
title_fullStr |
A Highly Selective Sensor for Cyanide in Organic Media and on Solid Surfaces |
title_full_unstemmed |
A Highly Selective Sensor for Cyanide in Organic Media and on Solid Surfaces |
title_sort |
highly selective sensor for cyanide in organic media and on solid surfaces |
publisher |
MDPI AG |
series |
Sensors |
issn |
1424-8220 |
publishDate |
2016-02-01 |
description |
The application of IR 786 perchlorate (IR-786) as a selective optical sensor for cyanide anion in both organic solution (acetonitrile (MeCN), 100%) and solvent-free solid surfaces was demonstrated. In MeCN, IR-786 was selective to two anions in the following order: CN− > OH−. A significant change in the characteristic dark green color of IR-786 in MeCN to yellow was observed as a result of nucleophilic addition of CN− to the fluorophore, i.e., formation of IR 786-(CN), which was also verified by a blue shift in the 775 nm absorbance peak to 430 nm. A distinct green fluorescence emission from the IR-786-(CN) in MeCN was also observed, which demonstrated the selectivity of IR-786 towards CN− in MeCN. Fluorescence emission studies of IR-786 showed that the lower detection limit and the sensitivity of IR-786 for CN− in MeCN was 0.5 μM and 0.5 to 8 μM, respectively. The potential use of IR-786 as a solvent-free solid state sensor for the selective sensing and monitoring of CN− in the environment was also demonstrated. On solvent-free solid state surfaces, the sensitivity of the IR-786 to CN− in water samples was in the range of 50–300 μM with minimal interference by OH−. |
topic |
IR-786 anion sensing cyanide sensing cyanine dyes near-infrared fluorophores optical sensors chemical sensors |
url |
http://www.mdpi.com/1424-8220/16/3/271 |
work_keys_str_mv |
AT belygonabarare ahighlyselectivesensorforcyanideinorganicmediaandonsolidsurfaces AT ilknurbabahan ahighlyselectivesensorforcyanideinorganicmediaandonsolidsurfaces AT yousefmhijji ahighlyselectivesensorforcyanideinorganicmediaandonsolidsurfaces AT enockbonyi ahighlyselectivesensorforcyanideinorganicmediaandonsolidsurfaces AT solomontadesse ahighlyselectivesensorforcyanideinorganicmediaandonsolidsurfaces AT kadiraslan ahighlyselectivesensorforcyanideinorganicmediaandonsolidsurfaces AT belygonabarare highlyselectivesensorforcyanideinorganicmediaandonsolidsurfaces AT ilknurbabahan highlyselectivesensorforcyanideinorganicmediaandonsolidsurfaces AT yousefmhijji highlyselectivesensorforcyanideinorganicmediaandonsolidsurfaces AT enockbonyi highlyselectivesensorforcyanideinorganicmediaandonsolidsurfaces AT solomontadesse highlyselectivesensorforcyanideinorganicmediaandonsolidsurfaces AT kadiraslan highlyselectivesensorforcyanideinorganicmediaandonsolidsurfaces |
_version_ |
1725463202133704704 |