Bis(μ-N-benzyl-N-furfuryldithiocarbamato)-1:2κ3S,S′:S′;2:1κ3S,S′:S′-bis[(N-benzyl-N-furfuryldithiocarbamato-κ2S,S′)cadmium]

Bis(μ-N-benzyl-N-furfuryldithiocarbamato)-1:2κ3S,S′:S′;2:1κ3S,S′:S′-bis[(N-benzyl-N-furfuryldithiocarbamato-κ2S,S′)cadmium]

In the centrosymmetric title compound, [Cd2(C13H12NOS2)4], pairs of dithiocarbamate ligands exhibit different structural functions. Each of the terminal ligands is bidentately coordinated to one CdII atom and forms a planar four-membered CS2Cd chelate ring, whereas pairs of the tridentate bridging l...

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Main Authors: Rajni Kant, Vivek K. Gupta, Kamini Kapoor, P. Valarmathi, S. Thirumaran
Format: Article
Language:English
Published: International Union of Crystallography 2012-01-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811051348
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spelling doaj-155492b28afd44c5886f04c7c55677a82020-11-24T21:25:55ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-01-01681m12m1310.1107/S1600536811051348Bis(μ-N-benzyl-N-furfuryldithiocarbamato)-1:2κ3S,S′:S′;2:1κ3S,S′:S′-bis[(N-benzyl-N-furfuryldithiocarbamato-κ2S,S′)cadmium]Rajni KantVivek K. GuptaKamini KapoorP. ValarmathiS. ThirumaranIn the centrosymmetric title compound, [Cd2(C13H12NOS2)4], pairs of dithiocarbamate ligands exhibit different structural functions. Each of the terminal ligands is bidentately coordinated to one CdII atom and forms a planar four-membered CS2Cd chelate ring, whereas pairs of the tridentate bridging ligands link two neighbouring CdII atoms, forming extended eight-membered C2S4Cd2 tricyclic units whose geometry can be approximated by a chair conformation. The coordination polyhedron of the CdII atoms is a distorted square-pyramid. The five-membered furan ring and the benzene ring are disordered over two sets of sites with an occupancy ratio of 0.62 (8):0.38 (8).http://scripts.iucr.org/cgi-bin/paper?S1600536811051348
collection DOAJ
language English
format Article
sources DOAJ
author Rajni Kant
Vivek K. Gupta
Kamini Kapoor
P. Valarmathi
S. Thirumaran
spellingShingle Rajni Kant
Vivek K. Gupta
Kamini Kapoor
P. Valarmathi
S. Thirumaran
Bis(μ-N-benzyl-N-furfuryldithiocarbamato)-1:2κ3S,S′:S′;2:1κ3S,S′:S′-bis[(N-benzyl-N-furfuryldithiocarbamato-κ2S,S′)cadmium]
Acta Crystallographica Section E
author_facet Rajni Kant
Vivek K. Gupta
Kamini Kapoor
P. Valarmathi
S. Thirumaran
author_sort Rajni Kant
title Bis(μ-N-benzyl-N-furfuryldithiocarbamato)-1:2κ3S,S′:S′;2:1κ3S,S′:S′-bis[(N-benzyl-N-furfuryldithiocarbamato-κ2S,S′)cadmium]
title_short Bis(μ-N-benzyl-N-furfuryldithiocarbamato)-1:2κ3S,S′:S′;2:1κ3S,S′:S′-bis[(N-benzyl-N-furfuryldithiocarbamato-κ2S,S′)cadmium]
title_full Bis(μ-N-benzyl-N-furfuryldithiocarbamato)-1:2κ3S,S′:S′;2:1κ3S,S′:S′-bis[(N-benzyl-N-furfuryldithiocarbamato-κ2S,S′)cadmium]
title_fullStr Bis(μ-N-benzyl-N-furfuryldithiocarbamato)-1:2κ3S,S′:S′;2:1κ3S,S′:S′-bis[(N-benzyl-N-furfuryldithiocarbamato-κ2S,S′)cadmium]
title_full_unstemmed Bis(μ-N-benzyl-N-furfuryldithiocarbamato)-1:2κ3S,S′:S′;2:1κ3S,S′:S′-bis[(N-benzyl-N-furfuryldithiocarbamato-κ2S,S′)cadmium]
title_sort bis(μ-n-benzyl-n-furfuryldithiocarbamato)-1:2κ3s,s′:s′;2:1κ3s,s′:s′-bis[(n-benzyl-n-furfuryldithiocarbamato-κ2s,s′)cadmium]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-01-01
description In the centrosymmetric title compound, [Cd2(C13H12NOS2)4], pairs of dithiocarbamate ligands exhibit different structural functions. Each of the terminal ligands is bidentately coordinated to one CdII atom and forms a planar four-membered CS2Cd chelate ring, whereas pairs of the tridentate bridging ligands link two neighbouring CdII atoms, forming extended eight-membered C2S4Cd2 tricyclic units whose geometry can be approximated by a chair conformation. The coordination polyhedron of the CdII atoms is a distorted square-pyramid. The five-membered furan ring and the benzene ring are disordered over two sets of sites with an occupancy ratio of 0.62 (8):0.38 (8).
url http://scripts.iucr.org/cgi-bin/paper?S1600536811051348
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