Bis(μ-N-benzyl-N-furfuryldithiocarbamato)-1:2κ3S,S′:S′;2:1κ3S,S′:S′-bis[(N-benzyl-N-furfuryldithiocarbamato-κ2S,S′)cadmium]
In the centrosymmetric title compound, [Cd2(C13H12NOS2)4], pairs of dithiocarbamate ligands exhibit different structural functions. Each of the terminal ligands is bidentately coordinated to one CdII atom and forms a planar four-membered CS2Cd chelate ring, whereas pairs of the tridentate bridging l...
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International Union of Crystallography
2012-01-01
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Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811051348 |
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doaj-155492b28afd44c5886f04c7c55677a82020-11-24T21:25:55ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-01-01681m12m1310.1107/S1600536811051348Bis(μ-N-benzyl-N-furfuryldithiocarbamato)-1:2κ3S,S′:S′;2:1κ3S,S′:S′-bis[(N-benzyl-N-furfuryldithiocarbamato-κ2S,S′)cadmium]Rajni KantVivek K. GuptaKamini KapoorP. ValarmathiS. ThirumaranIn the centrosymmetric title compound, [Cd2(C13H12NOS2)4], pairs of dithiocarbamate ligands exhibit different structural functions. Each of the terminal ligands is bidentately coordinated to one CdII atom and forms a planar four-membered CS2Cd chelate ring, whereas pairs of the tridentate bridging ligands link two neighbouring CdII atoms, forming extended eight-membered C2S4Cd2 tricyclic units whose geometry can be approximated by a chair conformation. The coordination polyhedron of the CdII atoms is a distorted square-pyramid. The five-membered furan ring and the benzene ring are disordered over two sets of sites with an occupancy ratio of 0.62 (8):0.38 (8).http://scripts.iucr.org/cgi-bin/paper?S1600536811051348 |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Rajni Kant Vivek K. Gupta Kamini Kapoor P. Valarmathi S. Thirumaran |
spellingShingle |
Rajni Kant Vivek K. Gupta Kamini Kapoor P. Valarmathi S. Thirumaran Bis(μ-N-benzyl-N-furfuryldithiocarbamato)-1:2κ3S,S′:S′;2:1κ3S,S′:S′-bis[(N-benzyl-N-furfuryldithiocarbamato-κ2S,S′)cadmium] Acta Crystallographica Section E |
author_facet |
Rajni Kant Vivek K. Gupta Kamini Kapoor P. Valarmathi S. Thirumaran |
author_sort |
Rajni Kant |
title |
Bis(μ-N-benzyl-N-furfuryldithiocarbamato)-1:2κ3S,S′:S′;2:1κ3S,S′:S′-bis[(N-benzyl-N-furfuryldithiocarbamato-κ2S,S′)cadmium] |
title_short |
Bis(μ-N-benzyl-N-furfuryldithiocarbamato)-1:2κ3S,S′:S′;2:1κ3S,S′:S′-bis[(N-benzyl-N-furfuryldithiocarbamato-κ2S,S′)cadmium] |
title_full |
Bis(μ-N-benzyl-N-furfuryldithiocarbamato)-1:2κ3S,S′:S′;2:1κ3S,S′:S′-bis[(N-benzyl-N-furfuryldithiocarbamato-κ2S,S′)cadmium] |
title_fullStr |
Bis(μ-N-benzyl-N-furfuryldithiocarbamato)-1:2κ3S,S′:S′;2:1κ3S,S′:S′-bis[(N-benzyl-N-furfuryldithiocarbamato-κ2S,S′)cadmium] |
title_full_unstemmed |
Bis(μ-N-benzyl-N-furfuryldithiocarbamato)-1:2κ3S,S′:S′;2:1κ3S,S′:S′-bis[(N-benzyl-N-furfuryldithiocarbamato-κ2S,S′)cadmium] |
title_sort |
bis(μ-n-benzyl-n-furfuryldithiocarbamato)-1:2κ3s,s′:s′;2:1κ3s,s′:s′-bis[(n-benzyl-n-furfuryldithiocarbamato-κ2s,s′)cadmium] |
publisher |
International Union of Crystallography |
series |
Acta Crystallographica Section E |
issn |
1600-5368 |
publishDate |
2012-01-01 |
description |
In the centrosymmetric title compound, [Cd2(C13H12NOS2)4], pairs of dithiocarbamate ligands exhibit different structural functions. Each of the terminal ligands is bidentately coordinated to one CdII atom and forms a planar four-membered CS2Cd chelate ring, whereas pairs of the tridentate bridging ligands link two neighbouring CdII atoms, forming extended eight-membered C2S4Cd2 tricyclic units whose geometry can be approximated by a chair conformation. The coordination polyhedron of the CdII atoms is a distorted square-pyramid. The five-membered furan ring and the benzene ring are disordered over two sets of sites with an occupancy ratio of 0.62 (8):0.38 (8). |
url |
http://scripts.iucr.org/cgi-bin/paper?S1600536811051348 |
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