{4-Hydroxy-N′-[(2E,3Z)-4-oxido-4-phenylbut-3-en-2-ylidene]benzohydrazidato}dimethyltin(IV)
The SnIV atom in the title compound, [Sn(CH3)2(C17H14N2O3)], is five-coordinated within a C2N2O donor set provided by the N,N,O-tridentate ligand and two methyl groups. The resultant coordination geometry is intermediate between trigonal-bipyramidal and square-pyramidal. In the crystal, supramolecul...
Main Authors: | , , , , |
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Format: | Article |
Language: | English |
Published: |
International Union of Crystallography
2011-07-01
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Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811023506 |
Summary: | The SnIV atom in the title compound, [Sn(CH3)2(C17H14N2O3)], is five-coordinated within a C2N2O donor set provided by the N,N,O-tridentate ligand and two methyl groups. The resultant coordination geometry is intermediate between trigonal-bipyramidal and square-pyramidal. In the crystal, supramolecular zigzag chains propagating along the c- axis direction are mediated by O—H...O hydrogen bonds, and weak C—H...π interactions consolidate the packing. |
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ISSN: | 1600-5368 |