Poly[[μ-1,4-anhydroerythritolato-di-μ-aqua-sodium(I)] monohydrate]

In the title compound, {[Na(C4H7O3)(H2O)2]·H2O}n, the sodium ion is octahedrally coordinated by two bridging 1,4-anhydroerythritolate ligands, unexpectedly coordinated by the ring oxygen and four water ligands. This bonding pattern leads to one-dimensional antitactical polymeric chains alon...

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Main Authors: Peter Klüfers, Peter Mayer, Patrick Zeller, Tobias Kerscher
Format: Article
Language:English
Published: International Union of Crystallography 2008-12-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536808039640
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spelling doaj-158ad0e812f3429d9b1c3e69388d33502020-11-25T00:50:36ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-12-016412m1637m163710.1107/S1600536808039640Poly[[μ-1,4-anhydroerythritolato-di-μ-aqua-sodium(I)] monohydrate]Peter KlüfersPeter MayerPatrick ZellerTobias KerscherIn the title compound, {[Na(C4H7O3)(H2O)2]·H2O}n, the sodium ion is octahedrally coordinated by two bridging 1,4-anhydroerythritolate ligands, unexpectedly coordinated by the ring oxygen and four water ligands. This bonding pattern leads to one-dimensional antitactical polymeric chains along [010]. One of the exocyclic O atoms of the anhydroerythritolate group is an acceptor in four hydrogen bonds, giving further evidence that it is deprotonated.http://scripts.iucr.org/cgi-bin/paper?S1600536808039640
collection DOAJ
language English
format Article
sources DOAJ
author Peter Klüfers
Peter Mayer
Patrick Zeller
Tobias Kerscher
spellingShingle Peter Klüfers
Peter Mayer
Patrick Zeller
Tobias Kerscher
Poly[[μ-1,4-anhydroerythritolato-di-μ-aqua-sodium(I)] monohydrate]
Acta Crystallographica Section E
author_facet Peter Klüfers
Peter Mayer
Patrick Zeller
Tobias Kerscher
author_sort Peter Klüfers
title Poly[[μ-1,4-anhydroerythritolato-di-μ-aqua-sodium(I)] monohydrate]
title_short Poly[[μ-1,4-anhydroerythritolato-di-μ-aqua-sodium(I)] monohydrate]
title_full Poly[[μ-1,4-anhydroerythritolato-di-μ-aqua-sodium(I)] monohydrate]
title_fullStr Poly[[μ-1,4-anhydroerythritolato-di-μ-aqua-sodium(I)] monohydrate]
title_full_unstemmed Poly[[μ-1,4-anhydroerythritolato-di-μ-aqua-sodium(I)] monohydrate]
title_sort poly[[μ-1,4-anhydroerythritolato-di-μ-aqua-sodium(i)] monohydrate]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2008-12-01
description In the title compound, {[Na(C4H7O3)(H2O)2]·H2O}n, the sodium ion is octahedrally coordinated by two bridging 1,4-anhydroerythritolate ligands, unexpectedly coordinated by the ring oxygen and four water ligands. This bonding pattern leads to one-dimensional antitactical polymeric chains along [010]. One of the exocyclic O atoms of the anhydroerythritolate group is an acceptor in four hydrogen bonds, giving further evidence that it is deprotonated.
url http://scripts.iucr.org/cgi-bin/paper?S1600536808039640
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AT patrickzeller poly95614anhydroerythritolatodi956aquasodiumimonohydrate
AT tobiaskerscher poly95614anhydroerythritolatodi956aquasodiumimonohydrate
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