Poly[[μ-1,4-anhydroerythritolato-di-μ-aqua-sodium(I)] monohydrate]
In the title compound, {[Na(C4H7O3)(H2O)2]·H2O}n, the sodium ion is octahedrally coordinated by two bridging 1,4-anhydroerythritolate ligands, unexpectedly coordinated by the ring oxygen and four water ligands. This bonding pattern leads to one-dimensional antitactical polymeric chains alon...
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International Union of Crystallography
2008-12-01
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Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808039640 |
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doaj-158ad0e812f3429d9b1c3e69388d33502020-11-25T00:50:36ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-12-016412m1637m163710.1107/S1600536808039640Poly[[μ-1,4-anhydroerythritolato-di-μ-aqua-sodium(I)] monohydrate]Peter KlüfersPeter MayerPatrick ZellerTobias KerscherIn the title compound, {[Na(C4H7O3)(H2O)2]·H2O}n, the sodium ion is octahedrally coordinated by two bridging 1,4-anhydroerythritolate ligands, unexpectedly coordinated by the ring oxygen and four water ligands. This bonding pattern leads to one-dimensional antitactical polymeric chains along [010]. One of the exocyclic O atoms of the anhydroerythritolate group is an acceptor in four hydrogen bonds, giving further evidence that it is deprotonated.http://scripts.iucr.org/cgi-bin/paper?S1600536808039640 |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Peter Klüfers Peter Mayer Patrick Zeller Tobias Kerscher |
spellingShingle |
Peter Klüfers Peter Mayer Patrick Zeller Tobias Kerscher Poly[[μ-1,4-anhydroerythritolato-di-μ-aqua-sodium(I)] monohydrate] Acta Crystallographica Section E |
author_facet |
Peter Klüfers Peter Mayer Patrick Zeller Tobias Kerscher |
author_sort |
Peter Klüfers |
title |
Poly[[μ-1,4-anhydroerythritolato-di-μ-aqua-sodium(I)] monohydrate] |
title_short |
Poly[[μ-1,4-anhydroerythritolato-di-μ-aqua-sodium(I)] monohydrate] |
title_full |
Poly[[μ-1,4-anhydroerythritolato-di-μ-aqua-sodium(I)] monohydrate] |
title_fullStr |
Poly[[μ-1,4-anhydroerythritolato-di-μ-aqua-sodium(I)] monohydrate] |
title_full_unstemmed |
Poly[[μ-1,4-anhydroerythritolato-di-μ-aqua-sodium(I)] monohydrate] |
title_sort |
poly[[μ-1,4-anhydroerythritolato-di-μ-aqua-sodium(i)] monohydrate] |
publisher |
International Union of Crystallography |
series |
Acta Crystallographica Section E |
issn |
1600-5368 |
publishDate |
2008-12-01 |
description |
In the title compound, {[Na(C4H7O3)(H2O)2]·H2O}n, the sodium ion is octahedrally coordinated by two bridging 1,4-anhydroerythritolate ligands, unexpectedly coordinated by the ring oxygen and four water ligands. This bonding pattern leads to one-dimensional antitactical polymeric chains along [010]. One of the exocyclic O atoms of the anhydroerythritolate group is an acceptor in four hydrogen bonds, giving further evidence that it is deprotonated. |
url |
http://scripts.iucr.org/cgi-bin/paper?S1600536808039640 |
work_keys_str_mv |
AT peterkl252fers poly95614anhydroerythritolatodi956aquasodiumimonohydrate AT petermayer poly95614anhydroerythritolatodi956aquasodiumimonohydrate AT patrickzeller poly95614anhydroerythritolatodi956aquasodiumimonohydrate AT tobiaskerscher poly95614anhydroerythritolatodi956aquasodiumimonohydrate |
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