One-dimensional ladder gallium coordination polymer

One-dimensional ladder gallium coordination polymer

A one-dimensional ladder-type coordination polymer, poly[[(μ2-hydroxido)(μ2-1H-pyrazole-3,5-dicarboxylato)gallium(III)] monohydrate], [Ga(C5H2N2O4)(OH)(H2O)]n or [Ga(HPDC)(OH)(H2O)]n, I, isotypic with a V3+ coordination polymer previously reported by Chen et al. [J. Coord. Chem. (2008). 61, 3556–356...

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Main Authors: Andrea B. Simões, Flávio Figueira, Ricardo F. Mendes, Jéssica S. Barbosa, João Rocha, Filipe A. Almeida Paz
Format: Article
Language:English
Published: International Union of Crystallography 2019-11-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
coordination polymers
gallium
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989019013446
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spelling doaj-159910f5fe3e4edaa1aef967eae1c27a2020-11-25T02:06:53ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902019-11-0175111607161210.1107/S2056989019013446sj5578One-dimensional ladder gallium coordination polymerAndrea B. Simões0Flávio Figueira1Ricardo F. Mendes2Jéssica S. Barbosa3João Rocha4Filipe A. Almeida Paz5CICECO–Aveiro Institute of Materials, Department of Chemistry, University of Aveiro, Campus Universitário de Santiago, 3810-193 Aveiro, PortugalCICECO–Aveiro Institute of Materials, Department of Chemistry, University of Aveiro, Campus Universitário de Santiago, 3810-193 Aveiro, PortugalCICECO–Aveiro Institute of Materials, Department of Chemistry, University of Aveiro, Campus Universitário de Santiago, 3810-193 Aveiro, PortugalCICECO–Aveiro Institute of Materials, Department of Chemistry, University of Aveiro, Campus Universitário de Santiago, 3810-193 Aveiro, PortugalCICECO–Aveiro Institute of Materials, Department of Chemistry, University of Aveiro, Campus Universitário de Santiago, 3810-193 Aveiro, PortugalCICECO–Aveiro Institute of Materials, Department of Chemistry, University of Aveiro, Campus Universitário de Santiago, 3810-193 Aveiro, PortugalA one-dimensional ladder-type coordination polymer, poly[[(μ2-hydroxido)(μ2-1H-pyrazole-3,5-dicarboxylato)gallium(III)] monohydrate], [Ga(C5H2N2O4)(OH)(H2O)]n or [Ga(HPDC)(OH)(H2O)]n, I, isotypic with a V3+ coordination polymer previously reported by Chen et al. [J. Coord. Chem. (2008). 61, 3556–3567] was prepared from Ga3+ and pyrazole-3,5-dicarboxylic acid monohydrate (H3PDC·H2O). Compound I was isolated using three distinct experimental methods: hydrothermal (HT), microwave-assisted (MWAS) and one-pot (OP) and the crystallite size should be fine-tuned according to the method employed. The coordination polymeric structure is based on a dimeric Ga3+ moiety comprising two μ2-bridging hydroxide groups, which are interconnected by HPDC2− anionic organic linkers. The close packing of individual polymers is strongly directed by the supramolecular interactions, namely several O—H...O and N—H...O hydrogen-bonding interactions.http://scripts.iucr.org/cgi-bin/paper?S2056989019013446crystal structurecoordination polymersgallium
collection DOAJ
language English
format Article
sources DOAJ
author Andrea B. Simões
Flávio Figueira
Ricardo F. Mendes
Jéssica S. Barbosa
João Rocha
Filipe A. Almeida Paz
spellingShingle Andrea B. Simões
Flávio Figueira
Ricardo F. Mendes
Jéssica S. Barbosa
João Rocha
Filipe A. Almeida Paz
One-dimensional ladder gallium coordination polymer
Acta Crystallographica Section E: Crystallographic Communications
crystal structure
coordination polymers
gallium
author_facet Andrea B. Simões
Flávio Figueira
Ricardo F. Mendes
Jéssica S. Barbosa
João Rocha
Filipe A. Almeida Paz
author_sort Andrea B. Simões
title One-dimensional ladder gallium coordination polymer
title_short One-dimensional ladder gallium coordination polymer
title_full One-dimensional ladder gallium coordination polymer
title_fullStr One-dimensional ladder gallium coordination polymer
title_full_unstemmed One-dimensional ladder gallium coordination polymer
title_sort one-dimensional ladder gallium coordination polymer
publisher International Union of Crystallography
series Acta Crystallographica Section E: Crystallographic Communications
issn 2056-9890
publishDate 2019-11-01
description A one-dimensional ladder-type coordination polymer, poly[[(μ2-hydroxido)(μ2-1H-pyrazole-3,5-dicarboxylato)gallium(III)] monohydrate], [Ga(C5H2N2O4)(OH)(H2O)]n or [Ga(HPDC)(OH)(H2O)]n, I, isotypic with a V3+ coordination polymer previously reported by Chen et al. [J. Coord. Chem. (2008). 61, 3556–3567] was prepared from Ga3+ and pyrazole-3,5-dicarboxylic acid monohydrate (H3PDC·H2O). Compound I was isolated using three distinct experimental methods: hydrothermal (HT), microwave-assisted (MWAS) and one-pot (OP) and the crystallite size should be fine-tuned according to the method employed. The coordination polymeric structure is based on a dimeric Ga3+ moiety comprising two μ2-bridging hydroxide groups, which are interconnected by HPDC2− anionic organic linkers. The close packing of individual polymers is strongly directed by the supramolecular interactions, namely several O—H...O and N—H...O hydrogen-bonding interactions.
topic crystal structure
coordination polymers
gallium
url http://scripts.iucr.org/cgi-bin/paper?S2056989019013446
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