Ultrafast proton transport in water-methanol mixtures
Femtosecond UV/IR pump-probe experiments and ab initio molecular dynamics simulations of 7-hydroxyquinoline in water-methanol mixtures demonstrate an unexpectedly dominant OH-/CH3O- transport pathway but consistent with a solvent-dependent photoacidity free energy-reactivity correlation behaviour.
Main Authors: | Ekimova Maria, Hoffmann Felix, Bekcioglu-Neff Gul, Rafferty Aidan, Nibbering Erik T. J., Sebastiani Daniel |
---|---|
Format: | Article |
Language: | English |
Published: |
EDP Sciences
2019-01-01
|
Series: | EPJ Web of Conferences |
Online Access: | https://www.epj-conferences.org/articles/epjconf/pdf/2019/10/epjconf_up2019_09004.pdf |
Similar Items
-
Ultrafast dynamics of hydrated excess protons in CH3CN:H2O mixtures
by: Dahms Fabian, et al.
Published: (2019-01-01) -
Potentiometric Studies on the Protonation Constants and Protonation Energies of Some Diamines in Methanol + Water Mixtures
by: Sangita Sharma, et al.
Published: (2007-01-01) -
The Determination of Protonation Constants of Peptidomimetic Cyclophanes in Binary Methanol-Water Mixtures
by: Piotr Seliger, et al.
Published: (2016-01-01) -
Ultrafast proton coupled electron transfer (PCET) dynamics in 9-anthranol-aliphatic amine system
by: Nibbering Erik T. J., et al.
Published: (2013-03-01) -
Ultrafast dephasing in hydrogen-bonded pyridine–water mixtures
by: Ariunbold Gombojav O., et al.
Published: (2021-05-01)