Bis(1,10-phenanthroline-κ2N,N′)(sulfato-κ2O,O′)nickel(II) propane-1,3-diol solvate
In the structure of the title compound, [Ni(SO4)(C12H8N2)2]·C3H8O2, the NiII ion (site symmetry 2) is six-coordinated in a distorted octahedral manner by four N atoms from two chelating 1,10-phenanthroline (phen) ligands and two O atoms from a bidentate sulfate ligand (2 symmetry). The...
Main Authors: | , , |
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Format: | Article |
Language: | English |
Published: |
International Union of Crystallography
2010-07-01
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Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810020210 |
Summary: | In the structure of the title compound, [Ni(SO4)(C12H8N2)2]·C3H8O2, the NiII ion (site symmetry 2) is six-coordinated in a distorted octahedral manner by four N atoms from two chelating 1,10-phenanthroline (phen) ligands and two O atoms from a bidentate sulfate ligand (2 symmetry). The dihedral angle between the two chelating NCCN groups is 80.9 (1)°. The central C atom of the propane-1,3-diol solvent molecule is likewise located on a twofold rotation axis. In the crystal structure, the [Ni(SO4)(C12H8N2)2] and C3H8O2 entities are connected through intermolecular O—H...O hydrogen bonding. |
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ISSN: | 1600-5368 |