Bis(1,10-phenanthroline-κ2N,N′)(sulfato-κ2O,O′)nickel(II) propane-1,3-diol solvate

Bis(1,10-phenanthroline-κ2N,N′)(sulfato-κ2O,O′)nickel(II) propane-1,3-diol solvate

In the structure of the title compound, [Ni(SO4)(C12H8N2)2]·C3H8O2, the NiII ion (site symmetry 2) is six-coordinated in a distorted octahedral manner by four N atoms from two chelating 1,10-phenanthroline (phen) ligands and two O atoms from a bidentate sulfate ligand (2 symmetry). The...

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Main Authors: Chao Ni, Kai-Long Zhong, Jiang-Dong Cui
Format: Article
Language:English
Published: International Union of Crystallography 2010-07-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810020210
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spelling doaj-15a77a1337c1434ab1f506e7c5632a542020-11-25T01:37:59ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-07-01667m746m74710.1107/S1600536810020210Bis(1,10-phenanthroline-κ2N,N′)(sulfato-κ2O,O′)nickel(II) propane-1,3-diol solvateChao NiKai-Long ZhongJiang-Dong CuiIn the structure of the title compound, [Ni(SO4)(C12H8N2)2]·C3H8O2, the NiII ion (site symmetry 2) is six-coordinated in a distorted octahedral manner by four N atoms from two chelating 1,10-phenanthroline (phen) ligands and two O atoms from a bidentate sulfate ligand (2 symmetry). The dihedral angle between the two chelating NCCN groups is 80.9 (1)°. The central C atom of the propane-1,3-diol solvent molecule is likewise located on a twofold rotation axis. In the crystal structure, the [Ni(SO4)(C12H8N2)2] and C3H8O2 entities are connected through intermolecular O—H...O hydrogen bonding. http://scripts.iucr.org/cgi-bin/paper?S1600536810020210
collection DOAJ
language English
format Article
sources DOAJ
author Chao Ni
Kai-Long Zhong
Jiang-Dong Cui
spellingShingle Chao Ni
Kai-Long Zhong
Jiang-Dong Cui
Bis(1,10-phenanthroline-κ2N,N′)(sulfato-κ2O,O′)nickel(II) propane-1,3-diol solvate
Acta Crystallographica Section E
author_facet Chao Ni
Kai-Long Zhong
Jiang-Dong Cui
author_sort Chao Ni
title Bis(1,10-phenanthroline-κ2N,N′)(sulfato-κ2O,O′)nickel(II) propane-1,3-diol solvate
title_short Bis(1,10-phenanthroline-κ2N,N′)(sulfato-κ2O,O′)nickel(II) propane-1,3-diol solvate
title_full Bis(1,10-phenanthroline-κ2N,N′)(sulfato-κ2O,O′)nickel(II) propane-1,3-diol solvate
title_fullStr Bis(1,10-phenanthroline-κ2N,N′)(sulfato-κ2O,O′)nickel(II) propane-1,3-diol solvate
title_full_unstemmed Bis(1,10-phenanthroline-κ2N,N′)(sulfato-κ2O,O′)nickel(II) propane-1,3-diol solvate
title_sort bis(1,10-phenanthroline-κ2n,n′)(sulfato-κ2o,o′)nickel(ii) propane-1,3-diol solvate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-07-01
description In the structure of the title compound, [Ni(SO4)(C12H8N2)2]·C3H8O2, the NiII ion (site symmetry 2) is six-coordinated in a distorted octahedral manner by four N atoms from two chelating 1,10-phenanthroline (phen) ligands and two O atoms from a bidentate sulfate ligand (2 symmetry). The dihedral angle between the two chelating NCCN groups is 80.9 (1)°. The central C atom of the propane-1,3-diol solvent molecule is likewise located on a twofold rotation axis. In the crystal structure, the [Ni(SO4)(C12H8N2)2] and C3H8O2 entities are connected through intermolecular O—H...O hydrogen bonding.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810020210
work_keys_str_mv AT chaoni bis110phenanthrolineamp9542nnamp8242sulfatoamp9542ooamp8242nickeliipropane13diolsolvate
AT kailongzhong bis110phenanthrolineamp9542nnamp8242sulfatoamp9542ooamp8242nickeliipropane13diolsolvate
AT jiangdongcui bis110phenanthrolineamp9542nnamp8242sulfatoamp9542ooamp8242nickeliipropane13diolsolvate
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