Superstructures of fluorescent cyclodextrin via click-reaction
Mono-(6-azido-6-deoxy)-β-cyclodextrin (CD) was covalently attached to an alkyne-modified 5-methyl-2-(pyridin-2-yl)thiazol-4-ol yielding a fluorophore containing CD in a click-type reaction. Intermolecular complexes were formed by poly(host–guest)-interactions. The supramolecular structures were char...
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Online Access: | https://doi.org/10.3762/bjoc.9.94 |
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doaj-1632766bd84d4da99793a9661d3488d22021-03-02T10:05:17ZengBeilstein-InstitutBeilstein Journal of Organic Chemistry1860-53972013-04-019182783110.3762/bjoc.9.941860-5397-9-94Superstructures of fluorescent cyclodextrin via click-reactionArkadius Maciollek0Helmut Ritter1Rainer Beckert2Institute of Organic Chemistry and Macromolecular Chemistry, Heinrich-Heine-University Duesseldorf, Universitaetsstraße 1, 40225 Duesseldorf, GermanyInstitute of Organic Chemistry and Macromolecular Chemistry, Heinrich-Heine-University Duesseldorf, Universitaetsstraße 1, 40225 Duesseldorf, GermanyInstitute of Organic Chemistry and Macromolecular Chemistry, Friedrich-Schiller-University, Humboldtstr. 10, 07743 Jena, GermanyMono-(6-azido-6-deoxy)-β-cyclodextrin (CD) was covalently attached to an alkyne-modified 5-methyl-2-(pyridin-2-yl)thiazol-4-ol yielding a fluorophore containing CD in a click-type reaction. Intermolecular complexes were formed by poly(host–guest)-interactions. The supramolecular structures were characterized by 1H NMR-ROESY spectroscopy, dynamic light scattering, UV–vis spectroscopy, fluorescence spectroscopy, and asymmetric flow field-flow fractionation. By adding potassium adamantane-1-carboxylate, the thiazol dye is displaced from the CD-cavity and the elongated noncovalent polymeric structures collapse.https://doi.org/10.3762/bjoc.9.94fluorescent dyecyclodextrinshost–guest interactionsupramolecular polymer |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Arkadius Maciollek Helmut Ritter Rainer Beckert |
spellingShingle |
Arkadius Maciollek Helmut Ritter Rainer Beckert Superstructures of fluorescent cyclodextrin via click-reaction Beilstein Journal of Organic Chemistry fluorescent dye cyclodextrins host–guest interaction supramolecular polymer |
author_facet |
Arkadius Maciollek Helmut Ritter Rainer Beckert |
author_sort |
Arkadius Maciollek |
title |
Superstructures of fluorescent cyclodextrin via click-reaction |
title_short |
Superstructures of fluorescent cyclodextrin via click-reaction |
title_full |
Superstructures of fluorescent cyclodextrin via click-reaction |
title_fullStr |
Superstructures of fluorescent cyclodextrin via click-reaction |
title_full_unstemmed |
Superstructures of fluorescent cyclodextrin via click-reaction |
title_sort |
superstructures of fluorescent cyclodextrin via click-reaction |
publisher |
Beilstein-Institut |
series |
Beilstein Journal of Organic Chemistry |
issn |
1860-5397 |
publishDate |
2013-04-01 |
description |
Mono-(6-azido-6-deoxy)-β-cyclodextrin (CD) was covalently attached to an alkyne-modified 5-methyl-2-(pyridin-2-yl)thiazol-4-ol yielding a fluorophore containing CD in a click-type reaction. Intermolecular complexes were formed by poly(host–guest)-interactions. The supramolecular structures were characterized by 1H NMR-ROESY spectroscopy, dynamic light scattering, UV–vis spectroscopy, fluorescence spectroscopy, and asymmetric flow field-flow fractionation. By adding potassium adamantane-1-carboxylate, the thiazol dye is displaced from the CD-cavity and the elongated noncovalent polymeric structures collapse. |
topic |
fluorescent dye cyclodextrins host–guest interaction supramolecular polymer |
url |
https://doi.org/10.3762/bjoc.9.94 |
work_keys_str_mv |
AT arkadiusmaciollek superstructuresoffluorescentcyclodextrinviaclickreaction AT helmutritter superstructuresoffluorescentcyclodextrinviaclickreaction AT rainerbeckert superstructuresoffluorescentcyclodextrinviaclickreaction |
_version_ |
1724237694524981248 |