SYNTHESIS AND STUDY OF COMPLEXES OF COPPER(II), ZINC, COBALT(II) AND NICKEL(II) WITH NITROFLUORENYLIDENE-9-AMINO(IMINO) DERIVATIVES

SYNTHESIS AND STUDY OF COMPLEXES OF COPPER(II), ZINC, COBALT(II) AND NICKEL(II) WITH NITROFLUORENYLIDENE-9-AMINO(IMINO) DERIVATIVES

The complexes of general formula MCl2∙L1-4∙nH2O (where L1 - N-(2,4,7-trinitrofluorenilidene-9)-p-dimethyl-aminoanilin, L2 - N-(2,4,5,7-tetranitrofluorenilidene-9)-p-dimethylaminoaniline, L3 - N-(2,4,7-trinitrofluorenilidene)-N-(p-dimethylaminophenyl)hydroxylamine, L4 - N-(2,4,5,7-tetranitrofluoreni...

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Bibliographic Details
Main Authors: S.B. Strashnova, O.V. Avramenko, M.N. Zhuk, O.V.Kovalchukova, P.V. Strashnov, B.E. Zaitsev
Format: Article
Language:English
Published: Academy of Sciences of Moldova, Institute of Chemistry 2009-12-01
Series:Chemistry Journal of Moldova: General, Industrial and Ecological Chemistry
Subjects:
nitrofluoreniliden-9-anilin
amino-group
Online Access:http://www.cjm.asm.md/sites/default/files/article_files/010_Strashnova.pdf
Description
Summary:The complexes of general formula MCl2∙L1-4∙nH2O (where L1 - N-(2,4,7-trinitrofluorenilidene-9)-p-dimethyl-aminoanilin, L2 - N-(2,4,5,7-tetranitrofluorenilidene-9)-p-dimethylaminoaniline, L3 - N-(2,4,7-trinitrofluorenilidene)-N-(p-dimethylaminophenyl)hydroxylamine, L4 - N-(2,4,5,7-tetranitrofluorenilidene-9)-N-(p-dimethylaminophenyl)-hydroxylamine; M=Cu, Co, Ni, Zn; n= 1-3 have been synthesized and investigated by different methods. Spectral criteria of co-ordination of the molecules L1 –L4 in electronic adsorption spectra were detected.
ISSN:1857-1727
2345-1688

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