Part 3. Triethylborane-air: a suitable initiator for intermolecular radical additions of S-2-oxoalkyl-thionocarbonates (S-xanthates) to olefins

Part 3. Triethylborane-air: a suitable initiator for intermolecular radical additions of S-2-oxoalkyl-thionocarbonates (S-xanthates) to olefins

Under carefully controlled conditions, the triethylborane-air combination proves to be an efficient radical initiator that allows intermolecular radical additions of S-2-oxoalkyl-thionocarbonates (S-xanthates) to olefins. Depending on both the structures of the xanthate and the olefin, the addition...

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Main Authors: Jean Boivin, Van Tai Nguyen
Format: Article
Language:English
Published: Beilstein-Institut 2007-12-01
Series:Beilstein Journal of Organic Chemistry
Online Access:https://doi.org/10.1186/1860-5397-3-47
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spelling doaj-177bf3d38831436bbf40e8f412324afa2021-03-02T09:40:29ZengBeilstein-InstitutBeilstein Journal of Organic Chemistry1860-53972007-12-01314710.1186/1860-5397-3-471860-5397-3-47Part 3. Triethylborane-air: a suitable initiator for intermolecular radical additions of S-2-oxoalkyl-thionocarbonates (S-xanthates) to olefinsJean Boivin0Van Tai Nguyen1Institut de Chimie des Substances Naturelles, C.N.R.S., Avenue de la Terrasse, 91198 Gif-sur-Yvette, FranceInstitut de Chimie des Substances Naturelles, C.N.R.S., Avenue de la Terrasse, 91198 Gif-sur-Yvette, FranceUnder carefully controlled conditions, the triethylborane-air combination proves to be an efficient radical initiator that allows intermolecular radical additions of S-2-oxoalkyl-thionocarbonates (S-xanthates) to olefins. Depending on both the structures of the xanthate and the olefin, the addition process can be achieved at room temperature or slightly higher.https://doi.org/10.1186/1860-5397-3-47
collection DOAJ
language English
format Article
sources DOAJ
author Jean Boivin
Van Tai Nguyen
spellingShingle Jean Boivin
Van Tai Nguyen
Part 3. Triethylborane-air: a suitable initiator for intermolecular radical additions of S-2-oxoalkyl-thionocarbonates (S-xanthates) to olefins
Beilstein Journal of Organic Chemistry
author_facet Jean Boivin
Van Tai Nguyen
author_sort Jean Boivin
title Part 3. Triethylborane-air: a suitable initiator for intermolecular radical additions of S-2-oxoalkyl-thionocarbonates (S-xanthates) to olefins
title_short Part 3. Triethylborane-air: a suitable initiator for intermolecular radical additions of S-2-oxoalkyl-thionocarbonates (S-xanthates) to olefins
title_full Part 3. Triethylborane-air: a suitable initiator for intermolecular radical additions of S-2-oxoalkyl-thionocarbonates (S-xanthates) to olefins
title_fullStr Part 3. Triethylborane-air: a suitable initiator for intermolecular radical additions of S-2-oxoalkyl-thionocarbonates (S-xanthates) to olefins
title_full_unstemmed Part 3. Triethylborane-air: a suitable initiator for intermolecular radical additions of S-2-oxoalkyl-thionocarbonates (S-xanthates) to olefins
title_sort part 3. triethylborane-air: a suitable initiator for intermolecular radical additions of s-2-oxoalkyl-thionocarbonates (s-xanthates) to olefins
publisher Beilstein-Institut
series Beilstein Journal of Organic Chemistry
issn 1860-5397
publishDate 2007-12-01
description Under carefully controlled conditions, the triethylborane-air combination proves to be an efficient radical initiator that allows intermolecular radical additions of S-2-oxoalkyl-thionocarbonates (S-xanthates) to olefins. Depending on both the structures of the xanthate and the olefin, the addition process can be achieved at room temperature or slightly higher.
url https://doi.org/10.1186/1860-5397-3-47
work_keys_str_mv AT jeanboivin part3triethylboraneairasuitableinitiatorforintermolecularradicaladditionsofs2oxoalkylthionocarbonatessxanthatestoolefins
AT vantainguyen part3triethylboraneairasuitableinitiatorforintermolecularradicaladditionsofs2oxoalkylthionocarbonatessxanthatestoolefins
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