Crystal structure of (E)-1-(2-nitrobenzylidene)-2,2-diphenylhydrazine

Crystal structure of (E)-1-(2-nitrobenzylidene)-2,2-diphenylhydrazine

The title compound, C19H15N3O2, shows an E conformation of the imine bond. The dihedral angle between the planes of the phenyl rings in the diphenylhydrazine groups is 88.52 (4)°. The 2-nitrobenzene ring shows a torsion angle of 10.17 (8)° with the C=N—N plane. A short intramolecular C—H...O contact...

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Main Authors: Marcos Flores-Alamo, Ruth Meléndrez-Luévano, José A. Ortiz Márquez, Estibaliz Sansinenea Royano, Blanca M. Cabrera-Vivas
Format: Article
Language:English
Published: International Union of Crystallography 2014-09-01
Series:Acta Crystallographica Section E
Subjects:
crystal structure
hydrazine
hydrogen bonding
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536814016109
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spelling doaj-17d0c8cd9bc54bc5b6f400b3a734eabf2020-11-25T00:59:44ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682014-09-01709o909o91010.1107/S1600536814016109hb7250Crystal structure of (E)-1-(2-nitrobenzylidene)-2,2-diphenylhydrazineMarcos Flores-Alamo0Ruth Meléndrez-Luévano1José A. Ortiz Márquez2Estibaliz Sansinenea Royano3Blanca M. Cabrera-Vivas4Facultad de Química, Universidad Nacional Autónoma de México, 04510, México DF, MexicoFacultad de Ciencias Químicas, Benemérita Universidad Autónoma de Puebla 72570, Puebla, Pue., MexicoFacultad de Ciencias Químicas, Benemérita Universidad Autónoma de Puebla 72570, Puebla, Pue., MexicoFacultad de Ciencias Químicas, Benemérita Universidad Autónoma de Puebla 72570, Puebla, Pue., MexicoFacultad de Ciencias Químicas, Benemérita Universidad Autónoma de Puebla 72570, Puebla, Pue., MexicoThe title compound, C19H15N3O2, shows an E conformation of the imine bond. The dihedral angle between the planes of the phenyl rings in the diphenylhydrazine groups is 88.52 (4)°. The 2-nitrobenzene ring shows a torsion angle of 10.17 (8)° with the C=N—N plane. A short intramolecular C—H...O contact occurs. In the crystal, only van der Waals contacts occur between the molecules.http://scripts.iucr.org/cgi-bin/paper?S1600536814016109crystal structurehydrazinehydrogen bonding
collection DOAJ
language English
format Article
sources DOAJ
author Marcos Flores-Alamo
Ruth Meléndrez-Luévano
José A. Ortiz Márquez
Estibaliz Sansinenea Royano
Blanca M. Cabrera-Vivas
spellingShingle Marcos Flores-Alamo
Ruth Meléndrez-Luévano
José A. Ortiz Márquez
Estibaliz Sansinenea Royano
Blanca M. Cabrera-Vivas
Crystal structure of (E)-1-(2-nitrobenzylidene)-2,2-diphenylhydrazine
Acta Crystallographica Section E
crystal structure
hydrazine
hydrogen bonding
author_facet Marcos Flores-Alamo
Ruth Meléndrez-Luévano
José A. Ortiz Márquez
Estibaliz Sansinenea Royano
Blanca M. Cabrera-Vivas
author_sort Marcos Flores-Alamo
title Crystal structure of (E)-1-(2-nitrobenzylidene)-2,2-diphenylhydrazine
title_short Crystal structure of (E)-1-(2-nitrobenzylidene)-2,2-diphenylhydrazine
title_full Crystal structure of (E)-1-(2-nitrobenzylidene)-2,2-diphenylhydrazine
title_fullStr Crystal structure of (E)-1-(2-nitrobenzylidene)-2,2-diphenylhydrazine
title_full_unstemmed Crystal structure of (E)-1-(2-nitrobenzylidene)-2,2-diphenylhydrazine
title_sort crystal structure of (e)-1-(2-nitrobenzylidene)-2,2-diphenylhydrazine
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2014-09-01
description The title compound, C19H15N3O2, shows an E conformation of the imine bond. The dihedral angle between the planes of the phenyl rings in the diphenylhydrazine groups is 88.52 (4)°. The 2-nitrobenzene ring shows a torsion angle of 10.17 (8)° with the C=N—N plane. A short intramolecular C—H...O contact occurs. In the crystal, only van der Waals contacts occur between the molecules.
topic crystal structure
hydrazine
hydrogen bonding
url http://scripts.iucr.org/cgi-bin/paper?S1600536814016109
work_keys_str_mv AT marcosfloresalamo crystalstructureofe12nitrobenzylidene22diphenylhydrazine
AT ruthmelendrezluevano crystalstructureofe12nitrobenzylidene22diphenylhydrazine
AT joseaortizmarquez crystalstructureofe12nitrobenzylidene22diphenylhydrazine
AT estibalizsansinenearoyano crystalstructureofe12nitrobenzylidene22diphenylhydrazine
AT blancamcabreravivas crystalstructureofe12nitrobenzylidene22diphenylhydrazine
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