Electrochemical Degradation of Phenol and Resorcinol Molecules through the Dissolution of Sacrificial Anodes of Macro-Corrosion Galvanic Cells
This paper reports on the processes of phenol and resorcinol electrodegradation carried-out through continuous anodic dissolution of aluminum alloy and carbon steel sacrificial anodes for artificially aerated Cu-Al alloy and Cu-Fe-based galvanic (macro-corrosion) cells and synthetically prepared was...
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doaj-17d4bca706f3413796e987d57573ad252020-11-25T02:26:55ZengMDPI AGWater2073-44412018-06-0110677010.3390/w10060770w10060770Electrochemical Degradation of Phenol and Resorcinol Molecules through the Dissolution of Sacrificial Anodes of Macro-Corrosion Galvanic CellsBoguslaw Pierozynski0Grazyna Piotrowska1Department of Chemistry, Faculty of Environmental Management and Agriculture, University of Warmia and Mazury in Olsztyn, Plac Lodzki 4, 10-727 Olsztyn, PolandDepartment of Chemistry, Faculty of Environmental Management and Agriculture, University of Warmia and Mazury in Olsztyn, Plac Lodzki 4, 10-727 Olsztyn, PolandThis paper reports on the processes of phenol and resorcinol electrodegradation carried-out through continuous anodic dissolution of aluminum alloy and carbon steel sacrificial anodes for artificially aerated Cu-Al alloy and Cu-Fe-based galvanic (macro-corrosion) cells and synthetically prepared wastewater solutions. Electrochemical experiments were carried-out by means of a laboratory size, PMMA (Poly-methyl methacrylate)-made electrolyser unit, where significant degrees of phenol (10–89%) and resorcinol (13–37%) decomposition were obtained and visualized through the respective chemical/spectroscopy analyses. In addition, quantitative determination of phenol, as well as resorcinol (and possible electrodegradation products) for the selected experimental conditions was performed by means of instrumental high-performance liquid chromatography/mass spectrometry analysis.http://www.mdpi.com/2073-4441/10/6/770phenol and resorcinol electrodegradationgalvanic cellssacrificial anodesHPLC/MS (high-performance liquid chromatography/mass spectrometry) analysis |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Boguslaw Pierozynski Grazyna Piotrowska |
spellingShingle |
Boguslaw Pierozynski Grazyna Piotrowska Electrochemical Degradation of Phenol and Resorcinol Molecules through the Dissolution of Sacrificial Anodes of Macro-Corrosion Galvanic Cells Water phenol and resorcinol electrodegradation galvanic cells sacrificial anodes HPLC/MS (high-performance liquid chromatography/mass spectrometry) analysis |
author_facet |
Boguslaw Pierozynski Grazyna Piotrowska |
author_sort |
Boguslaw Pierozynski |
title |
Electrochemical Degradation of Phenol and Resorcinol Molecules through the Dissolution of Sacrificial Anodes of Macro-Corrosion Galvanic Cells |
title_short |
Electrochemical Degradation of Phenol and Resorcinol Molecules through the Dissolution of Sacrificial Anodes of Macro-Corrosion Galvanic Cells |
title_full |
Electrochemical Degradation of Phenol and Resorcinol Molecules through the Dissolution of Sacrificial Anodes of Macro-Corrosion Galvanic Cells |
title_fullStr |
Electrochemical Degradation of Phenol and Resorcinol Molecules through the Dissolution of Sacrificial Anodes of Macro-Corrosion Galvanic Cells |
title_full_unstemmed |
Electrochemical Degradation of Phenol and Resorcinol Molecules through the Dissolution of Sacrificial Anodes of Macro-Corrosion Galvanic Cells |
title_sort |
electrochemical degradation of phenol and resorcinol molecules through the dissolution of sacrificial anodes of macro-corrosion galvanic cells |
publisher |
MDPI AG |
series |
Water |
issn |
2073-4441 |
publishDate |
2018-06-01 |
description |
This paper reports on the processes of phenol and resorcinol electrodegradation carried-out through continuous anodic dissolution of aluminum alloy and carbon steel sacrificial anodes for artificially aerated Cu-Al alloy and Cu-Fe-based galvanic (macro-corrosion) cells and synthetically prepared wastewater solutions. Electrochemical experiments were carried-out by means of a laboratory size, PMMA (Poly-methyl methacrylate)-made electrolyser unit, where significant degrees of phenol (10–89%) and resorcinol (13–37%) decomposition were obtained and visualized through the respective chemical/spectroscopy analyses. In addition, quantitative determination of phenol, as well as resorcinol (and possible electrodegradation products) for the selected experimental conditions was performed by means of instrumental high-performance liquid chromatography/mass spectrometry analysis. |
topic |
phenol and resorcinol electrodegradation galvanic cells sacrificial anodes HPLC/MS (high-performance liquid chromatography/mass spectrometry) analysis |
url |
http://www.mdpi.com/2073-4441/10/6/770 |
work_keys_str_mv |
AT boguslawpierozynski electrochemicaldegradationofphenolandresorcinolmoleculesthroughthedissolutionofsacrificialanodesofmacrocorrosiongalvaniccells AT grazynapiotrowska electrochemicaldegradationofphenolandresorcinolmoleculesthroughthedissolutionofsacrificialanodesofmacrocorrosiongalvaniccells |
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1724845101137526784 |