Electrochemical Degradation of Phenol and Resorcinol Molecules through the Dissolution of Sacrificial Anodes of Macro-Corrosion Galvanic Cells

This paper reports on the processes of phenol and resorcinol electrodegradation carried-out through continuous anodic dissolution of aluminum alloy and carbon steel sacrificial anodes for artificially aerated Cu-Al alloy and Cu-Fe-based galvanic (macro-corrosion) cells and synthetically prepared was...

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Main Authors:	Boguslaw Pierozynski, Grazyna Piotrowska
Format:	Article
Language:	English
Published:	MDPI AG 2018-06-01
Series:	Water
Subjects:	phenol and resorcinol electrodegradation galvanic cells sacrificial anodes HPLC/MS (high-performance liquid chromatography/mass spectrometry) analysis
Online Access:	http://www.mdpi.com/2073-4441/10/6/770

id	doaj-17d4bca706f3413796e987d57573ad25
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spelling	doaj-17d4bca706f3413796e987d57573ad252020-11-25T02:26:55ZengMDPI AGWater2073-44412018-06-0110677010.3390/w10060770w10060770Electrochemical Degradation of Phenol and Resorcinol Molecules through the Dissolution of Sacrificial Anodes of Macro-Corrosion Galvanic CellsBoguslaw Pierozynski0Grazyna Piotrowska1Department of Chemistry, Faculty of Environmental Management and Agriculture, University of Warmia and Mazury in Olsztyn, Plac Lodzki 4, 10-727 Olsztyn, PolandDepartment of Chemistry, Faculty of Environmental Management and Agriculture, University of Warmia and Mazury in Olsztyn, Plac Lodzki 4, 10-727 Olsztyn, PolandThis paper reports on the processes of phenol and resorcinol electrodegradation carried-out through continuous anodic dissolution of aluminum alloy and carbon steel sacrificial anodes for artificially aerated Cu-Al alloy and Cu-Fe-based galvanic (macro-corrosion) cells and synthetically prepared wastewater solutions. Electrochemical experiments were carried-out by means of a laboratory size, PMMA (Poly-methyl methacrylate)-made electrolyser unit, where significant degrees of phenol (10–89%) and resorcinol (13–37%) decomposition were obtained and visualized through the respective chemical/spectroscopy analyses. In addition, quantitative determination of phenol, as well as resorcinol (and possible electrodegradation products) for the selected experimental conditions was performed by means of instrumental high-performance liquid chromatography/mass spectrometry analysis.http://www.mdpi.com/2073-4441/10/6/770phenol and resorcinol electrodegradationgalvanic cellssacrificial anodesHPLC/MS (high-performance liquid chromatography/mass spectrometry) analysis
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Boguslaw Pierozynski Grazyna Piotrowska
spellingShingle	Boguslaw Pierozynski Grazyna Piotrowska Electrochemical Degradation of Phenol and Resorcinol Molecules through the Dissolution of Sacrificial Anodes of Macro-Corrosion Galvanic Cells Water phenol and resorcinol electrodegradation galvanic cells sacrificial anodes HPLC/MS (high-performance liquid chromatography/mass spectrometry) analysis
author_facet	Boguslaw Pierozynski Grazyna Piotrowska
author_sort	Boguslaw Pierozynski
title	Electrochemical Degradation of Phenol and Resorcinol Molecules through the Dissolution of Sacrificial Anodes of Macro-Corrosion Galvanic Cells
title_short	Electrochemical Degradation of Phenol and Resorcinol Molecules through the Dissolution of Sacrificial Anodes of Macro-Corrosion Galvanic Cells
title_full	Electrochemical Degradation of Phenol and Resorcinol Molecules through the Dissolution of Sacrificial Anodes of Macro-Corrosion Galvanic Cells
title_fullStr	Electrochemical Degradation of Phenol and Resorcinol Molecules through the Dissolution of Sacrificial Anodes of Macro-Corrosion Galvanic Cells
title_full_unstemmed	Electrochemical Degradation of Phenol and Resorcinol Molecules through the Dissolution of Sacrificial Anodes of Macro-Corrosion Galvanic Cells
title_sort	electrochemical degradation of phenol and resorcinol molecules through the dissolution of sacrificial anodes of macro-corrosion galvanic cells
publisher	MDPI AG
series	Water
issn	2073-4441
publishDate	2018-06-01
description	This paper reports on the processes of phenol and resorcinol electrodegradation carried-out through continuous anodic dissolution of aluminum alloy and carbon steel sacrificial anodes for artificially aerated Cu-Al alloy and Cu-Fe-based galvanic (macro-corrosion) cells and synthetically prepared wastewater solutions. Electrochemical experiments were carried-out by means of a laboratory size, PMMA (Poly-methyl methacrylate)-made electrolyser unit, where significant degrees of phenol (10–89%) and resorcinol (13–37%) decomposition were obtained and visualized through the respective chemical/spectroscopy analyses. In addition, quantitative determination of phenol, as well as resorcinol (and possible electrodegradation products) for the selected experimental conditions was performed by means of instrumental high-performance liquid chromatography/mass spectrometry analysis.
topic	phenol and resorcinol electrodegradation galvanic cells sacrificial anodes HPLC/MS (high-performance liquid chromatography/mass spectrometry) analysis
url	http://www.mdpi.com/2073-4441/10/6/770
work_keys_str_mv	AT boguslawpierozynski electrochemicaldegradationofphenolandresorcinolmoleculesthroughthedissolutionofsacrificialanodesofmacrocorrosiongalvaniccells AT grazynapiotrowska electrochemicaldegradationofphenolandresorcinolmoleculesthroughthedissolutionofsacrificialanodesofmacrocorrosiongalvaniccells
_version_	1724845101137526784

Electrochemical Degradation of Phenol and Resorcinol Molecules through the Dissolution of Sacrificial Anodes of Macro-Corrosion Galvanic Cells

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