Bioinspired Polymer-Bound Organocatalysts for Direct Asymmetric Aldol Reaction: Experimental and Computational Studies

Bioinspired Polymer-Bound Organocatalysts for Direct Asymmetric Aldol Reaction: Experimental and Computational Studies

A series of poly(2-oxazoline) (POX) derivatives bearing prolinamide pendants were designed as organocatalysts and evaluated in the direct asymmetric aldol reaction between aromatic aldehydes and cyclic ketones. The structural variation of the alkyl spacer connecting the polymer backbone with the cat...

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Bibliographic Details
Main Authors: Ganhong Du, Jun Ling, Fangyu Hu, Keyuan Liu, Long Ye, Liming Jiang
Format: Article
Language:English
Published: MDPI AG 2019-04-01
Series:Catalysts
Subjects:
aldol reaction
organocatalysis
stereoselectivity
acidic additives
DFT calculations
Online Access:https://www.mdpi.com/2073-4344/9/5/398

Internet

https://www.mdpi.com/2073-4344/9/5/398

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