An unsymmetrical porphyrin and its metal complexes: Synthesis, spectroscopy, thermal analysis and liquid crystal properties

• Main Authors: Zhuang Changfu, Tang Xuexin, Wang Dong, Xia Aiqing, Lian Wenhui, Shi Yuhua, Shi Tongshun
• Format: Article
• Language: English
• Published: Serbian Chemical Society 2009-01-01
• Series: Journal of the Serbian Chemical Society
• Subjects: porphyrin; transition metal complex; fluorescence spectroscopy; liquid crystal
• Online Access: http://www.doiserbia.nb.rs/img/doi/0352-5139/2009/0352-51390910097Z.pdf
• ISSN: 0352-5139; 1820-7421

The synthesis and characterization of a new unsymmetrical porphyrin liquid crystal, 5-(4-stearoyloxyphenyl)phenyl-10,15,20-triphenylporphyrin (SPTPPH2) and its transition metal complexes (SPTPPM, M(II) = Zn, Fe, Co, Ni, Cu or Mn) are reported. Their structure and properties were studied by elemental analysis, and UV-Vis, IR, mass and 1H-HMR spectroscopy. Their luminescent properties were studied by excitation and emission spectroscopy. The quantum yields of the S1 → S0 fluorescence were measured at room temperature. According to thermal studies, the complexes have a higher thermal stability (no decomposition until 200°C). Differential scanning calorimetry (DSC) data and an optical textural photograph, obtained using a polarizing microscope (POM), indicate that the porphyrin ligand had liquid crystalline character and that it exhibited more than one mesophase and a low-lying phase transition temperature, with transition temperatures of 19.3 and 79.4°C; the temperature range of the liquid crystal (LC) phase of the ligand was 70.1°C.