(±)-N-(3-Hydroxy-1,2-diphenylpropyl)-4-methylbenzenesulfonamide

(±)-N-(3-Hydroxy-1,2-diphenylpropyl)-4-methylbenzenesulfonamide

In the title compound, C22H23NO3S, the relative stereochemistry of the two stereogenic centres is anti with respect to the H atoms. The molecular packing of the crystal shows a double-strand arrangement, consisting of one strand of (S*,S*) enantiomers and one strand of (R*,R*) enantiomers. Both stra...

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Main Authors: Margaret A. Brimble, Peter D. W. Boyd, Ka Wai Choi, David Barker, Sok Teng Tong
Format: Article
Language:English
Published: International Union of Crystallography 2008-10-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536808028948
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spelling doaj-18d34a8b6b0e4f788a86c930ec2c25792020-11-25T02:40:12ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-10-016410o1990o199010.1107/S1600536808028948(±)-N-(3-Hydroxy-1,2-diphenylpropyl)-4-methylbenzenesulfonamideMargaret A. BrimblePeter D. W. BoydKa Wai ChoiDavid BarkerSok Teng TongIn the title compound, C22H23NO3S, the relative stereochemistry of the two stereogenic centres is anti with respect to the H atoms. The molecular packing of the crystal shows a double-strand arrangement, consisting of one strand of (S*,S*) enantiomers and one strand of (R*,R*) enantiomers. Both strands lie parallel to each other along the a axis. Each strand is made up of dimers in which the molecules are connected to each other via an intermolecular O—H...O hydrogen bond between the hydroxyl groups and an O—H...π interaction with the aromatic ring. These units are then connected to neighbouring dimers via N—H...O hydrogen bonds and C—H...O interactions. Intramolecular C—H...O interactions are also observed.http://scripts.iucr.org/cgi-bin/paper?S1600536808028948
collection DOAJ
language English
format Article
sources DOAJ
author Margaret A. Brimble
Peter D. W. Boyd
Ka Wai Choi
David Barker
Sok Teng Tong
spellingShingle Margaret A. Brimble
Peter D. W. Boyd
Ka Wai Choi
David Barker
Sok Teng Tong
(±)-N-(3-Hydroxy-1,2-diphenylpropyl)-4-methylbenzenesulfonamide
Acta Crystallographica Section E
author_facet Margaret A. Brimble
Peter D. W. Boyd
Ka Wai Choi
David Barker
Sok Teng Tong
author_sort Margaret A. Brimble
title (±)-N-(3-Hydroxy-1,2-diphenylpropyl)-4-methylbenzenesulfonamide
title_short (±)-N-(3-Hydroxy-1,2-diphenylpropyl)-4-methylbenzenesulfonamide
title_full (±)-N-(3-Hydroxy-1,2-diphenylpropyl)-4-methylbenzenesulfonamide
title_fullStr (±)-N-(3-Hydroxy-1,2-diphenylpropyl)-4-methylbenzenesulfonamide
title_full_unstemmed (±)-N-(3-Hydroxy-1,2-diphenylpropyl)-4-methylbenzenesulfonamide
title_sort (±)-n-(3-hydroxy-1,2-diphenylpropyl)-4-methylbenzenesulfonamide
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2008-10-01
description In the title compound, C22H23NO3S, the relative stereochemistry of the two stereogenic centres is anti with respect to the H atoms. The molecular packing of the crystal shows a double-strand arrangement, consisting of one strand of (S*,S*) enantiomers and one strand of (R*,R*) enantiomers. Both strands lie parallel to each other along the a axis. Each strand is made up of dimers in which the molecules are connected to each other via an intermolecular O—H...O hydrogen bond between the hydroxyl groups and an O—H...π interaction with the aromatic ring. These units are then connected to neighbouring dimers via N—H...O hydrogen bonds and C—H...O interactions. Intramolecular C—H...O interactions are also observed.
url http://scripts.iucr.org/cgi-bin/paper?S1600536808028948
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AT peterdwboyd 177n3hydroxy12diphenylpropyl4methylbenzenesulfonamide
AT kawaichoi 177n3hydroxy12diphenylpropyl4methylbenzenesulfonamide
AT davidbarker 177n3hydroxy12diphenylpropyl4methylbenzenesulfonamide
AT soktengtong 177n3hydroxy12diphenylpropyl4methylbenzenesulfonamide
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