catena-Poly[[[bis(3-aminopyrazine-2-carboxylato)triaquapraseodymium(III)]-μ-3-aminopyrazine-2-carboxylato-[(3-aminopyrazine-2-carboxylato)diaquaformatopraseodymium(III)]-μ-3-aminopyrazine-2-carboxylato] hexahydrate]
The asymmetric unit of the polymeric title compound, {[Pr2(C5H4N3O2)5(CHO2)(H2O)5]·6H2O}n, has two independent PrIII atoms; one is coordinated by two water molecules and the other by three water molecules. The first is N,O-chelated by three 3-aminopyrazine-2-carboxylate ions, whereas th...
Main Authors: | , |
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Format: | Article |
Language: | English |
Published: |
International Union of Crystallography
2011-09-01
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Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811031308 |
Summary: | The asymmetric unit of the polymeric title compound, {[Pr2(C5H4N3O2)5(CHO2)(H2O)5]·6H2O}n, has two independent PrIII atoms; one is coordinated by two water molecules and the other by three water molecules. The first is N,O-chelated by three 3-aminopyrazine-2-carboxylate ions, whereas the second is chelated by two carboxylate ions; both exist in a monocapped square-antiprismatic geometry. The polymeric chains that run along the a axis interact with the lattice water molecules, generating a three-dimensional hydrogen-bonded network. The formate ion is disordered over two positions with respect to the non-coordinated atoms in a 1:1 ratio. |
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ISSN: | 1600-5368 |