Crystal structure of bis[2-(1H-benzimidazol-2-yl-κN3)aniline-κN]bis(nitrato-κO)cadmium(II)
In the title compound, [Cd(NO3)2(C13H11N3)2], the CdII atom lies on a twofold rotation axis and is coordinated by four N atoms and two O atoms, provided by two bidentate 2-(1H-benzimidazol-2-yl)aniline ligands, and two nitrato O atoms, forming a distorted octahedral geometry [range of bond angles ar...
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International Union of Crystallography
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doaj-1998c1c1bcce4ccf8167632b3b4932432020-11-25T01:50:25ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902019-10-0175101463146610.1107/S2056989019012416is5523Crystal structure of bis[2-(1H-benzimidazol-2-yl-κN3)aniline-κN]bis(nitrato-κO)cadmium(II)Yongtae Kim0Sung Kwon Kang1Department of Chemistry, Chungnam National University, Daejeon 305-764, Republic of KoreaDepartment of Chemistry, Chungnam National University, Daejeon 305-764, Republic of KoreaIn the title compound, [Cd(NO3)2(C13H11N3)2], the CdII atom lies on a twofold rotation axis and is coordinated by four N atoms and two O atoms, provided by two bidentate 2-(1H-benzimidazol-2-yl)aniline ligands, and two nitrato O atoms, forming a distorted octahedral geometry [range of bond angles around the Cd atom = 73.82 (2)–106.95 (8)°]. In the ligand, the dihedral angle between the aniline ring and the benzimidazole ring system is 30.43 (7)°. The discrete complex molecule is stabilized by an intramolecular N—H...O hydrogen bond. In the crystal, intermolecular N—H...O hydrogen bonds link the molecules, forming a three-dimensional network.http://scripts.iucr.org/cgi-bin/paper?S2056989019012416crystal structureCdII N-heterocyclic complexbenzimidazoleN—H...O hydrogen bonds |
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DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Yongtae Kim Sung Kwon Kang |
spellingShingle |
Yongtae Kim Sung Kwon Kang Crystal structure of bis[2-(1H-benzimidazol-2-yl-κN3)aniline-κN]bis(nitrato-κO)cadmium(II) Acta Crystallographica Section E: Crystallographic Communications crystal structure CdII N-heterocyclic complex benzimidazole N—H...O hydrogen bonds |
author_facet |
Yongtae Kim Sung Kwon Kang |
author_sort |
Yongtae Kim |
title |
Crystal structure of bis[2-(1H-benzimidazol-2-yl-κN3)aniline-κN]bis(nitrato-κO)cadmium(II) |
title_short |
Crystal structure of bis[2-(1H-benzimidazol-2-yl-κN3)aniline-κN]bis(nitrato-κO)cadmium(II) |
title_full |
Crystal structure of bis[2-(1H-benzimidazol-2-yl-κN3)aniline-κN]bis(nitrato-κO)cadmium(II) |
title_fullStr |
Crystal structure of bis[2-(1H-benzimidazol-2-yl-κN3)aniline-κN]bis(nitrato-κO)cadmium(II) |
title_full_unstemmed |
Crystal structure of bis[2-(1H-benzimidazol-2-yl-κN3)aniline-κN]bis(nitrato-κO)cadmium(II) |
title_sort |
crystal structure of bis[2-(1h-benzimidazol-2-yl-κn3)aniline-κn]bis(nitrato-κo)cadmium(ii) |
publisher |
International Union of Crystallography |
series |
Acta Crystallographica Section E: Crystallographic Communications |
issn |
2056-9890 |
publishDate |
2019-10-01 |
description |
In the title compound, [Cd(NO3)2(C13H11N3)2], the CdII atom lies on a twofold rotation axis and is coordinated by four N atoms and two O atoms, provided by two bidentate 2-(1H-benzimidazol-2-yl)aniline ligands, and two nitrato O atoms, forming a distorted octahedral geometry [range of bond angles around the Cd atom = 73.82 (2)–106.95 (8)°]. In the ligand, the dihedral angle between the aniline ring and the benzimidazole ring system is 30.43 (7)°. The discrete complex molecule is stabilized by an intramolecular N—H...O hydrogen bond. In the crystal, intermolecular N—H...O hydrogen bonds link the molecules, forming a three-dimensional network. |
topic |
crystal structure CdII N-heterocyclic complex benzimidazole N—H...O hydrogen bonds |
url |
http://scripts.iucr.org/cgi-bin/paper?S2056989019012416 |
work_keys_str_mv |
AT yongtaekim crystalstructureofbis21hbenzimidazol2ylkn3anilineknbisnitratokocadmiumii AT sungkwonkang crystalstructureofbis21hbenzimidazol2ylkn3anilineknbisnitratokocadmiumii |
_version_ |
1725002026114351104 |