(E)-2-(5-Chloro-2-hydroxybenzylidene)-N-cyclohexylhydrazine-1-carbothioamide

(E)-2-(5-Chloro-2-hydroxybenzylidene)-N-cyclohexylhydrazine-1-carbothioamide

In the title compound, C14H18ClN3OS, the phenol ring is almost coplanar with the hydrazinecarbothioamide moiety, making a dihedral angle of 6.92 (8)°. The cyclohexane ring has a chair conformation and the conformation about the C=N bond is E. In the crystal, molecules are linked by N—H...O and O—H.....

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Bibliographic Details
Main Authors: Md. Azharul Arafath, Farook Adam, Mohd. R. Razali
Format: Article
Language:English
Published: International Union of Crystallography 2017-01-01
Series:IUCrData
Subjects:
crystal structure
carbothioamide Schiff base
hydrazine-1-carbothioamide
hydrogen bonding
Cl...Cl interaction
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2414314616019970
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spelling doaj-1a402d2bc251455a920344e616385fca2020-11-24T22:02:44ZengInternational Union of CrystallographyIUCrData2414-31462017-01-0121x16199710.1107/S2414314616019970su4104(E)-2-(5-Chloro-2-hydroxybenzylidene)-N-cyclohexylhydrazine-1-carbothioamideMd. Azharul Arafath0Farook Adam1Mohd. R. Razali2The School of Chemical Sciences, Universiti Sains Malaysia (USM), Penang 11800, MalaysiaThe School of Chemical Sciences, Universiti Sains Malaysia (USM), Penang 11800, MalaysiaThe School of Chemical Sciences, Universiti Sains Malaysia (USM), Penang 11800, MalaysiaIn the title compound, C14H18ClN3OS, the phenol ring is almost coplanar with the hydrazinecarbothioamide moiety, making a dihedral angle of 6.92 (8)°. The cyclohexane ring has a chair conformation and the conformation about the C=N bond is E. In the crystal, molecules are linked by N—H...O and O—H...S hydrogen bonds, forming inversion dimers with an R22(14) ring motif flanked by two R22(6) ring motifs. The dimers are linked by short Cl...Cl interactions, forming layers parallel to the ab plane.http://scripts.iucr.org/cgi-bin/paper?S2414314616019970crystal structurecarbothioamide Schiff basehydrazine-1-carbothioamidehydrogen bondingCl...Cl interaction
collection DOAJ
language English
format Article
sources DOAJ
author Md. Azharul Arafath
Farook Adam
Mohd. R. Razali
spellingShingle Md. Azharul Arafath
Farook Adam
Mohd. R. Razali
(E)-2-(5-Chloro-2-hydroxybenzylidene)-N-cyclohexylhydrazine-1-carbothioamide
IUCrData
crystal structure
carbothioamide Schiff base
hydrazine-1-carbothioamide
hydrogen bonding
Cl...Cl interaction
author_facet Md. Azharul Arafath
Farook Adam
Mohd. R. Razali
author_sort Md. Azharul Arafath
title (E)-2-(5-Chloro-2-hydroxybenzylidene)-N-cyclohexylhydrazine-1-carbothioamide
title_short (E)-2-(5-Chloro-2-hydroxybenzylidene)-N-cyclohexylhydrazine-1-carbothioamide
title_full (E)-2-(5-Chloro-2-hydroxybenzylidene)-N-cyclohexylhydrazine-1-carbothioamide
title_fullStr (E)-2-(5-Chloro-2-hydroxybenzylidene)-N-cyclohexylhydrazine-1-carbothioamide
title_full_unstemmed (E)-2-(5-Chloro-2-hydroxybenzylidene)-N-cyclohexylhydrazine-1-carbothioamide
title_sort (e)-2-(5-chloro-2-hydroxybenzylidene)-n-cyclohexylhydrazine-1-carbothioamide
publisher International Union of Crystallography
series IUCrData
issn 2414-3146
publishDate 2017-01-01
description In the title compound, C14H18ClN3OS, the phenol ring is almost coplanar with the hydrazinecarbothioamide moiety, making a dihedral angle of 6.92 (8)°. The cyclohexane ring has a chair conformation and the conformation about the C=N bond is E. In the crystal, molecules are linked by N—H...O and O—H...S hydrogen bonds, forming inversion dimers with an R22(14) ring motif flanked by two R22(6) ring motifs. The dimers are linked by short Cl...Cl interactions, forming layers parallel to the ab plane.
topic crystal structure
carbothioamide Schiff base
hydrazine-1-carbothioamide
hydrogen bonding
Cl...Cl interaction
url http://scripts.iucr.org/cgi-bin/paper?S2414314616019970
work_keys_str_mv AT mdazharularafath e25chloro2hydroxybenzylidenencyclohexylhydrazine1carbothioamide
AT farookadam e25chloro2hydroxybenzylidenencyclohexylhydrazine1carbothioamide
AT mohdrrazali e25chloro2hydroxybenzylidenencyclohexylhydrazine1carbothioamide
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