One Nanoscale Zn(II)-Nd(III) Complex With Schiff Base Ligand: NIR Luminescent Sensing of Anions and Nitro Explosives

One Nanoscale Zn(II)-Nd(III) Complex With Schiff Base Ligand: NIR Luminescent Sensing of Anions and Nitro Explosives

One Zn-Nd complex [Zn2Nd4L2(OAc)10(OH)2(CH3OH)2] (1) was synthesized from Schiff base ligand bis(3-methoxysalicylidene)ethylene-1,2-phenylenediamine (H2L). 1 shows nanoscale rectangular structure with sizes of about 0.8 × 1.1 × 2.8 nm. 1 exhibits typical near-infrared luminescence of Nd(III) under t...

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Main Authors: Xia Liu, Xiaoping Yang, Yanan Ma, Jieni Liu, Dongliang Shi, Mengyu Niu, Desmond Schipper
Format: Article
Language:English
Published: Frontiers Media S.A. 2020-10-01
Series:Frontiers in Chemistry
Subjects:
lanthanide complex
Schiff base ligand
nanoscale structure
NIR luminescence
luminescent sensing
Online Access:https://www.frontiersin.org/article/10.3389/fchem.2020.536907/full
id doaj-1a40f9383d04422eb90ce3e792c77e8b
record_format Article
spelling doaj-1a40f9383d04422eb90ce3e792c77e8b2020-11-25T03:54:17ZengFrontiers Media S.A.Frontiers in Chemistry2296-26462020-10-01810.3389/fchem.2020.536907536907One Nanoscale Zn(II)-Nd(III) Complex With Schiff Base Ligand: NIR Luminescent Sensing of Anions and Nitro ExplosivesXia Liu0Xiaoping Yang1Yanan Ma2Jieni Liu3Dongliang Shi4Mengyu Niu5Desmond Schipper6College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou, ChinaCollege of Chemistry and Materials Engineering, Wenzhou University, Wenzhou, ChinaCollege of Chemistry and Materials Engineering, Wenzhou University, Wenzhou, ChinaCollege of Chemistry and Materials Engineering, Wenzhou University, Wenzhou, ChinaCollege of Chemistry and Materials Engineering, Wenzhou University, Wenzhou, ChinaCollege of Chemistry and Materials Engineering, Wenzhou University, Wenzhou, ChinaDepartment of Chemistry and Biochemistry, The University of Texas at Austin, Austin, TX, United StatesOne Zn-Nd complex [Zn2Nd4L2(OAc)10(OH)2(CH3OH)2] (1) was synthesized from Schiff base ligand bis(3-methoxysalicylidene)ethylene-1,2-phenylenediamine (H2L). 1 shows nanoscale rectangular structure with sizes of about 0.8 × 1.1 × 2.8 nm. 1 exhibits typical near-infrared luminescence of Nd(III) under the excitation of UV-visible light. Further study shows that the complex displays luminescent response behavior to anions and nitro explosives, especially with high sensitivity to H2PO2- and 2,4,6-trinitrophenol.https://www.frontiersin.org/article/10.3389/fchem.2020.536907/fulllanthanide complexSchiff base ligandnanoscale structureNIR luminescenceluminescent sensing
collection DOAJ
language English
format Article
sources DOAJ
author Xia Liu
Xiaoping Yang
Yanan Ma
Jieni Liu
Dongliang Shi
Mengyu Niu
Desmond Schipper
spellingShingle Xia Liu
Xiaoping Yang
Yanan Ma
Jieni Liu
Dongliang Shi
Mengyu Niu
Desmond Schipper
One Nanoscale Zn(II)-Nd(III) Complex With Schiff Base Ligand: NIR Luminescent Sensing of Anions and Nitro Explosives
Frontiers in Chemistry
lanthanide complex
Schiff base ligand
nanoscale structure
NIR luminescence
luminescent sensing
author_facet Xia Liu
Xiaoping Yang
Yanan Ma
Jieni Liu
Dongliang Shi
Mengyu Niu
Desmond Schipper
author_sort Xia Liu
title One Nanoscale Zn(II)-Nd(III) Complex With Schiff Base Ligand: NIR Luminescent Sensing of Anions and Nitro Explosives
title_short One Nanoscale Zn(II)-Nd(III) Complex With Schiff Base Ligand: NIR Luminescent Sensing of Anions and Nitro Explosives
title_full One Nanoscale Zn(II)-Nd(III) Complex With Schiff Base Ligand: NIR Luminescent Sensing of Anions and Nitro Explosives
title_fullStr One Nanoscale Zn(II)-Nd(III) Complex With Schiff Base Ligand: NIR Luminescent Sensing of Anions and Nitro Explosives
title_full_unstemmed One Nanoscale Zn(II)-Nd(III) Complex With Schiff Base Ligand: NIR Luminescent Sensing of Anions and Nitro Explosives
title_sort one nanoscale zn(ii)-nd(iii) complex with schiff base ligand: nir luminescent sensing of anions and nitro explosives
publisher Frontiers Media S.A.
series Frontiers in Chemistry
issn 2296-2646
publishDate 2020-10-01
description One Zn-Nd complex [Zn2Nd4L2(OAc)10(OH)2(CH3OH)2] (1) was synthesized from Schiff base ligand bis(3-methoxysalicylidene)ethylene-1,2-phenylenediamine (H2L). 1 shows nanoscale rectangular structure with sizes of about 0.8 × 1.1 × 2.8 nm. 1 exhibits typical near-infrared luminescence of Nd(III) under the excitation of UV-visible light. Further study shows that the complex displays luminescent response behavior to anions and nitro explosives, especially with high sensitivity to H2PO2- and 2,4,6-trinitrophenol.
topic lanthanide complex
Schiff base ligand
nanoscale structure
NIR luminescence
luminescent sensing
url https://www.frontiersin.org/article/10.3389/fchem.2020.536907/full
work_keys_str_mv AT xialiu onenanoscalezniindiiicomplexwithschiffbaseligandnirluminescentsensingofanionsandnitroexplosives
AT xiaopingyang onenanoscalezniindiiicomplexwithschiffbaseligandnirluminescentsensingofanionsandnitroexplosives
AT yananma onenanoscalezniindiiicomplexwithschiffbaseligandnirluminescentsensingofanionsandnitroexplosives
AT jieniliu onenanoscalezniindiiicomplexwithschiffbaseligandnirluminescentsensingofanionsandnitroexplosives
AT dongliangshi onenanoscalezniindiiicomplexwithschiffbaseligandnirluminescentsensingofanionsandnitroexplosives
AT mengyuniu onenanoscalezniindiiicomplexwithschiffbaseligandnirluminescentsensingofanionsandnitroexplosives
AT desmondschipper onenanoscalezniindiiicomplexwithschiffbaseligandnirluminescentsensingofanionsandnitroexplosives
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