catena-Poly[(μ2-3-carboxy-5-nitrobenzoato)(μ3-5-nitrobenzene-1,3-dicarboxylato)(1,10-phenanthroline)gadolinium(III)]

catena-Poly[(μ2-3-carboxy-5-nitrobenzoato)(μ3-5-nitrobenzene-1,3-dicarboxylato)(1,10-phenanthroline)gadolinium(III)]

The crystal structure of the title complex, [Gd(C8H3NO6)(C8H4NO6)(C12H8N2)]n, contains polymeric chains made up of GdIII atoms, 1,10-phenanthroline and fully or half-deprotonated 5-nitrobenzene-1,3-dicarboxylic acid (H2L) ligands. The GdIII atom is coordinated in a distorted bicapped trigonal-prisma...

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Main Authors: Zhi-Li Fang, Jun Wang
Format: Article
Language:English
Published: International Union of Crystallography 2010-10-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810035452
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spelling doaj-1a6f5567bc084e09832b7fd693eb426a2020-11-24T21:53:25ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-10-016610m1230m123110.1107/S1600536810035452catena-Poly[(μ2-3-carboxy-5-nitrobenzoato)(μ3-5-nitrobenzene-1,3-dicarboxylato)(1,10-phenanthroline)gadolinium(III)]Zhi-Li FangJun WangThe crystal structure of the title complex, [Gd(C8H3NO6)(C8H4NO6)(C12H8N2)]n, contains polymeric chains made up of GdIII atoms, 1,10-phenanthroline and fully or half-deprotonated 5-nitrobenzene-1,3-dicarboxylic acid (H2L) ligands. The GdIII atom is coordinated in a distorted bicapped trigonal-prismatic fashion by six O atoms from two HL− and three L2− ligands, and by two N atoms from the 1,10-phenanthroline ligand. The L2− ligands bridge the Gd–phenanthroline units, forming chains running parallel to [100]. O—H...O hydrogen bonding as well as π–π stacking interactions with an interplanar distance of 3.599 (2) Å assemble neighboring polymeric chains. http://scripts.iucr.org/cgi-bin/paper?S1600536810035452
collection DOAJ
language English
format Article
sources DOAJ
author Zhi-Li Fang
Jun Wang
spellingShingle Zhi-Li Fang
Jun Wang
catena-Poly[(μ2-3-carboxy-5-nitrobenzoato)(μ3-5-nitrobenzene-1,3-dicarboxylato)(1,10-phenanthroline)gadolinium(III)]
Acta Crystallographica Section E
author_facet Zhi-Li Fang
Jun Wang
author_sort Zhi-Li Fang
title catena-Poly[(μ2-3-carboxy-5-nitrobenzoato)(μ3-5-nitrobenzene-1,3-dicarboxylato)(1,10-phenanthroline)gadolinium(III)]
title_short catena-Poly[(μ2-3-carboxy-5-nitrobenzoato)(μ3-5-nitrobenzene-1,3-dicarboxylato)(1,10-phenanthroline)gadolinium(III)]
title_full catena-Poly[(μ2-3-carboxy-5-nitrobenzoato)(μ3-5-nitrobenzene-1,3-dicarboxylato)(1,10-phenanthroline)gadolinium(III)]
title_fullStr catena-Poly[(μ2-3-carboxy-5-nitrobenzoato)(μ3-5-nitrobenzene-1,3-dicarboxylato)(1,10-phenanthroline)gadolinium(III)]
title_full_unstemmed catena-Poly[(μ2-3-carboxy-5-nitrobenzoato)(μ3-5-nitrobenzene-1,3-dicarboxylato)(1,10-phenanthroline)gadolinium(III)]
title_sort catena-poly[(μ2-3-carboxy-5-nitrobenzoato)(μ3-5-nitrobenzene-1,3-dicarboxylato)(1,10-phenanthroline)gadolinium(iii)]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-10-01
description The crystal structure of the title complex, [Gd(C8H3NO6)(C8H4NO6)(C12H8N2)]n, contains polymeric chains made up of GdIII atoms, 1,10-phenanthroline and fully or half-deprotonated 5-nitrobenzene-1,3-dicarboxylic acid (H2L) ligands. The GdIII atom is coordinated in a distorted bicapped trigonal-prismatic fashion by six O atoms from two HL− and three L2− ligands, and by two N atoms from the 1,10-phenanthroline ligand. The L2− ligands bridge the Gd–phenanthroline units, forming chains running parallel to [100]. O—H...O hydrogen bonding as well as π–π stacking interactions with an interplanar distance of 3.599 (2) Å assemble neighboring polymeric chains.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810035452
work_keys_str_mv AT zhilifang catenapolyamp95623carboxy5nitrobenzoatoamp95635nitrobenzene13dicarboxylato110phenanthrolinegadoliniumiii
AT junwang catenapolyamp95623carboxy5nitrobenzoatoamp95635nitrobenzene13dicarboxylato110phenanthrolinegadoliniumiii
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