catena-Poly[(μ2-3-carboxy-5-nitrobenzoato)(μ3-5-nitrobenzene-1,3-dicarboxylato)(1,10-phenanthroline)gadolinium(III)]
The crystal structure of the title complex, [Gd(C8H3NO6)(C8H4NO6)(C12H8N2)]n, contains polymeric chains made up of GdIII atoms, 1,10-phenanthroline and fully or half-deprotonated 5-nitrobenzene-1,3-dicarboxylic acid (H2L) ligands. The GdIII atom is coordinated in a distorted bicapped trigonal-prisma...
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International Union of Crystallography
2010-10-01
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Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810035452 |
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doaj-1a6f5567bc084e09832b7fd693eb426a2020-11-24T21:53:25ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-10-016610m1230m123110.1107/S1600536810035452catena-Poly[(μ2-3-carboxy-5-nitrobenzoato)(μ3-5-nitrobenzene-1,3-dicarboxylato)(1,10-phenanthroline)gadolinium(III)]Zhi-Li FangJun WangThe crystal structure of the title complex, [Gd(C8H3NO6)(C8H4NO6)(C12H8N2)]n, contains polymeric chains made up of GdIII atoms, 1,10-phenanthroline and fully or half-deprotonated 5-nitrobenzene-1,3-dicarboxylic acid (H2L) ligands. The GdIII atom is coordinated in a distorted bicapped trigonal-prismatic fashion by six O atoms from two HL− and three L2− ligands, and by two N atoms from the 1,10-phenanthroline ligand. The L2− ligands bridge the Gd–phenanthroline units, forming chains running parallel to [100]. O—H...O hydrogen bonding as well as π–π stacking interactions with an interplanar distance of 3.599 (2) Å assemble neighboring polymeric chains. http://scripts.iucr.org/cgi-bin/paper?S1600536810035452 |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Zhi-Li Fang Jun Wang |
spellingShingle |
Zhi-Li Fang Jun Wang catena-Poly[(μ2-3-carboxy-5-nitrobenzoato)(μ3-5-nitrobenzene-1,3-dicarboxylato)(1,10-phenanthroline)gadolinium(III)] Acta Crystallographica Section E |
author_facet |
Zhi-Li Fang Jun Wang |
author_sort |
Zhi-Li Fang |
title |
catena-Poly[(μ2-3-carboxy-5-nitrobenzoato)(μ3-5-nitrobenzene-1,3-dicarboxylato)(1,10-phenanthroline)gadolinium(III)] |
title_short |
catena-Poly[(μ2-3-carboxy-5-nitrobenzoato)(μ3-5-nitrobenzene-1,3-dicarboxylato)(1,10-phenanthroline)gadolinium(III)] |
title_full |
catena-Poly[(μ2-3-carboxy-5-nitrobenzoato)(μ3-5-nitrobenzene-1,3-dicarboxylato)(1,10-phenanthroline)gadolinium(III)] |
title_fullStr |
catena-Poly[(μ2-3-carboxy-5-nitrobenzoato)(μ3-5-nitrobenzene-1,3-dicarboxylato)(1,10-phenanthroline)gadolinium(III)] |
title_full_unstemmed |
catena-Poly[(μ2-3-carboxy-5-nitrobenzoato)(μ3-5-nitrobenzene-1,3-dicarboxylato)(1,10-phenanthroline)gadolinium(III)] |
title_sort |
catena-poly[(μ2-3-carboxy-5-nitrobenzoato)(μ3-5-nitrobenzene-1,3-dicarboxylato)(1,10-phenanthroline)gadolinium(iii)] |
publisher |
International Union of Crystallography |
series |
Acta Crystallographica Section E |
issn |
1600-5368 |
publishDate |
2010-10-01 |
description |
The crystal structure of the title complex, [Gd(C8H3NO6)(C8H4NO6)(C12H8N2)]n, contains polymeric chains made up of GdIII atoms, 1,10-phenanthroline and fully or half-deprotonated 5-nitrobenzene-1,3-dicarboxylic acid (H2L) ligands. The GdIII atom is coordinated in a distorted bicapped trigonal-prismatic fashion by six O atoms from two HL− and three L2− ligands, and by two N atoms from the 1,10-phenanthroline ligand. The L2− ligands bridge the Gd–phenanthroline units, forming chains running parallel to [100]. O—H...O hydrogen bonding as well as π–π stacking interactions with an interplanar distance of 3.599 (2) Å assemble neighboring polymeric chains. |
url |
http://scripts.iucr.org/cgi-bin/paper?S1600536810035452 |
work_keys_str_mv |
AT zhilifang catenapolyamp95623carboxy5nitrobenzoatoamp95635nitrobenzene13dicarboxylato110phenanthrolinegadoliniumiii AT junwang catenapolyamp95623carboxy5nitrobenzoatoamp95635nitrobenzene13dicarboxylato110phenanthrolinegadoliniumiii |
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1725872466171002880 |