Aquachlorido{6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato-κ2O1,N,N′,O1′}cobalt(III) dimethylformamide monosolvate

Aquachlorido{6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato-κ2O1,N,N′,O1′}cobalt(III) dimethylformamide monosolvate

In the title compound, [Co(C18H18N2O4)Cl(H2O)]·C3H7NO, the CoIII ion is six-coordinated by a tetradentate 6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolate ligand, with a chloride ion and an aqua ligand in the apical positions. The c...

Full description

Bibliographic Details
Main Authors: Yun Wei, Ting Pang, Jiacheng Liu, Meng Li, Lili Liang
Format: Article
Language:English
Published: International Union of Crystallography 2012-04-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812011324
id doaj-1afedbbaf66741d387bc0e1f86acb4a1
record_format Article
spelling doaj-1afedbbaf66741d387bc0e1f86acb4a12020-11-25T00:52:34ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-04-01684m455m45610.1107/S1600536812011324Aquachlorido{6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato-κ2O1,N,N′,O1′}cobalt(III) dimethylformamide monosolvateYun WeiTing PangJiacheng LiuMeng LiLili LiangIn the title compound, [Co(C18H18N2O4)Cl(H2O)]·C3H7NO, the CoIII ion is six-coordinated by a tetradentate 6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolate ligand, with a chloride ion and an aqua ligand in the apical positions. The compound crystallized as a dimethylformamide (DMF) monosolvate. In the crystal, complex molecules are linked via O—Hwater...O hydrogen bonds to form a dimer-like arrangement. These dimers are linked via a C—H...Cl interaction, and the DMF molecule is linked to the complex molecule by C—H...O interactions.http://scripts.iucr.org/cgi-bin/paper?S1600536812011324
collection DOAJ
language English
format Article
sources DOAJ
author Yun Wei
Ting Pang
Jiacheng Liu
Meng Li
Lili Liang
spellingShingle Yun Wei
Ting Pang
Jiacheng Liu
Meng Li
Lili Liang
Aquachlorido{6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato-κ2O1,N,N′,O1′}cobalt(III) dimethylformamide monosolvate
Acta Crystallographica Section E
author_facet Yun Wei
Ting Pang
Jiacheng Liu
Meng Li
Lili Liang
author_sort Yun Wei
title Aquachlorido{6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato-κ2O1,N,N′,O1′}cobalt(III) dimethylformamide monosolvate
title_short Aquachlorido{6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato-κ2O1,N,N′,O1′}cobalt(III) dimethylformamide monosolvate
title_full Aquachlorido{6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato-κ2O1,N,N′,O1′}cobalt(III) dimethylformamide monosolvate
title_fullStr Aquachlorido{6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato-κ2O1,N,N′,O1′}cobalt(III) dimethylformamide monosolvate
title_full_unstemmed Aquachlorido{6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato-κ2O1,N,N′,O1′}cobalt(III) dimethylformamide monosolvate
title_sort aquachlorido{6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato-κ2o1,n,n′,o1′}cobalt(iii) dimethylformamide monosolvate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-04-01
description In the title compound, [Co(C18H18N2O4)Cl(H2O)]·C3H7NO, the CoIII ion is six-coordinated by a tetradentate 6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolate ligand, with a chloride ion and an aqua ligand in the apical positions. The compound crystallized as a dimethylformamide (DMF) monosolvate. In the crystal, complex molecules are linked via O—Hwater...O hydrogen bonds to form a dimer-like arrangement. These dimers are linked via a C—H...Cl interaction, and the DMF molecule is linked to the complex molecule by C—H...O interactions.
url http://scripts.iucr.org/cgi-bin/paper?S1600536812011324
work_keys_str_mv AT yunwei aquachlorido66amp8242dimethoxy22amp8242ethane12diylbisnitrilomethanylylidenediphenolatoamp9542o1nnamp8242o1amp8242cobaltiiidimethylformamidemonosolvate
AT tingpang aquachlorido66amp8242dimethoxy22amp8242ethane12diylbisnitrilomethanylylidenediphenolatoamp9542o1nnamp8242o1amp8242cobaltiiidimethylformamidemonosolvate
AT jiachengliu aquachlorido66amp8242dimethoxy22amp8242ethane12diylbisnitrilomethanylylidenediphenolatoamp9542o1nnamp8242o1amp8242cobaltiiidimethylformamidemonosolvate
AT mengli aquachlorido66amp8242dimethoxy22amp8242ethane12diylbisnitrilomethanylylidenediphenolatoamp9542o1nnamp8242o1amp8242cobaltiiidimethylformamidemonosolvate
AT lililiang aquachlorido66amp8242dimethoxy22amp8242ethane12diylbisnitrilomethanylylidenediphenolatoamp9542o1nnamp8242o1amp8242cobaltiiidimethylformamidemonosolvate
_version_ 1725241702902398976

Similar Items