Di-μ-benzoato-κ3O,O′:O′;κ3O:O,O′-bis[(benzoato-κ2O,O′)(1,10-phenanthroline-κ2N,N′)cadmium]

Di-μ-benzoato-κ3O,O′:O′;κ3O:O,O′-bis[(benzoato-κ2O,O′)(1,10-phenanthroline-κ2N,N′)cadmium]

The dinuclear title compound, [Cd2(C7H5O2)4(C12H8N2)2], lies on a crystallographic twofold axis. The CdII ions are connected by two bridging benzoate anions and each ion is seven-coordinated by five O atoms from three benzoate ligands and by two N atoms from 1,10-phenanthroline. The benzoate ligands...

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Main Authors: Hong-Jin Li, Zhu-Qing Gao, Jin-Zhong Gu
Format: Article
Language:English
Published: International Union of Crystallography 2011-07-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811022185
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spelling doaj-1b115c32d2a84ffc9d2f132ff72b63912020-11-24T21:28:57ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-07-01677m919m91910.1107/S1600536811022185Di-μ-benzoato-κ3O,O′:O′;κ3O:O,O′-bis[(benzoato-κ2O,O′)(1,10-phenanthroline-κ2N,N′)cadmium]Hong-Jin LiZhu-Qing GaoJin-Zhong GuThe dinuclear title compound, [Cd2(C7H5O2)4(C12H8N2)2], lies on a crystallographic twofold axis. The CdII ions are connected by two bridging benzoate anions and each ion is seven-coordinated by five O atoms from three benzoate ligands and by two N atoms from 1,10-phenanthroline. The benzoate ligands adopt two different coordination modes, acting as bidentate and bridging tridentate ligands. The discrete neutral molecules further extend their structure into a three-dimensional supramolecular framework by intermolecular π–π [interplanar distances of 3.392 (4) Å] and C—H...π stacking interactions [H–mean plane = 2.567 (4) and 2.781 (4) Å].http://scripts.iucr.org/cgi-bin/paper?S1600536811022185
collection DOAJ
language English
format Article
sources DOAJ
author Hong-Jin Li
Zhu-Qing Gao
Jin-Zhong Gu
spellingShingle Hong-Jin Li
Zhu-Qing Gao
Jin-Zhong Gu
Di-μ-benzoato-κ3O,O′:O′;κ3O:O,O′-bis[(benzoato-κ2O,O′)(1,10-phenanthroline-κ2N,N′)cadmium]
Acta Crystallographica Section E
author_facet Hong-Jin Li
Zhu-Qing Gao
Jin-Zhong Gu
author_sort Hong-Jin Li
title Di-μ-benzoato-κ3O,O′:O′;κ3O:O,O′-bis[(benzoato-κ2O,O′)(1,10-phenanthroline-κ2N,N′)cadmium]
title_short Di-μ-benzoato-κ3O,O′:O′;κ3O:O,O′-bis[(benzoato-κ2O,O′)(1,10-phenanthroline-κ2N,N′)cadmium]
title_full Di-μ-benzoato-κ3O,O′:O′;κ3O:O,O′-bis[(benzoato-κ2O,O′)(1,10-phenanthroline-κ2N,N′)cadmium]
title_fullStr Di-μ-benzoato-κ3O,O′:O′;κ3O:O,O′-bis[(benzoato-κ2O,O′)(1,10-phenanthroline-κ2N,N′)cadmium]
title_full_unstemmed Di-μ-benzoato-κ3O,O′:O′;κ3O:O,O′-bis[(benzoato-κ2O,O′)(1,10-phenanthroline-κ2N,N′)cadmium]
title_sort di-μ-benzoato-κ3o,o′:o′;κ3o:o,o′-bis[(benzoato-κ2o,o′)(1,10-phenanthroline-κ2n,n′)cadmium]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2011-07-01
description The dinuclear title compound, [Cd2(C7H5O2)4(C12H8N2)2], lies on a crystallographic twofold axis. The CdII ions are connected by two bridging benzoate anions and each ion is seven-coordinated by five O atoms from three benzoate ligands and by two N atoms from 1,10-phenanthroline. The benzoate ligands adopt two different coordination modes, acting as bidentate and bridging tridentate ligands. The discrete neutral molecules further extend their structure into a three-dimensional supramolecular framework by intermolecular π–π [interplanar distances of 3.392 (4) Å] and C—H...π stacking interactions [H–mean plane = 2.567 (4) and 2.781 (4) Å].
url http://scripts.iucr.org/cgi-bin/paper?S1600536811022185
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