Study on the inhibition of mild steel corrosion by 1,3-bis-(morpholin-4-yl-phenyl-methyl)-thiourea in hydrochloric acid medium

1,3-Bis-(morpholin-4-yl-phenyl-methyl)-thiourea (MBT) was synthesized and their influence on the inhibition of corrosion on mild steel in various hydrochloric acid concentrations has been investigated by weight loss, potentiodynamic polarization, electrochemical impedance (EI), Tafel polarization, s...

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Main Authors: Devaraj Karthik, D. Tamilvendan, G. Venkatesa Prabhu
Format: Article
Language:English
Published: Elsevier 2014-12-01
Series:Journal of Saudi Chemical Society
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S1319610311001979
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spelling doaj-1b3632fe5c294be8a02f7d5f8e36008a2020-11-25T01:06:13ZengElsevierJournal of Saudi Chemical Society1319-61032014-12-0118683584410.1016/j.jscs.2011.10.009Study on the inhibition of mild steel corrosion by 1,3-bis-(morpholin-4-yl-phenyl-methyl)-thiourea in hydrochloric acid mediumDevaraj Karthik0D. Tamilvendan1G. Venkatesa Prabhu2Department of Chemistry, National Institute of Technology, Tiruchirappalli 620 015, IndiaCentre for Research and Development, PRIST University, Thanjavur 613 403, Tamil Nadu, IndiaDepartment of Chemistry, National Institute of Technology, Tiruchirappalli 620 015, India1,3-Bis-(morpholin-4-yl-phenyl-methyl)-thiourea (MBT) was synthesized and their influence on the inhibition of corrosion on mild steel in various hydrochloric acid concentrations has been investigated by weight loss, potentiodynamic polarization, electrochemical impedance (EI), Tafel polarization, scanning electron microscope (SEM) and FT-IR methods. The result of weight loss study shows that the corrosion inhibition efficiency (IE) is directly proportional to the concentration of the inhibitor and inversely proportional to the temperature. Electrochemical study proved that the inhibitor acts as a mixed type inhibitor. SEM shows the formation of a protective film of the inhibitor on the mild steel. The IR data also provide evidence for the anticorrosion effect of the inhibitor.http://www.sciencedirect.com/science/article/pii/S1319610311001979CorrosionInhibition efficiencyPotentiodynamic polarizationElectrochemical impedanceTafel polarizationScanning electron microscope
collection DOAJ
language English
format Article
sources DOAJ
author Devaraj Karthik
D. Tamilvendan
G. Venkatesa Prabhu
spellingShingle Devaraj Karthik
D. Tamilvendan
G. Venkatesa Prabhu
Study on the inhibition of mild steel corrosion by 1,3-bis-(morpholin-4-yl-phenyl-methyl)-thiourea in hydrochloric acid medium
Journal of Saudi Chemical Society
Corrosion
Inhibition efficiency
Potentiodynamic polarization
Electrochemical impedance
Tafel polarization
Scanning electron microscope
author_facet Devaraj Karthik
D. Tamilvendan
G. Venkatesa Prabhu
author_sort Devaraj Karthik
title Study on the inhibition of mild steel corrosion by 1,3-bis-(morpholin-4-yl-phenyl-methyl)-thiourea in hydrochloric acid medium
title_short Study on the inhibition of mild steel corrosion by 1,3-bis-(morpholin-4-yl-phenyl-methyl)-thiourea in hydrochloric acid medium
title_full Study on the inhibition of mild steel corrosion by 1,3-bis-(morpholin-4-yl-phenyl-methyl)-thiourea in hydrochloric acid medium
title_fullStr Study on the inhibition of mild steel corrosion by 1,3-bis-(morpholin-4-yl-phenyl-methyl)-thiourea in hydrochloric acid medium
title_full_unstemmed Study on the inhibition of mild steel corrosion by 1,3-bis-(morpholin-4-yl-phenyl-methyl)-thiourea in hydrochloric acid medium
title_sort study on the inhibition of mild steel corrosion by 1,3-bis-(morpholin-4-yl-phenyl-methyl)-thiourea in hydrochloric acid medium
publisher Elsevier
series Journal of Saudi Chemical Society
issn 1319-6103
publishDate 2014-12-01
description 1,3-Bis-(morpholin-4-yl-phenyl-methyl)-thiourea (MBT) was synthesized and their influence on the inhibition of corrosion on mild steel in various hydrochloric acid concentrations has been investigated by weight loss, potentiodynamic polarization, electrochemical impedance (EI), Tafel polarization, scanning electron microscope (SEM) and FT-IR methods. The result of weight loss study shows that the corrosion inhibition efficiency (IE) is directly proportional to the concentration of the inhibitor and inversely proportional to the temperature. Electrochemical study proved that the inhibitor acts as a mixed type inhibitor. SEM shows the formation of a protective film of the inhibitor on the mild steel. The IR data also provide evidence for the anticorrosion effect of the inhibitor.
topic Corrosion
Inhibition efficiency
Potentiodynamic polarization
Electrochemical impedance
Tafel polarization
Scanning electron microscope
url http://www.sciencedirect.com/science/article/pii/S1319610311001979
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