Crystal structure of 4,4′-(disulfanediyl)dibutanoic acid–4,4′-bipyridine (1/1)
4,4′-(Disulfanediyl)dibutanoic acid (dtba) and 4,4′-bipyridine (4,4′-bpy) crystallize in an 1:1 ratio, leading to the title co-crystal with composition C8H14O4S2·C10H8N2. A distinctive feature of the crystal structure is the geometry of the dtba moiety, which appears to be stretched [with a 9.98 (1)...
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International Union of Crystallography
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doaj-1c2fc8e4a4a64a0697c838f81dcedb592020-11-24T21:45:14ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682014-09-0170915716010.1107/S1600536814018558wm5041Crystal structure of 4,4′-(disulfanediyl)dibutanoic acid–4,4′-bipyridine (1/1)Ana María Atria0Maria Teresa Garland1Ricardo Baggio2Facultad de Ciencias Químicas y Farmacéuticas, Universidad de Chile, Casilla 233, Santiago, ChileDepartamento de Física, Facultad de Ciencias Físicas y Matemáticas, Universidad de Chile, Santiago de Chile, ChileDepartamento de Física, Centro Atómico Constituyentes, Comisión Nacional de Energía Atómica, Buenos Aires, Argentina4,4′-(Disulfanediyl)dibutanoic acid (dtba) and 4,4′-bipyridine (4,4′-bpy) crystallize in an 1:1 ratio, leading to the title co-crystal with composition C8H14O4S2·C10H8N2. A distinctive feature of the crystal structure is the geometry of the dtba moiety, which appears to be stretched [with a 9.98 (1) Å span between outermost carbons] and acts as an hydrogen-bonding connector, forming linear chains along [-211] with the 4,4′-bpy moiety by way of O—H...N hydrogen bonds and C—H...O interactions. The influence of the molecular shape on the hydrogen-bonding pattern is analysed by comparing the title compound and two other 4,4′-bpy co-crystals with closely related molecules of similar formulation but different geometry, showing the way in which this correlates with the packing arrangement.http://scripts.iucr.org/cgi-bin/paper?S1600536814018558crystal structurehydrogen-bonding dispositionco-crystal |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Ana María Atria Maria Teresa Garland Ricardo Baggio |
spellingShingle |
Ana María Atria Maria Teresa Garland Ricardo Baggio Crystal structure of 4,4′-(disulfanediyl)dibutanoic acid–4,4′-bipyridine (1/1) Acta Crystallographica Section E crystal structure hydrogen-bonding disposition co-crystal |
author_facet |
Ana María Atria Maria Teresa Garland Ricardo Baggio |
author_sort |
Ana María Atria |
title |
Crystal structure of 4,4′-(disulfanediyl)dibutanoic acid–4,4′-bipyridine (1/1) |
title_short |
Crystal structure of 4,4′-(disulfanediyl)dibutanoic acid–4,4′-bipyridine (1/1) |
title_full |
Crystal structure of 4,4′-(disulfanediyl)dibutanoic acid–4,4′-bipyridine (1/1) |
title_fullStr |
Crystal structure of 4,4′-(disulfanediyl)dibutanoic acid–4,4′-bipyridine (1/1) |
title_full_unstemmed |
Crystal structure of 4,4′-(disulfanediyl)dibutanoic acid–4,4′-bipyridine (1/1) |
title_sort |
crystal structure of 4,4′-(disulfanediyl)dibutanoic acid–4,4′-bipyridine (1/1) |
publisher |
International Union of Crystallography |
series |
Acta Crystallographica Section E |
issn |
1600-5368 |
publishDate |
2014-09-01 |
description |
4,4′-(Disulfanediyl)dibutanoic acid (dtba) and 4,4′-bipyridine (4,4′-bpy) crystallize in an 1:1 ratio, leading to the title co-crystal with composition C8H14O4S2·C10H8N2. A distinctive feature of the crystal structure is the geometry of the dtba moiety, which appears to be stretched [with a 9.98 (1) Å span between outermost carbons] and acts as an hydrogen-bonding connector, forming linear chains along [-211] with the 4,4′-bpy moiety by way of O—H...N hydrogen bonds and C—H...O interactions. The influence of the molecular shape on the hydrogen-bonding pattern is analysed by comparing the title compound and two other 4,4′-bpy co-crystals with closely related molecules of similar formulation but different geometry, showing the way in which this correlates with the packing arrangement. |
topic |
crystal structure hydrogen-bonding disposition co-crystal |
url |
http://scripts.iucr.org/cgi-bin/paper?S1600536814018558 |
work_keys_str_mv |
AT anamariaatria crystalstructureof44disulfanediyldibutanoicacid44bipyridine11 AT mariateresagarland crystalstructureof44disulfanediyldibutanoicacid44bipyridine11 AT ricardobaggio crystalstructureof44disulfanediyldibutanoicacid44bipyridine11 |
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1725905755033305088 |