Autocatalytic and oscillatory reaction networks that form guanidines and products of their cyclization

So far, only a few chemical oscillators based on organic reactions have been developed. Here, the authors report both autocatalytic and oscillatory reaction networks that form substituted guanidines from thiouronium salts; when coupled to cascade cyclization, this reaction network produces oscillati...

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Main Authors:	Alexander I. Novichkov, Anton I. Hanopolskyi, Xiaoming Miao, Linda J. W. Shimon, Yael Diskin-Posner, Sergey N. Semenov
Format:	Article
Language:	English
Published:	Nature Publishing Group 2021-05-01
Series:	Nature Communications
Online Access:	https://doi.org/10.1038/s41467-021-23206-9

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spelling	doaj-1c6275c48f0e4de699754dd9efaad4e82021-05-23T11:11:57ZengNature Publishing GroupNature Communications2041-17232021-05-0112111310.1038/s41467-021-23206-9Autocatalytic and oscillatory reaction networks that form guanidines and products of their cyclizationAlexander I. Novichkov0Anton I. Hanopolskyi1Xiaoming Miao2Linda J. W. Shimon3Yael Diskin-Posner4Sergey N. Semenov5Department of Molecular Chemistry and Materials Science, Weizmann Institute of ScienceDepartment of Molecular Chemistry and Materials Science, Weizmann Institute of ScienceDepartment of Molecular Chemistry and Materials Science, Weizmann Institute of ScienceDepartment of Chemical Research Support, Weizmann Institute of ScienceDepartment of Chemical Research Support, Weizmann Institute of ScienceDepartment of Molecular Chemistry and Materials Science, Weizmann Institute of ScienceSo far, only a few chemical oscillators based on organic reactions have been developed. Here, the authors report both autocatalytic and oscillatory reaction networks that form substituted guanidines from thiouronium salts; when coupled to cascade cyclization, this reaction network produces oscillations in the production of pyrimidine-based heterocycles.https://doi.org/10.1038/s41467-021-23206-9
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Alexander I. Novichkov Anton I. Hanopolskyi Xiaoming Miao Linda J. W. Shimon Yael Diskin-Posner Sergey N. Semenov
spellingShingle	Alexander I. Novichkov Anton I. Hanopolskyi Xiaoming Miao Linda J. W. Shimon Yael Diskin-Posner Sergey N. Semenov Autocatalytic and oscillatory reaction networks that form guanidines and products of their cyclization Nature Communications
author_facet	Alexander I. Novichkov Anton I. Hanopolskyi Xiaoming Miao Linda J. W. Shimon Yael Diskin-Posner Sergey N. Semenov
author_sort	Alexander I. Novichkov
title	Autocatalytic and oscillatory reaction networks that form guanidines and products of their cyclization
title_short	Autocatalytic and oscillatory reaction networks that form guanidines and products of their cyclization
title_full	Autocatalytic and oscillatory reaction networks that form guanidines and products of their cyclization
title_fullStr	Autocatalytic and oscillatory reaction networks that form guanidines and products of their cyclization
title_full_unstemmed	Autocatalytic and oscillatory reaction networks that form guanidines and products of their cyclization
title_sort	autocatalytic and oscillatory reaction networks that form guanidines and products of their cyclization
publisher	Nature Publishing Group
series	Nature Communications
issn	2041-1723
publishDate	2021-05-01
description	So far, only a few chemical oscillators based on organic reactions have been developed. Here, the authors report both autocatalytic and oscillatory reaction networks that form substituted guanidines from thiouronium salts; when coupled to cascade cyclization, this reaction network produces oscillations in the production of pyrimidine-based heterocycles.
url	https://doi.org/10.1038/s41467-021-23206-9
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Autocatalytic and oscillatory reaction networks that form guanidines and products of their cyclization

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