Thin Porous Poly(ionic liquid) Coatings for Enhanced Headspace Solid Phase Microextraction

In this contribution, thin poly(ionic liquid) (PIL) coatings with a well-defined pore structure built up from interpolyelectrolyte complexation between a PIL and poly(acrylic acid) (PAA) were successfully used for enhanced solid phase microextraction (SPME). The introduction of porosity with tunable...

Full description

Bibliographic Details
Main Authors: David J. S. Patinha, Hong Wang, Jiayin Yuan, Sílvia M. Rocha, Armando J. D. Silvestre, Isabel M. Marrucho
Format: Article
Language:English
Published: MDPI AG 2020-08-01
Series:Polymers
Subjects:
Online Access:https://www.mdpi.com/2073-4360/12/9/1909
id doaj-1cfbd9a6caa54b4f8ce5e21df5fb58f6
record_format Article
spelling doaj-1cfbd9a6caa54b4f8ce5e21df5fb58f62020-11-25T03:51:32ZengMDPI AGPolymers2073-43602020-08-01121909190910.3390/polym12091909Thin Porous Poly(ionic liquid) Coatings for Enhanced Headspace Solid Phase MicroextractionDavid J. S. Patinha0Hong Wang1Jiayin Yuan2Sílvia M. Rocha3Armando J. D. Silvestre4Isabel M. Marrucho5Instituto de Tecnologia Química e Biológica António Xavier, Universidade Nova de Lisboa, Av. Da República, 2780-157 Oeiras, PortugalKey Laboratory of Functional Polymer Materials, Ministry of Education, Institute of Polymer Chemistry, Nankai University, Tianjin 300071, ChinaDepartment of Materials and Environmental Chemistry, Stockholm University, 10691 Stockholm, SwedenLAQV-REQUIMTE & Department of Chemistry, University of Aveiro, Campus Universitário de Santiago, 3810-193 Aveiro, PortugalCICECO—Aveiro Institute of Materials and Department of Chemistry, University of Aveiro, 3810-193 Aveiro, PortugalCentro de Química Estrutural and Departamento de Engenharia Química, Instituto Superior Técnico, Universidade de Lisboa, Avenida Rovisco Pais, 1049-001 Lisboa, PortugalIn this contribution, thin poly(ionic liquid) (PIL) coatings with a well-defined pore structure built up from interpolyelectrolyte complexation between a PIL and poly(acrylic acid) (PAA) were successfully used for enhanced solid phase microextraction (SPME). The introduction of porosity with tunable polarity through the highly versatile PIL chemistry clearly boosts the potential of SPME in the detection of compounds at rather low concentrations. This work will inspire researchers to further explore the potential of porous poly(ionic liquid) materials in sensing and separation applications.https://www.mdpi.com/2073-4360/12/9/1909solid phase microextraction (SPME)poly(ionic liquid)interpolyelectrolyte complexationporous materialssurface coating
collection DOAJ
language English
format Article
sources DOAJ
author David J. S. Patinha
Hong Wang
Jiayin Yuan
Sílvia M. Rocha
Armando J. D. Silvestre
Isabel M. Marrucho
spellingShingle David J. S. Patinha
Hong Wang
Jiayin Yuan
Sílvia M. Rocha
Armando J. D. Silvestre
Isabel M. Marrucho
Thin Porous Poly(ionic liquid) Coatings for Enhanced Headspace Solid Phase Microextraction
Polymers
solid phase microextraction (SPME)
poly(ionic liquid)
interpolyelectrolyte complexation
porous materials
surface coating
author_facet David J. S. Patinha
Hong Wang
Jiayin Yuan
Sílvia M. Rocha
Armando J. D. Silvestre
Isabel M. Marrucho
author_sort David J. S. Patinha
title Thin Porous Poly(ionic liquid) Coatings for Enhanced Headspace Solid Phase Microextraction
title_short Thin Porous Poly(ionic liquid) Coatings for Enhanced Headspace Solid Phase Microextraction
title_full Thin Porous Poly(ionic liquid) Coatings for Enhanced Headspace Solid Phase Microextraction
title_fullStr Thin Porous Poly(ionic liquid) Coatings for Enhanced Headspace Solid Phase Microextraction
title_full_unstemmed Thin Porous Poly(ionic liquid) Coatings for Enhanced Headspace Solid Phase Microextraction
title_sort thin porous poly(ionic liquid) coatings for enhanced headspace solid phase microextraction
publisher MDPI AG
series Polymers
issn 2073-4360
publishDate 2020-08-01
description In this contribution, thin poly(ionic liquid) (PIL) coatings with a well-defined pore structure built up from interpolyelectrolyte complexation between a PIL and poly(acrylic acid) (PAA) were successfully used for enhanced solid phase microextraction (SPME). The introduction of porosity with tunable polarity through the highly versatile PIL chemistry clearly boosts the potential of SPME in the detection of compounds at rather low concentrations. This work will inspire researchers to further explore the potential of porous poly(ionic liquid) materials in sensing and separation applications.
topic solid phase microextraction (SPME)
poly(ionic liquid)
interpolyelectrolyte complexation
porous materials
surface coating
url https://www.mdpi.com/2073-4360/12/9/1909
work_keys_str_mv AT davidjspatinha thinporouspolyionicliquidcoatingsforenhancedheadspacesolidphasemicroextraction
AT hongwang thinporouspolyionicliquidcoatingsforenhancedheadspacesolidphasemicroextraction
AT jiayinyuan thinporouspolyionicliquidcoatingsforenhancedheadspacesolidphasemicroextraction
AT silviamrocha thinporouspolyionicliquidcoatingsforenhancedheadspacesolidphasemicroextraction
AT armandojdsilvestre thinporouspolyionicliquidcoatingsforenhancedheadspacesolidphasemicroextraction
AT isabelmmarrucho thinporouspolyionicliquidcoatingsforenhancedheadspacesolidphasemicroextraction
_version_ 1724487058476498944